• Korean Chemical Engineering Research
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• v.57 no.2
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• pp.185-197
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• 2019

Deactivation of porous photocatalytic materials was studied using three types of microstructured particles: macroporous titania particles, titania microspheres, and porous silica microspheres containing CNTs and $TiO_2$ nanoparticles. All particles were synthesized by emulsion-assisted self-assembly using micron-sized droplets as micro-reactors. During repeated cycles of the photocatalytic decomposition reaction, the non-dimensionalized initial rate constants (a) were estimated as a function of UV irradiation time (t) from experimental kinetics data, and the results were plotted for a regression according to the exponentially decaying equation, $a=a_0\;{\exp}(-k_dt)$. The retardation constant ($k_d$) was then compared for macroporous titania microparticles with different pore diameters to examine the effect of pore size on photocatalytic deactivation. Nonporous or larger macropores resulted in smaller values of the deactivation constant, indicating that the adsorption of organic materials during the photocatalytic decomposition reaction hinders the generation of active radicals from the titania surface. A similar approach was adopted to evaluate the activation constant of porous silica particles containing CNT and $TiO_2$ nanoparticles to compare the deactivation during recycling of the photocatalyst. As the amount of CNTs increased, the deactivation constant decreased, indicating that the conductive CNTs enhanced the generation of active radicals in the aqueous medium during photocatalytic oxidation.

• Journal of Environmental Science International
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• v.20 no.6
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• pp.729-736
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• 2011

This work is to compare the experiment results by a continuous fixed-bed adsorption of water vapor, acetone vapor, and toluene vapor on zeolite 13X (SAU) and silica-alumina (SAK). SAU and SAK have very different pore structure but similar composition as inorganic adsorbent. The relationship between the equilibrium adsorption capacity and specific pore size range were studied. Adsorption of water vapor was more suitable on SAU than SAK because SAU has relatively more developed pores around $5\;\AA$ than SAK in the pore range of $10\sim100\;\AA$. Adsorption of acetone vapor was more suitable on SAK than SAU because SAK has relatively more developed pores around $5\sim10\;\AA$ than SAK in the pore range of less than $10\;\AA$. Adsorption of toluene vapor was more suitable on SAK than SAU because SAK has relatively more developed pores in the pore range of $10\sim100\;\AA$ than SAK. Adsorption capacity of the adsorbent was closely related to the surface area generated in the specific pore size region. But it was difficult to distinguish the relationships between adsorption capacity and micro area, and the external surface area of adsorbent.

• The Journal of Advanced Prosthodontics
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• v.12 no.5
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• pp.291-298
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• 2020

PURPOSE. The aim of this study is to evaluate the influence of repeated surface treatments on wettability and surface roughness for zirconia surface and bond strength of zirconia-based ceramics to resin cement. MATERIALS AND METHODS. Seventy blocks (10 × 10 × 3 mm) of zirconia-based ceramics were fabricated and divided into two groups according to the surface treatments: (A) 110 ㎛ Al₂O₃ airborne-particle abrasion and (R) 110 ㎛ silica modified Al₂O₃ airborne-particle abrasion. At stage 2, each group was subdivided into 5 groups according to the surface retreatments: (a) 110 ㎛ Al₂O₃ airborne-particle abrasion, (r) 110 ㎛ silica modified Al₂O₃ airborne-particle abrasion, (D) diamond bur, (Da) diamond bur + 110 ㎛ Al₂O₃ airborne-particle abrasion, and (Dr) diamond bur + 110 ㎛ silica modified Al₂O₃ airborne-particle abrasion. Cylinders of self-adhesive resin cement were cemented onto each treated ceramic surface and subjected to micro-shear bond strength test. Additional specimens were prepared for roughness and wettability analyses. The data were subjected to t-test and One-way ANOVA followed by Tukey's post hoc test (α=.05). RESULTS. At stage 1, group R presented higher bond strength values than group A (P=.000). There was a statistically significant increase of bond strength at stage 2 for group A (P=.003). The diamond bur influenced the surface roughness, increasing the values (P=.023). Group R provided better wettability. Regardless of the applied surface treatment, most of failures were adhesive. CONCLUSION. The combination of application and reapplication of Rocatec Plus showed the best results of bond strength. Surface retreatment and recementation might be an indicated clinical strategy.

