• Title/Summary/Keyword: micro-pore

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A Case Study on the Cause and Reinforcement of Railroad Facilities Settlement According to the Ground Excavation (지반굴착에 따른 철도시설물의 침하 원인 및 보강 사례연구)

  • Oh, Beyung-Sam
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.10
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    • pp.85-94
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    • 2012
  • Recent development trend of construction projects in the urban area is the efficient use of insufficient land, however caused to difficult construction conditions because of many adjacent structures. This paper presents the case study that analyzed the ground settlement of railroad structure for the double track railway project of Gyeongui line, adjacent to the high rise building under ground excavating for substructure work, considering interaction of soft ground characteristics. Field survey and measurement works were carried out during construction of station and excavation of high rise building, and field data were analyzed to find the source of settlement of platform and railway. In addition, the soil reinforcement and foundation restoration were performed using in-situ injection method, i.e., D-ROG(Digitalized Restoring On Grout) method which filled the pore of bottom and around of foundation with micro-cement.

Development of Cu-CeO2 Catalysts for Selective Oxidation of CO (일산화탄소의 선택적 산화반응을 위한 Cu-CeO2 촉매의 개발)

  • Jung, C.-R.;Han, J.;Yoon, S.P.;Nam, S.-W.;Lim, T.-H.;Hong, S.-A.;Lee, H.-I.
    • Clean Technology
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    • v.8 no.1
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    • pp.53-59
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    • 2002
  • $Cu-CeO_2$ catalysts were prepared by co-precipitation and liquid phase oxidation (CP-LPO) and the prepared catalysts were examined as selective oxidation of carbon monoxide catalysts for the application of fuel cell vehicles. The prepared $Cu-CeO_2$ catalysts showed high reaction activity, but it was hard to find the correlation between the amount of Cu loaded and the reaction activities. As increase of the amount of Cu loaded, the micro pore structure of the catalyst was changed. It is due to the formation of solid solution between Cu and $CeO_2$. During pretreatment, the catalyst formed the solid-solution of Cu-Ce-O, resulting in the improvement of catalytic activity.

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Preparation of Higher Reinforced PVDF Hollow Fiber Microfiltration Membrane (고강도 PVDF 중공사 정밀여과막 제조 특성)

  • Choi, R.S.;Park, H.H.
    • Membrane Journal
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    • v.20 no.4
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    • pp.320-325
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    • 2010
  • This paper was carried out to study the preparation condition and the permeation flux of reinforced poly(vinylidene fluoride) (PVDF) hollow fiber microfiltration (MF) membrane with the solvent, additive, second miscible polymer, and preparation condition used poly(vinylidene fluoride) (PVDF) such as a material with the excellent chemical stability and the milder preparation condition. The performance of the reinforced MF membrane prepared obtained the average $0.3{\mu}m$ pore size, $42kg_f/cm^2$ tensile strength, and the high water flux of 600 LMH. The change of membrane performance with various additives was considerably affected on the water flux and rejection. For hydrophilic modification of hydrophobic PVDF MF membrane, the MF membrane might be prepared with a prefer water flux and rejection by addition of hydrophilic poly(methyl methacrylate) (PMMA).

Preparation of Silica/collagen Microsphere Composit Doped with Silver Nanoparticles (은 나노입자를 담지한 collagen/silica microsphere 복합체의 제조)

  • Jung, Hyo Jung;Kim, Yeon Bum;Chang, Yoon Ho
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.722-726
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    • 2008
  • Silica microsphere is a world leading innovative material used in adsorbent packing materials in HPLC technology. The application of microsphere lies in the ability to the surface modification of silica with the special materials such as polymers, metals and bio-active materials. Collagen is a major structural protein of connective tissues and has a good biocompatibility. In this study, we prepared the purified silica porous microsphere, having micro diameters in the range of a pore volume at least 50% by the aggregation procedure of colloidal silica with the polymerization method (PICA). The microspheres were modified by collagen hydrogel to improve the biocompatible properties for biomedical product. The silica/collagen microsphere composite doped with silver nanoparticles was prepared and investigated the capabilities of biomaterial application through the evaluation of the structure characteristics of the microsphere composit.

