• Title/Summary/Keyword: microfibrils

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Preparation of Syndiotactic Poly(vinyl alcohol) Microfibrils with Radiopaque Inorganic Particles (방사선불투과성 무기입자를 첨가한 교대배열 폴리비닐알코올 마이크로피브릴의 제조)

  • Jo, Hye Won;Cha, Jin Wook;Han, Sung Soo;Lee, Joon Seok;Oh, Tae Hwan
    • Polymer(Korea)
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    • v.37 no.5
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    • pp.563-570
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    • 2013
  • Poly(vinyl pivalate) (PVPi) was bulk polymerized to make poly(vinyl alcohol) (PVA) microfibrils to apply for polymeric embolization coils replacing metalic coils. Then, syndiotactic PVA (s-PVA) microfibrils having number-average degree of polymerization of 1100 and s-diad content of 60.4% were prepared via saponification of the PVPi with no separate spinning process. To make s-PVA microfibrils with radiopacity, zirconium dioxide ($ZrO_2$) and barium sulfate ($BaSO_4$) were added into s-PVA microfibrils during saponification. The computed tomography (CT) value indicating radiopacity reached up to over 1000 when the amount of $ZrO_2$ and $BaSO_4$ were 12 and 6 wt%, respectively.

Development of Multipurpose Seed Paper from Waste Paper ( I ) - Focused on functional chemicals behavior - (폐지를 이용한 기능성 육묘지의 제조(제1보) -기능성 약제의 거동-)

  • Park Soung Bae;Eom Tae Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.4 s.107
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    • pp.41-48
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    • 2004
  • To make a basepaper for multipurposed seed paper, old news print (ONP) and mixed office waste paper (MOW), modified and unmodified with a commercial cellulase, were investigated. Each handsheet was applied with different chemicals such as insecticides, germicides and herbicides. The interactions behaviors of chemicals used with base papers were evaluated by means of the contents of chemicals impregnation and dissolving behaviors in water and soil. The ONP and MOW treated with the cellulase had higher impregnation and dissolving capacities in both water and soil than untreated ONP and MOW. However, the modified ONP showed lower impregnation and dissolving capacities compared to the modified MOW. The content of impregnation of chemicals would be affected with the degree of microfibrils produced by the modification treatment. Otherwise, dissolving capacities of chemicals depend on the affinity of the residual lignin in the paper.

Use of Modern Microscopes in Analysing Fiber and Paper Properties (II)-New Aspect in Fibrillation of Pulp Fibers during Refining-

  • Kim, Chul-Hwan;Keigh R. Wadhams
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.3
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    • pp.60-67
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    • 1999
  • The CLSM and the image analysis technique enhanced observation of fiber wall fibrillation occurred in both the outer and the fiber wall surfaces during refining by non-destructive techniques. In the early stages of refining, it was well observed that a partial separation between the S1 and S2 layer in the secondary wall was made generating a space in the wet fiber walls . With further refining, it was clearly shown that the shear forces imparted by the refiner bar surfaces caused the S1 layer to become totally separated from the S2 layer as well as creating microfibrils. Furthermore, the fibrillation in the inner fiber wall surfaces could be due to the normal force (Fn) by refiner bars, friction force between a fiber and refiner bars (Fs) and inner friction force between fiber walls(fs). It was confirmed that the concept of fibrillation should be extended to fibrillation in the inner fiber wall surfaces as well as internal and external fribrillation.

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A Simpler Method to Estimate the Elastic Constant of Collagen-like Microfibril Using Voigt-Reuss Bounds (복합재료역학을 이용한 콜라겐 단백질 마이크로피브릴의 탄성율 예측 개선)

  • Yoon, Young-June;Bae, Cheol-Soo
    • Journal of Biomedical Engineering Research
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    • v.31 no.3
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    • pp.194-198
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    • 2010
  • The effective Young’s modulus of a microfibril surrounded by water may be simply calculated by using the upper (Voigt) and lower (Reuss) bounds, which is one way to estimate the Young’s modulus in composite materials. The Steered Molecular Dynamics (SMD) has been used for estimating the Young’s modulus of a microfibril surrounded by water. In this paper, the result estimated by the upper (Voigt) and lower (Reuss) bounds shows 9.2% to 21.8% discrepancy from the result estimated by SMD, but introducing “efficiency of reinforcement parameter” removes the discrepancy and shows good agreement with the result estimated by SMD. We found the best fit for the Young’s modulus against the size of the gap between microfibrils. Also the steps using these bounds are much simpler than SMD.

