• 제목/요약/키워드: micro-pore

검색결과 337건 처리시간 0.029초

Origins and Paleoceanographic Significance of Layered Diatom Ooze from Bransfield Strait in the Northern Antarctic Peninsula around 2.5 kyrs BP

  • Yoon, Ho-Il;Kim, Yea-Dong;Park, Byong-Kwon;Kang, Cheon-Yun;Bae, Sung-Ho;Yoo, Kyu-Chul
    • Ocean and Polar Research
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    • 제24권3호
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    • pp.301-311
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    • 2002
  • We used diatom and porewater data of two piston cores from the central subbasin and one from the western subbasin in the Bransfield Strait in the northern Antarctic Peninsula to elucidate the depositional mechanism of the layered diatom ooze. The layered diatom ooze is characterized by an abundance of organic carbon, biogenic silica, sulfde sulfur, and lower porewater sulfate concentration. This lack of pore-water sulfate concentration in the diatom ooze interval may reflect development of reducing micro-environment in which bacterially mediated sulfate reduction occurred. The negative relationship between the total organic carbon and sulfate contents, however, indicates that sulfate reduction was partly taking place but does not control organic carbon preservation in this unit. Rather, well-preserved Chaetoceros resting spores in the layered diatom ooze indicate a rapid sedimentation of the diatom as a result of repetitive iceedge blooms on the Bransfield shelf during the cold period (around 2500 yrs BP) when the permanent seaice existed on the shelf, During this period, it is expected that the downslope-flowing cold and dense water was also formed on the Bransfield shelf as a result of sea ice formation, playing an important role for the formation of layered diatom ooze in the Bransfield subbasins.

Triacetin이 탄소복합 필터의 연기성분 흡착능에 미치는 영향

  • 김정열;신창호;김종열
    • 한국연초학회지
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    • 제20권2호
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    • pp.205-209
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    • 1998
  • This study was conducted to evaluate the effect of triacetin(TA) treatment during manufacturing carbon dual filter for the adsorption of cigarette smoke components by activated carbons. The measurements were carried out by separation of activated carbon from carbon dual filter, and the specific surface area analyzed. The specific surface area of activated carbon from the domestic cigarette filter and from the foreign cigarette filter by degassing at 9$0^{\circ}C$ was 163$\pm$32$m^2$/g, and 16.6$\pm$1.9$m^2$/g, respectively. Those values were very lower than that of degassing at 35$0^{\circ}C$ (Domestic brand: 952$\pm$30$m^2$/g, and Foreign brand: 847$\pm$73$m^2$/g). By comparing the adsorption capacity of acetone and benzene with and without triacetin treated activated carbon, there was a 20% reduction of adsorption capacity by 5% triacetin treatment. Also, from the cilia toxicity test with carbon dual filter treated 0 % TA and 8 % TA, the cilia survival time was 706$\pm$74sec. and 603$\pm$64sec. for 0% TA and 8% TA, respectively. The delivery rate of vapour phase of cigarette smoke, which consists of main components of cilia toxicity, was higher at 8% TA filter than 0 % TA filter. Our results indicate that the treated TA covered the micro-pore of activated carbon, and then reduced specific surface area, finally, decreased the adsorption of vapour phase from cigarette smoke.

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중력여과 방식의 MBR을 이용한 하수처리에서 HRT 변화에 따른 EPS의 거동과 막오염에 대한 영향 (Behavior and Influence of EPS on Membrane Fouling by Changing of HRT in MBR with Gravitational Filtration)

  • 김시원;곽성진;이의신;홍승모;민경석
    • 한국물환경학회지
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    • 제22권5호
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    • pp.865-870
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    • 2006
  • The behavior and influence of EPS on membrane fouling by changing of hydraulic retention time was investigated, using lab. scale submerged membrane bio-reactor, which was operated with gravitational filtration and fed supernatant of primary sedimentation in waste water treatment plant as influent. The membrane was adopted micro-filter of polyethylene hollow fiber. EPS was analysed as polysaccharides and protein especially, into soluble and bound EPS separately. The concentration of soluble EPS was increased at short HRT, then membrane fouling was rapidly progressed and flux was depressed. The most of EPS clogged membrane pore were polysaccharides, while protein was important parameter affected on membrane fouling because of it's more accumulating in the more term operating.