Micellar Enhanced Ceramic Microfiltration for Removal of Aqueous Ferrous Ion: Effect of Surfactant Concentration and $N_2$-back-flushing (용존 철(II) 제거를 위한 미셀형성 세라믹 정밀여과: 계면활성제 농도 및 질소 역세척의 영향)

  • Park, Jin-Yong;Kang, Sung-Gyu
    • Membrane Journal
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    • v.19 no.2
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    • pp.136-144
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    • 2009
  • In this study, sodium dedocyl sulfate (SDS), which was anionic surfactant, was added for forming micelles to remove ferrous ions that could be contained with a small amount in industrial water. Then aggregates were formed by adsorption or binding of ferrous ions on the surface of micelles, and then rejected by ceramic membranes to remove ferrous ions. Ferrous concentration was fixed at 1mM and SDS was changed as $0{\sim}10mM$ to investigate the effect of the anionic surfactant. As a result, rejection rate of ferrous was the highest to 88.97% at 6mM. And we used ELS (Electrophoretic Light Scattering Spectrometer) to investigate particle size distribution of micellar aggregates depending on SDS concentration. Then distribution of large aggregates was the highest at 6mM. And we investigated effects of $N_2$-back-flushing time (BT) during periodic $N_2$-back-flushing on ceramic membranes. Finally optimal $N_2$-BT for NCMT-723l (pore size $0.10{\mu}m$) membrane was 20 sec.

Corrosion Behavior of Dental Alloys Cast by Various Casting Methods (치과용 주조합금의 주조방법에 따른 부식거동)

  • Choe Han-Cheol;Ko Yeong-Mu
    • Journal of the Korean institute of surface engineering
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    • v.37 no.5
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    • pp.296-300
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    • 2004
  • The defects of partial denture frameworks are mainly shrinkage porosity, inclusions, micro-crack, particles from investment, and dendritic structure. In order to investigate a good casting condition of partial denture frameworks, the three casting alloys and casting methods were used and detected casting defects were analyzed by using electrochemical methods. Three casting alloys (63Co-27Cr-5.5Mo, 63Ni-16Cr, 63Co-30Cr-5Mo) were prepared for fabricating partial denture frameworks with various casting methods; centrifugal casting (Kerr, USA), high frequency induction casting (Jelenko Eagle, USA), vacuum pressure casting (Bego, Germany). The casting temperature was $1,380^{\circ}C$ (63Co-27Cr-5.5Mo and 63Ni-16Cr) and $1,420^{\circ}C$ (63Co-30Cr-5Mo). The casting morphologies were analyzed using FE-SEM and EDX. The corrosion test of the dendritic structure was performed through potentiodynamic method in 0.9% NaCl solutions at $36.5^{\circ}C$ and corrosion surface was observed using SEM. The defects of partial denture frameworks improved in the order of centrifugal casting, high frequency induction casting, and vacuum pressure casting method, especially, pore defects were found at part of clasp in the case of centrifugal casting method. The structure of casting showed dendritic structure for three casting alloys. In the 63Co-27Cr-5.5Mo and 63Co-30Cr-5Mo, $\alpha$-Co and $\varepsilon$-Co phases were identified at matrix and $${\gamma}$-Ni_2$Cr second phase were shown in 63Ni-16Cr. Also, the corrosion resistance of cast structure increased in the order of vacuum pressure casting, high frequency induction casting, and centrifugal casting method.

Assessing the anion type effect on the hydro-mechanical properties of smectite from macro and micro-structure aspects

  • Goodarzi, Amir R.;Akbari, Hamid R.
    • Geomechanics and Engineering
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    • v.7 no.2
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    • pp.183-200
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    • 2014
  • The expansivity of clayey soils is a complicated phenomenon which may affect the stability of geotechnical structures and geo-environmental projects. In all common factors for the monitoring of soil expansion, less attention is given to anion type of pore space solutions. Therefore, this paper is concerned with the impact of various concentrations of different inorganic salts including NaCl, $Na_2SO_4$, and $Na_2CO_3$ on the macro and microstructure behavior of the expandable smectite clay. Comparison of the responses of the smectite/NaCl and smectite/$Na_2SO_4$ mixtures indicates that the effect of anion valance on the soil engineering properties is not very pronounced, regardless of the electrolyte concentration. However, at presence of carbonate as potential determining ions (PDIs) the swelling power increases up to 1.5 times compared to sulfate or chloride ions. The samples with $Na_2CO_3$ are also more deformable and show lower osmotic compressibility than the other mixtures. This demonstrates that the barrier performance of smectite greatly decreases in case of anions with the non-specific adsorption (e.g., $Cl^-$ and $SO{_4}^{2-}$) as the salinity of solution increases. Based on the results of the X-ray diffraction and sedimentation tests, the high soil volumetric changes upon exposure to carbonate is attributed to an increase in the repulsive forces between smectite basic unit layers due to the PDI effect of $CO{_3}^{2-}$ and increasing the pH level which enhance the buffering capacity of smectite. The study concluded that the nature of anion through its influence on the re-arrangement of soil microstructure and osmotic phenomena governs the hydro-mechanical parameters of expansive clays. It seems not coinciding with the double layer theory of the Gouy-Chapman double layer model.