• Journal of the Korean Ceramic Society
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• v.44 no.9
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• pp.502-509
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• 2007

This paper investigated how Fine Fly Ash (FFA) with $14,000\;cm^2/g$ of Fineness affects the micro structure and material properties of High-Performance Concrete (HPC) before and after hardening from Material Test of HPC and Cement Paste. FFA is applied as a substitute of Silica Fume which is used necessarily in producing HPC. As a Material Test results, 5% FFA series specimen shows the lower fluidity than SF series specimen. When, however, the Fluidity of 10% FFA series specimen is increased reversely to the similar value of SF series specimen. The Porosity of FFA series specimen of 3 day age is displayed to $21{\sim}24%$, which is higher than $19{\sim}20%$ porosity of SF series specimen, while that of 28 day age is reached to $8{\sim}9%$, which is improved compared with 10% fo SF series specimen. It can be thought that FFA has better influence on the porosity of HPC in case of long term age. The Compressive strength of FFA series specimen shows the similar result with the property of porosity. The compressive strength of 28 day age FFA series specimen is $98{\sim}106%$ of SF series specimen and 107% of plain specimen to reveal better strength development.

• Korean Journal of Materials Research
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• v.23 no.1
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• pp.53-58
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• 2013

Superhydrophobic $SiO_2$ layers with a micro-nano hierarchical surface structure were prepared. $SiO_2$ layers deposited via an electrospray method combined with a sol-gel chemical route were rough on the microscale. Au particles were decorated on the surface of the microscale-rough $SiO_2$ layers by use of the photo-reduction process with different intensities ($0.11-1.9mW/cm^2$) and illumination times (60-240 sec) of ultraviolet light. With the aid of nanoscale Au nanoparticles, this consequently resulted in a micro-nano hierarchical surface structure. Subsequent fluorination treatment with a solution containing trichloro(1H,2H,2H,2H-perfluorooctyl)silane fluorinated the hierarchical $SiO_2$ layers. The change in surface roughness factor was in good agreement with that observed for the water contact angle, where the surface roughness factor developed as a measure needed to evaluate the degree of surface roughness. The resulting $SiO_2$ layers revealed excellent repellency toward various liquid droplets with different surface tensions ranging from 46 to 72.3 mN/m. Especially, the micro-nano hierarchical surface created at an illumination intensity of $0.11mW/cm^2$ and illumination time of 60 sec showed the largest water contact angle of $170^{\circ}$. Based on the Cassie-Baxter and Young-Dupre equations, the surface fraction and work of adhesion for the micronano hierarchical $SiO_2$ layers were evaluated. The work of adhesion was estimated to be less than $3{\times}10^{-3}N/m$ for all the liquid droplets. This exceptionally small work of adhesion is likely to be responsible for the strong repellency of the liquids to the micro-nano hierarchical $SiO_2$ layers.

• Journal of Ceramic Processing Research
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• v.13 no.spc2
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• pp.332-335
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• 2012

A molded transformer is maintenance-free, which makes it unnecessary to replace the insulating material, like in an oil-filled transformer, because the epoxy, which is a molded insulating resin, does not suffer variations in its insulating performance for heat cycles over a long time, as compared to insulating oil. In spite of these advantages, a molded transformer may still be accessed by the user, which is not good in regards to reliability or noise compared to the oil transformers. In particular, a distrust exists regarding reliability due to the long-term insulating performance. These properties have been studied in regards to the improvement of epoxy composites and molded transformer insulation. There have nevertheless been insufficient investigations into the insulation properties of epoxy composites. In this study, it is a researching of the epoxy for insulating material. In order to prepare the specimens, a main resin, a hardener, an accelerator, and a nano/micro filler were used. Varying amounts of TiO2 and ZnO nano fillers were added to the epoxy mixture along with a fixed amount of micro silica. This paper presents the DC insulation breakdown test, thermal expansion coefficient, and thermal conductivity results for the manufactured specimens. From these results, it has been found that the insulating performance of nano/micro epoxy composites is improved as compared to plain molded transformer insulation, and that nano/micro epoxy composites contribute to the reliability and compactness of molded transformers.