화상분석기와 CLSM을 이용한 침.활엽수 섬유의 배합비에 따른 인쇄화상 분석 (Analysis of Printed Image Depending on Mixing Ratios of Softwood and Hardwood fibers Using Image Analyzer and CLSM)

  • 이장호;박종문
    • 펄프종이기술
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    • 제34권3호
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    • pp.25-31
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    • 2002
  • The purpose of this study was to analyze how the fiber properties and mixing ratio of softwood and hardwood pulp affect on roundness of printed image. Softwood pulp and hardwood pulp were refined to 400 and 600ml CSF by Valley beater and handsheets of 70 g/$m^2$ basis weight were made at different mixing ratios of hardwood and softwood pulp. The roundness, dot area, and shape of the printed dot were measured by Image Analyzer. The depths and shapes of the acridine orange penetration into paper were measured by CLSM. With higher mixing ratio of hardwood pulp, the paper showed higher air-permeability and better formation, especially at lower freeness. The roundness of the printed image became better and the dot size became smaller when the amount of hardwood pulp increased. Penetration depth of acridine orange by CLSM became greater and roundness increased to real circle when the amount of hardwood pulp increased. It was thought that higher mixing ratio of hardwood fibers resulted in efficient penetration by better formation with uniform micro-pore distribution and it increased roundness. It was thought that fiber properties and mixing ratio affected the structure of paper and the shape of the printed dot. This study showed that the measurement of depth of the liquid penetration into paper without destruction and contact was feasible. Moreover, this method showed that the shape of the liquid penetration was measurable.

Development of New Reverse Micellar Microencapsulation Technique to Load Water-Soluble Drug into PLGA Microspheres

  • Kim Hyun Joo;Cho Mi Hyun;Sah Hong Kee
    • Archives of Pharmacal Research
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    • 제28권3호
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    • pp.370-375
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    • 2005
  • The objective of this study was to develop a new reverse micelle-based microencapsulation technique to load tetracycline hydrochloride into PLGA microspheres. To do so, a reverse micellar system was formulated to dissolve tetracycline hydrochloride and water in ethyl formate with the aid of cetyltrimethylammonium bromide. The resultant micellar solution was used to dissolve 0.3 to 0.75 g of PLGA, and microspheres were prepared following a modified solvent quenching technique. As a control experiment, the drug was encapsulated into PLGA microspheres via a conventional methylene chloride-based emulsion procedure. The micro­spheres were then characterized with regard to drug loading efficiency, their size distribution and morphology. The reverse micellar procedure led to the formation of free-flowing, spherical microspheres with the size mode of 88 ~m. When PLGA microspheres were prepared follow­ing the conventional methylene chloride-based procedure, most of tetracycline hydrochloride leached to the aqueous external phase: A maximal loading efficiency observed our experimental conditions was below $5\%$. Their surfaces had numerous pores, while their internal architecture was honey-combed. In sharp contrast, the new reverse micellar encapsulation technique permitted the attainment of a maximal loading efficiency of 63.19 $\pm$$0.64\%$. Also, the microspheres had smooth and pore-free surfaces, and hollow cavities were absent from their internal matrices. The results of this study demonstrated that PLGA microspheres could be successfully prepared following the new reverse micellar encapsulation technique.

LIFE-SPAN SIMULATION AND DESIGN APPROACH FOR REINFORCED CONCRETE STRUCTURES

  • An, Xuehui;Maekawa, Koichi;Ishida, Tetsuya
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 2007년도 정기 학술대회 논문집
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    • pp.3-17
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    • 2007
  • This paper provides an introduction to life-span simulation and numerical approach to support the performance design processes of reinforced concrete structures. An integrated computational system is proposed for life-span simulation of reinforced concrete. Conservation of moisture, carbon dioxide, oxygen, chloride, calcium and momentum is solved with hydration, carbonation, corrosion, ion dissolution. damage evolution and their thermodynamic/mechanical equilibrium. Coupled analysis of mass transport and damage mechanics associated with steel corrosion is presented for structural performance assessment of reinforced concrete. Multi-scale modeling of micro-pore formation and transport phenomena of moisture and ions are mutually linked for predicting the corrosion of reinforcement and volumetric changes. The interaction of crack propagation with corroded gel migration can also be simulated. Two finite element codes. multi-chemo physical simulation code (DuCOM) and nonlinear dynamic code of structural reinforced concrete (COM3) were combined together to form the integrated simulation system. This computational system was verified by the laboratory scale and large scale experiments of damaged reinforced concrete members under static loads, and has been applied to safety and serviceability assessment of existing structures. Based on the damage details predicted by the nonlinear finite element analytical system, the life-span-cost of RC structures including the original construction costs and the repairing costs for possible damage during the service life can be evaluated for design purpose.