The interation between surfactants and keratinous tissues (계면활성제가 케라틴조직에 미치는 영향)

  • Breuer, M.M.
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.7 no.1
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    • pp.53-76
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    • 1979
  • During cosmetic treatments, SURFACTANTS penetrate into KERATINOUS TISSUES (hair, skin and nails). Whereas some of these surfactant molecules migrate to the vital tissues, a considerable fraction remains bound to the keratin. The extent of binding depends both on the nature of the head group and the length of the hydrophobic tail of the detergent molecules. In addition to entering the amorphous region of the keratin, some of the detergents also penetrate into the crystalline microfibrils and change their structures affecting their tensile properties. Owing to an uneven distribution of detergent molecules in the tissues, an anisotropy of the elastic moduli will occur, resulting in considerable internal stresses which, in rum, might lead to a deterioration of hair, skin and nails. The chemical behavior of keratins is also influenced by the presence of absorbed detergent in their structures. Depending on the detergents and the conditions, these effects can be either protective or detrimental. The deposition of detergent molecules into keratin can be enhanced or diminished by the inclusion of appropriate ingredients into the product formulae.

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Ultrastructure of Cryptococcus neoformans in the Skin Tissue (조직내 Cryptococcus neoformans의 전자현미경적 관찰)

  • Seo, Young-Hoon;Kwon, Tae-Jung;Kim, Chung-Sook
    • Applied Microscopy
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    • v.12 no.1
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    • pp.49-56
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    • 1982
  • A case of systemic cryptococcosis developed in 4 year old boy was described and illustrated by light and electron microscope. Light microscopically, the upper dermis of the skin showed chronic nonspecific inflammation with numerous spherical spores surrounded by a clear halo created by the wide gelatinous capsule. Ultrastructurally, the C. neoformans showed the wide capsule containing microfibrils that appeared to radiate from the cell wall and to coil and interwine in various directions. The cell was uninucleate with a single nucleolus. Along the inner nuclear envelope, numerous small vesicles were present. In addition, C. neoformans presented membranous organelles derived from the plasma membrane and comparable to bacterial mesosomes.

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Ultrastructure of Wood Cell Wall Tracheids - The Structure of Spiral Thickenings in Compression Wood - (목재세포벽(木材細胞壁)의 미세구조(微細構造)에 관한 연구(硏究) - Compression wood의 나선비후(螺旋肥厚)의 구조(構造) -)

  • Lee, Won-Yong
    • Journal of the Korean Wood Science and Technology
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    • v.9 no.1
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    • pp.1-12
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    • 1981
  • The structure of spiral thickenings, particulary the appearance, arrangement and orientation of thickenings in compression wood of Torreya nucifera, were studied in detail by light and polarizing microscope, scanning and transmission electron microscope. The results obtained are as follows: (1) Using the inclined sections at an angle of 45 degrees to the fiber axis, it seems that we can not only observe the more accurate transverse view of the thickenings but also investigate the formation of their thickenings. (2) Generally 2-4 pieces of thickenings are projected to the cell lumen as nipple-like appearance in transverse section and are as frequent, well developed, forming pair and have the rope-like appearance in radial surface. (3) The secondary wall of early wood is composed of 3 layers (S1, S2, S3) and orientation of thickening appears S helix but that of late wood is of 2 layers (S1, S2) and that orientation shows Z helix. Above two regions are demaracted at several tracheid cells from the growth ring boundary. (4) Orientation of thickening seems to be a element showing the characteristics of compression wood in Torreya nucifera. (5) It believes that the thickenings of compression wood are integral part of the S3 in early wood tracheids and of the S2 in late wood and have the same orientations as the inner-most microfibrils in these layers. (6) Thickening and cavities seem to be not formed together in a secondary cell wall of same tracheids.