• KSBB Journal
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• v.24 no.5
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• pp.432-438
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• 2009

Here, we demonstrated simple nucleic acid, RNA, concentration method using polymer micro chip containing glass bead ($100\;{\mu}m$). Polymer micro chip was fabricated by PDMS ($1.5\;cm\;{\times}\;1.5\;cm$, $100\;{\mu}m$ in the height) including pillar structure ($160\;{\mu}m\;(I)\;{\times}\;80\;{\mu}m\;(w)\;{\times}\;100\;{\mu}m\;(h)$, gap size $50\;{\mu}m$) for blocking micro bead. RNA could be adsorbed on micro glass bead at low pH by hydrogen bonding whereas RNA was released at high pH by electrostatic force between silica surface and RNA. Amount of glass beads and flow rate were optimized in aspects of adsorption and desorption of RNA. Adsorption and desorption rate was measured with real time PCR. This concentrated RNA was applied to amplification micro chip in which NASBA (Nucleic Acid Sequence Based Amplification) was performed. As a result, E.coli O157 : H7 in the concentration of 10 c.f.u./10 mL was successfully detected by these serial processes (concentration and amplification) with polymer micro chips. It implies this simple concentration method using polymer micro chip can be directly applied to ultra sensitive method to measure viable bacteria and virus in clinical samples as well as environmental samples.

• Tribology and Lubricants
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• v.25 no.2
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• pp.86-95
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• 2009

Adhesion tests were carried out in order to investigate the effect of temperature on the adhesion behavior between a PMMA film and a fused silica lens in the micro scale. For the tests, a microtribometer system was specially designed and constructed. The pull-off forces on the PMMA film were measured under atmospheric condition as the temperature of the PMMA film was increased from 300 K to 443 K and decreased to 300 K. The contact area between the PMMA film and the lens was observed during the test. The adhesion behavior was changed with the change of the PMMA surface state as the temperature increased. In glassy state below 363 K, the pull-off force did not change with the increase of temperature. In rubbery state from 383 K to 413 K, the pull-off force increased greatly as the temperature increased. In addition, the area of contact was enlarged. In viscous state above 423 K, the fingering instability was observed in the area of contact when the PMMA film contacted with the lens. It was also found that the adhesion behavior can be varied with the thermal history of the PMMA film. The residual solvent in the PMMA film could emerge to the PMMA surface due to the heating and reduced the pull-off force.

• Laser Solutions
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• v.18 no.3
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• pp.14-19
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• 2015

A helical fabricating method using $CO_2$ laser was utilized for producing cone-shaped structure on a silica substrate. Output power and the number of scanning radiation were modified in order to control the structure. The experiment shows that the depth and width of cone-shape were increased with higher output power of the laser and the number of scanning. We demonstrate fabrication of multidirectional side-firing optical fiber with diameter of 440 um using the $CO_2$ laser fabrication technique.

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.377-382
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• 2014

Micro-/macroporous carbons (MMCs) were prepared using a hollow mesoporous silica capsule (HMSC) as a sacrificial hard template. The carbonization process after the infiltration of furfuryl alcohol into the template-free HMSC material afforded MMC materials in high yield. The hard template HMSC could be removed by HF etching without deteriorating the structure of MMC. The MMC materials were fully characterized by SEM, TEM, PXRD, XPS, and Raman spectroscopy. The replication processes were so successful that MMCs exhibited a hollow capsular structure with multimodal microporosity. Detailed textural properties of MMC materials were investigated by volumetric $N_2$ adsorption-desorption analysis at 77 K. To explore the gas sorption abilities of MMCs for other gases, $H_2$ and $CO_2$ sorption analyses were also performed at various temperatures. The multimodal MMC materials were found to be good sorbents for both $H_2$ and $CO_2$ at low pressure.