• Korean Chemical Engineering Research
• /
• v.47 no.3
• /
• pp.332-336
• /
• 2009

When NCAs(non-conductive adhesives) are used for adhesion of micro-electronic devices, they often show problems such as delamination and cracking, due to the differences of CTE(coefficients of thermal expansion) between NCAs and substrates. Additions of inorganic particles or flexibilizers have been performed to solve those problems. The effects of silica addition on thermal/mechanical properties of amino modified siloxane(AMS)/silica/epoxy-nanocomposites were examined. The silica was treated by 3-glycidoxypropyltrimethoxysilane(GPTMS) for better compatibility between silica and epoxy matrix. AMS/silica/epoxy-nanocomposites filled with various amounts of AMS(1 and 3 phr) and various amounts of silica(3, 5 and 7 phr) were prepared. And Tg, moduli and CTE of nanocomposites were analyzed. Tg of AMS/Aerosil(non-modified silica)/epoxy-nanocomposites decreased from 125 to $118^{\circ}C$ with increasing Aerosil contents and moduli increased from 2,225 to 2,523 MPa with increasing Aerosil contents. Tg of AMS/M-silica (modified silica)/epoxy-nanocomposites decreased from 124 to $120^{\circ}C$ with increasing M-silica contents and moduli increased from 1,981 to 2,743 MPa with increasing M-silica contents. CTE of AMS/Aerosil/epoxy-nanocomposites and AMS/M-silica/epoxy-nanocomposites showed decreasing tendency regardless of the surface treatments.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.67 no.9
• /
• pp.1189-1196
• /
• 2018

7 type composites (40, 45, 50, 55, 60, 65, and 70 wt.%)were prepared for the environmentally friendly GIS Spacer. Five kinds of samples were prepared for optimization of the filler content ratio (MS: MA = 1: 9, 3: 7, 5: 5, 7: 3, 9: 1) of epoxy / microsilica and microalumina. As a result of evaluation of the partial discharge resistance characteristic, surface erosion is generally slowed down as the fill amount of micro silica is increased. Also, partial discharge resistance characteristics for the development of insulating materials with optimal mixing ratios of heterologous showed a higher partial resistance of discharge and a decrease in erosion, as the filler content ratio of micro silica was larger. In the future, various researches such as electrical, mechanical, and thermal studies will be needed to develop insulating materials that can commercialize power devices in environmentally friendly insulating gas.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.04a
• /
• pp.285-291
• /
• 1998

During recent years, the durability of concrete structures has been considered in concret practice and material research. To preserve the brittleness of concrete as well as energy absorption and impact resistance, amount of fiber usage has greatly increased in the field of public works. Ultra fine powder, silica fume, mixed into concrete, it reduce void of concrete structure. Especially, there's a great effect for strength improvement of concrete by initial pozzolanic reactions. For these reasons, if silica fume mixed into concrete, it decrease the total void by microfilter effect . Pozzolan reaction, between cement particle and silica powder, can elaborate the micro structure of matrix. And so, in this paper, we deal SFRC for the purpose of efficiently using of industrial by-products(silica fume). Also we performed the test for durability such as freeze-thaw resistance and accelerated carbonation of SFRC using silica fume.

• Structural Engineering and Mechanics
• /
• v.51 no.3
• /
• pp.403-412
• /
• 2014

In this paper, enhancement of corrosion and chloride resistance of high performance self compacting concrete (SCC) through incorporating nanosilica into the binder has been investigated. For this purpose, different mixtures were designed with different amounts of silica fume and nano silica admixtures. Different binder contents were also investigated to observe the binder content effect on the concrete properties. Corrosion behavior was evaluated by chloride penetration and resitivity tests. Water absorption and capillary absorption were also measured as other durability-related properties. The results showed that water absorption, capillary absorption and Cl ion percentage decreased rather significantly in the mixtures containing admixtures especially blend of silica fume and nano silica. By addition of the admixtures, resistivity of the SCC mixtures increased which can lead to reduction of corrosion probability.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2004.11a
• /
• pp.341-344
• /
• 2004

In the present research, slump, modulus of rupture (MOR) and flexural toughness $(I_{30})$ of high performance hybrid fiber reinforced concrete (HPHFRC) mixed with micro-fiber (carbon fiber) and macro-fiber (steel fiber) and replaced with silica fume were assessed with the analysis of variance (ANOVA). Steel fiber was a considerable significant factor in aspect of the response values of MOR and boo Based on the significance of factors related to response values from ANOVA, following assessments were available; Slump decrease: carbon fiber >> steel fiber > silica fume; MOR: steel fiber > silica fume > carbon fiber; $I_{30}$: steel fiber > carbon fiber > silica fume. Steel fiber $1.0\%$, carbon fiber $0.25\%$ and silica fume $5.0\%$, and Steel fiber $1.0\%$, carbon fiber $0.25\%$ and silica fume $2.5\%$ were obtained as the most optimum mixture.