Case report: Mass mortality of olive flounder (Paralichthys olivaceus) caused by acute gas bubble disease

  • Lee, Yoonhang;Kim, Nameun;Lee, Ju-yeop;Kang, Hyoyeong;Sung, Minji;Yu, Young-Bin;Kim, Kyunghoi;Je, Jae-Young;Kim, Hyun-Woo;Kang, Ju-Chan;Kim, Do-Hyung
    • Journal of fish pathology
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    • v.34 no.2
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    • pp.255-259
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    • 2021
  • This is the first report describing acute mass mortality occurred in juvenile olive flounder (Paralichthys olivaceus) caused by gas bubble disease (GBD). A total of 610 fish (average weight = 35 g), which were more than half of the fish acclimated at 17℃ in an aquarium, were killed within two days of acclimation. The dead and moribund fish showed excessively opened opercula and mouths, and occasionally, severe exophthalmia. Through microscopic observation, numerous gas emboli were found in the gills of the dead and live fish, while the fish were not infected with any microbial pathogens. The dissolved oxygen (DO) saturation level of the rearing water and seawater nearby the facility reached 145% and 286%, respectively, whereas other water quality parameters (such as salinity, pH, and chemical oxygen demand) were normal. The extreme saturation rate of seawater in the shore nearby seemed to be due to an enormous algal bloom that occurred there. Through molecular identification based on 18S rDNA sequences, the most dominant algal species was most closely related to Ulva californica (99.87% sequence identity) followed by U. prolifera, U. linza, and U. curvata (99.81%). Therefore, it can be concluded that supersaturated seawater due to mass algal bloom caused gas bubble disease in the olive flounder, leading to mass mortality. After technical adjustment, such as increased aeration, lowered water circulation rate, and inlet water filtration using micro-pore carbon filters, the DO level became normal, no further mortality occurred and the status of the fish was stabilized.

Fabrication of Micro-Porous Membrane via a Solution Spreading Phase Inversion Method (용액 퍼짐 상분리법을 통한 마이크로 기공 분리막 제조)

  • Choi, Ook;Park, Chul Ho
    • Membrane Journal
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    • v.29 no.2
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    • pp.105-110
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    • 2019
  • Porous membranes are widely used in industry for removing particulate matter. Unlike conventional porous membrane fabrication methods, the solution spreading phase separation method can form pores very simply. The first step is to wet the mesh with the support layer, then to let the polysulfone solution flow into a solvent without water. The solvent is readily vaporized and the polysulfone is made into a thin film. When the polysulfone solution is mixed with water to form pores, the pore size can be adjusted according to the concentration ratio of the polysulfone solution. The thickness of the membrane is easily controlled by the concentration of the solution. The porous separator has the formation of meshes intact and is very useful for forming a three-dimensional structure. The solution spreading phase separation method proposed in this study is characterized by its high cost competitiveness compared with conventional membranes due to its low production cost and easy process control.

Material Properties of Repair Mortar Considering Accelerator Type and Curing Conditions (급결제 종류 및 양생조건을 고려한 보수용 모르타르의 재료특성)

  • Shin, Seung-Bong;Kim, Gyu-Yong;Nam, Jeong-Soo;Shin, Kyoung-Su;Lee, Bo-Kyeong
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.4
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    • pp.299-306
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    • 2019
  • In general, repair mortar is used to rehabilitate underground communities, but difficulties are encountered in the execution of long-term construction due to spatial co-operatives. In this study, the engineering properties of repair mortar according to the curing condition and accelerator type were reviewed. The results showed that the aluminate, alkali-free and calcium-aluminate precipitates in the water curing conditions showed higher compressive strength at the beginning of age than mortar specimens under air curing conditions, and increased. Especially in CA and AF test specimen with cement mineral quick setting, a large amount of ettringite products were observed compared with AL, thus reducing the pore volume and increasing the strength of the compound by micro-filling effect were found.