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Micro-Heatsink Fabricated by Electroless Plating (무전해 도금으로 제조한 마이크로 히트싱크)

  • An Hyun Jin;Son Won Il;Hong Joo Hee;Hong Jae-Min
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.2 s.31
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    • pp.11-16
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    • 2004
  • Electronic devices are getting smaller due to integration of electronic chip, and heat generated in electronic devices can cause loss of performance and/or reliability of the devices. In this research, metals such as gold, nickel and copper are plated onto a porous membrane by electroless plating method to make an efficient micro-heatsinks. Electroless plating includes sensitization and activation steps in pre-treatment steps. A polycarbonate(PC) membrane was sensitizied, activated and deposited in each metal solution for plating. Among manufactured microfibrils, heat transfer and radiation properties of Ni-microfibril with high surface area were more effective than those of $Au^-$ and Cu-microfibril.

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Ultrastructural and Cytochemical Studies on Root Hair Cells of Ginseng(Panax ginseng C.A. Meyer) (인삼(人蔘)(Panax ginseng C.A Meyer) 근모세포(根毛細胞)의 미세구조(微細構造) 및 (세포화학적)細胞化學的 연구(硏究))

  • Jeong, B.K.;Kim, W.K.
    • Applied Microscopy
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    • v.15 no.2
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    • pp.69-79
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    • 1985
  • Ultrastructural and cytochemical studies of the root hair cell and the trichoblast were undertaken with light and electron microscopes to clarify the type of root hair, fine structure and the activities of acid phosphatase and ATPase. The root hair was differentiated from the middle portion of the cell, and perpendicularly to the long axis of the cell. Consequently, the type of root hair comes under the panicoid type. In the trichoblast, nucleus and cytoplasm are located in the vicinity of cortex. On the contrary, after the root hair is formed, they migrate to the apical region of the root hair, and the basal region of the root hair is filled with numerous vacuoles. Cell walls of actively growing root hairs are subdivided into two layers on the basis of the arrangement of cellulose microfibrils. New cell wall of the root hair is presumptively formed from Golgi complex-derived vesicles. Activity of acid phosphatase appeared on tonoplast, plasma membrane, and nuclear envelope, whereas ATPase activity appeared on the plasma membrane, heterochromatin, and mitochondrial cristae.

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Cell Biological Studies on Growth and Development Effect of$Ca^{2+}$ and polyamine of $\beta-glucan$synthetase activity in carrot root protoplast (생체생장에 관한 세포생물학적 연구 당근 뿌리의 원형질체에서 polyamine과 $Ca^{2+}$$\beta-glucan$ synthetase 활성도에 미치는 영향)

  • 이순희
    • Journal of Plant Biology
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    • v.30 no.3
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    • pp.173-179
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    • 1987
  • The effect of polyamine, Ca2+ and calmodulin on GS ($\beta$-glucan synthetase) activity was studied in Daucus carota root. The Ca2+ is shown to have no effect on the GS activity whereas the GS II activity is increased in response to increase in concentration of the Ca2+. When the protoplasts are cultured, for 4 days, the GS II activity increases as a tunction of time and reachs a maximum after 3 days at a time when the network of cellulose microfibrils is known to be synthesized. The effect of the Ca2+ and 1mM spermine on the GS II activity turns out to be synergistic, especially more synergistic at lower concentration of the Ca2+. The GS II activity seems to be enhanced by the Ca2+. The GS II activity in the protoplast treated by the calcium channel blocker, verapamil, turns out to be lower than that of the control. Cumulative results suggest that the Ca2+ stimulates the cell wall regeneration via enhancement of the GS II activity responsible for synthesizing the cell wall component throught synergistic effect with spermine.

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