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W CMP 공정에서의 연마패드표면 안정화 상태와 그 개선 (Stability and Improvement of Polishing Pad in W CMP)

  • 박재홍;키노시타 마사하루;요시다 코이치;신이치 마츠무라;정해도
    • 한국전기전자재료학회논문지
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    • 제20권12호
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    • pp.1027-1033
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    • 2007
  • In this research, the polishing pad for W CMP has been analyzed to understand stabilization of polishing performance. For stabilization of process, the polishing pad condition is one of important factors. The polishing pad plays a key role in polishing process, because it contact with reacted surface of wafer[1]. The physical property of pad surface is ruled by conditioning tool which makes roughness and profile of pad surface. Pad surface affects on polishing performance such as RR(Removal Rate) and uniformity in CMP. The stabilized pad surface has stable roughness. And its surface has high level of wettability which can increase the probability of abrasive adhesion on pad. The result of this research is that the reduction of break-in and dummy polishing process were achieved by artificial machining to make stable pad surface. In this research, urethane polishing pad which is named IC pad(Nitta-Haas Inc.) and has micro pore structure, is studied. Because, this type of pad is the most conventional type.

Simple approach to calculate chloride diffusivity of concrete considering carbonation

  • Yoon, In-Seok
    • Computers and Concrete
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    • 제6권1호
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    • pp.1-18
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    • 2009
  • Chloride diffusivity of concrete is a crucial material parameter for service life determination and durability designing of marine concrete. Many research works on this issue have been conducted, varying from empirical solutions obtained experimentally to image analysis, based on multi-scale modeling. One of the simple approaches is to express the chloride diffusivity of concrete by a multi-factor function, however, the influences of various factors on the chloride diffusivity are ambiguous. Furthermore, the majority of these research works have not dealt with the carbonation process of concrete, although this process affects the chloride diffusivity of concrete significantly. The purpose of this study is to establish a simple approach to calculate the chloride diffusivity of (non)carbonated concrete. The chloride diffusivity of concrete should be defined, based on engineering and scientific knowledge of cement and concrete materials. In this paper, a lot of parameters affecting the chloride diffusivity, such as the diffusivity in pore solution, tortuosity, micro-structural properties of hardened cement paste, volumetric portion of aggregate, are taken into consideration in the calculation of the chloride diffusivity of noncarbonated concrete. For carbonated concrete, reduced porosity due to carbonation is calculated and used for calculating the chloride diffusivity. The results are compared with experimental data and previous research works.

화학적 발포와 레이저 하이브리드 공정을 이용한 마이크로 셀루러 폴리이미드 필름 제조 (Fabrication of Microcellular Polyimide Film using Hybrid Laser Process with Chemical Blowing Agents)

  • 마용원;강문석;오재용;신보성
    • 한국기계가공학회지
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    • 제12권6호
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    • pp.17-22
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    • 2013
  • Recently, microcellular polymer films have been widely used as absorbents, support cells, and sensors in the industrial fields of IT, NT, BT, and ST. The conventional fabrication methods of microcellular polymer films are not only more complicated than those of non-microcellular polymer films, but also require a longer production time. In this paper, we propose a new hybrid fabrication method for microcellular polymer films; films can be rapidly made using UV laser processing with chemical blowing agents. The experimental results show that the number of the micropores increased with respect to the laser fluence and the concentration of the chemical blowing agents.

Evaluation of homogenized thermal conductivities of imperfect carbon-carbon textile composites using the Mori-Tanaka method

  • Vorel, Jan;Sejnoha, Michal
    • Structural Engineering and Mechanics
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    • 제33권4호
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    • pp.429-446
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    • 2009
  • Three-scale homogenization procedure is proposed in this paper to provide estimates of the effective thermal conductivities of porous carbon-carbon textile composites. On each scale - the level of fiber tow (micro-scale), the level of yarns (meso-scale) and the level of laminate (macro-scale) - a two step homogenization procedure based on the Mori-Tanaka averaging scheme is adopted. This involves evaluation of the effective properties first in the absence of pores. In the next step, an ellipsoidal pore is introduced into a new, generally orthotropic, matrix to make provision for the presence of crimp voids and transverse and delamination cracks resulting from the thermal transformation of a polymeric precursor into the carbon matrix. Other sources of imperfections also attributed to the manufacturing processes, including non-uniform texture of the reinforcements, are taken into consideration through the histograms of inclination angles measured along the fiber tow path together with a particular shape of the equivalent ellipsoidal inclusion proposed already in Sko ek (1998). The analysis shows that a reasonable agreement of the numerical predictions with experimental measurements can be achieved.