• Conservation Science in Museum
• /
• v.27
• /
• pp.91-102
• /
• 2022

Silica-based inorganic fillers for restoration of iron objects have been used for the reduction of thermal expansivity and the improvement of melt flow index. However, the higher the amount of filler is applied, the more degradation of mechanical properties and the yellowing occur, which could cause retreatment of the objects with adding stress to them. Thus, research on not only the quantification of a mixture of resin and filler but also the yellowing should be emphasized. Experiments on mechanical properties were carried out with a silica-based light filler, Micro Shell as a comparison group. The results of the experiment showed Micro Shell reduced the number of occurrences of the yellowing by 34% compared to existing fillers. The value of adhesion and specific gravity was also improved depending on the filler amount. The results of this research indicate the possibility of using Micro Shell as a new filler.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.10
• /
• pp.3378-3382
• /
• 2012

A superhydrophobic surface with a water contact angle > $150^{\circ}$ has attracted great interest from both fundamental and practical aspects. In this study, we demonstrated that hydrophobicity of a silica nanotube (SNT) array can be easily controlled by the SNT aspect ratio. In addition, the adhesive and anti-adhesive properties were controlled without modifying the hydrophobic surface. Various silica structures on a polydimethylsiloxane substrate were prepared using the desired alumina template. Bundle-arrayed and bowl-arrayed silica surfaces exhibited extraordinary superhydrophobicity due to the large frontal surface area and hierarchical micro/nanostructure. As the strategy used in this study is biocompatible and a wide range of hydrophobicities are capable of being controlled by the SNT aspect ratio, a hydrophobic surface composed of an SNT array could be an attractive candidate for bioapplications, such as cell and protein chips.

• Transactions of Materials Processing
• /
• v.11 no.7
• /
• pp.601-607
• /
• 2002

Optically transparent materials such as fused silica, quartz and crystal have become important in the filed of optics and optoelectronics. Laser ablation continues to grow as an important technique for micromachining and surface modification of various materials, because many problems caused by direct contact between tools and workpiece can be avoided. Especially, laser ablation with excimer lasers enables fine micromachining of transparent materials such as fused silica, quartz and crystal, etc. In this study, laser-induced wet etching of fused silica in organic solution was conducted. KrF excimer laser was used as a light source and acetone solution of pyrene was used as etchant. Changing the number of laser pulses, micro holes of various depths are fabricated.

• Advances in materials Research
• /
• v.12 no.3
• /
• pp.227-242
• /
• 2023

Polyester composites play a vital role in civil engineering applications, especially in bridge and car park structures. Therefore, the addition of waste silica-based fillers will both improve the mechanical and durability performance of composites and produce an environmentally friendly material. In this study, the mechanical performance of polyester composites was investigated experimentally and numerically by adding micro and nano-sized silica-based fillers, marble powder, silica fume and nano-silica. 24 cubes for the compression test and 18 prisms for the flexural test were produced in six different groups containing 30% marble powder, 5% silica fume and 1% nano-silica by weight. SEM/EDS testing was used to investigate the distribution of filler particles in the matrix. Experimentally collected results were used to validate tests in the Abaqus software. Additionally, the Extended Finite Element Method (XFEM) was used to estimate the fracture process for the flexural test. The results show that the added silica fume, marble powder and nano silica improves the compressive strength of polyester composites by 32-38% and the flexural tensile strength by 10-60% compared to pure polyester composite. The numerically obtained results matched well with the experimental data, demonstrating the accuracy and feasibility of the calibrated finite element model.

• Journal of the Korea Concrete Institute
• /
• v.19 no.1
• /
• pp.47-56
• /
• 2007

Recently, tunnels are increasingly constructed in this country with the increased construction of highways, high-speed railways and subways. Shotcrete is one of the major processes in the tunnel construction. Many problems, however, exist in the current shotcrete practice. The purpose of the study is, therefore, to explore the trobles in the current shotcreting practice, and to develop high-quality silica fume shotcrete. For the purpose of security a long-term durability of shotcrete, this study conducted combined deterioration tests. In this study, a combined deterioration test in consideration of a variety of deterioration factors were proceeded. Especially, micro-silica fume that was used frequently in overseas because of a outstanding strength-promotion effect was applied to combined deterioration test, and a long-term durability of shotcrete was investigated according to additions mixing. As a result of test, the shotcrete mixed Micro-silica fume showed a good deterioration quality compared with the other mixes. And is shows that the Micro-silica fume has an outstanding strength-promotion effect and is effective to secure a long-term durability of shotcrete by means of decreasing a deterioration caused by steel fiber mixed.