• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2004년도 춘계학술대회 논문집
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• pp.245-249
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• 2004

Transparent materials such as fused silica are important materials in optical and optoelectronics field because of its outstanding properties, such as transparency in a wide wavelength range, strong damage resistance for laser irradiation, and high thermal and chemical stability. However, these properties make it difficult to micromachine silica in micro-sized quantities. In this study, we fabricated a micro patterns on the surface of fused silica plate using laser induced wet etching. KrF excimer laser was used as a light source. There were no burrs and micro cracks on the etched surface of fused silica and the flatness of the etched surface was fairly good. We investigated the influence of etchant upon the etch rate and quality in laser induced wet etching. Pyrene-acetone, toluene, and pyrene-toluene solution were used as etchant. In the side of etch rate, toluene and pyrene-toluene solution were better than pyrene-acetone solution.

• 한국터널지하공간학회 논문집
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• 제8권2호
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• pp.165-182
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• 2006

본 연구에서는 실리카 흄을 혼합한 숏크리트의 강도증진 효과를 파악하기 위해 현장실험을 실시하였고, 유럽통합규격(EFNARC)에 의거하여 품질평가를 수행하였다. 그리고 탄산화와 동결융해의 복합인자에 의한 열화시험을 수행하여 고강도 숏크리트의 장기내구성을 평가하였다 실험결과 실리카 흄을 혼입한 숏크리트의 압축강도는 45.2~55.8MPa, 휨강도는 5.01~6.66MPa로 혼입하지 않은 경우에 비해 각각 37~79%, 17~61%의 강도증진 효과가 나타났고, 실리카 흄 치환율이 7.5~10%일 때 강도증진 효과가 가장 우수한 것으로 나타났다. 또한, 실리카 흄을 치환한 숏크리트의 상대동탄성계수, 질량감소율 및 탄산화 진행율 등을 측정한 결과, 실리카 흄이 강섬유 혼입에 의한 숏크리트의 열화현상을 최소한으로 감소시켜, 숏크리트의 장기내구성을 확보하는데 효과가 있음을 알수 있었다.

• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.45-50
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• 2014

A fully packed capillary electrochromatographic (CEC) microchip with an on-column micro-solid phase extraction (SPE) bed for the preconcentration and separation of organic analytes was prepared. A linear microchannel with monodisperse colloidal silica packing was formed on a cyclic olefinic copolymer microchip with two reservoirs on both ends. Silver-cemented silica packing frit structure was formed at the entrance of the microchannel by electroless plating treatment as a base layer. A gold coating was formed on it by reducing $Au^{3+}$ to gold with hydroxylamine. Finally micro-SPE bed was formed by self-assembly adsorption of 1-dodecanethiol on it. Micro-SPE beds were about 100-150 ${\mu}m$ long. Approximately $10^3$ fold sensitivity enhancements for Sulforhodamine B, and Fluorescein in nM concentration levels were possible with 80 s preconcentration. Basic extraction characteristics were studied.

• 소성∙가공
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• 제13권3호
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• pp.268-272
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• 2004

Transparent materials such as fused silica are widely utilized in optical and optoelectronics field because of its outstanding properties, such as transparency in a wide wavelength range, strong damage resistance for laser irradiation, and high thermal and chemical stability. In this study, we made a few micro patterns on the surface of fused silica plate using laser induced wet etching. KrF excimer laser was used as a light source. There were no burrs and micro cracks on the etched surface of fused silica and the flatness of the etched surface was fairly good. We investigated the influence of etchant upon the etch rate and quality in laser induced wet etching. Pyrene-acetone solution and toluene were used as etchant. In the side of etch rate, toluene solution was better than pyrene-acetone solution. But we made in wider range of energy density using pyrene-acetone solution. But pyrene-acetone solution gave us wider window of energy density for successful micro patterning.

• 한국전기전자재료학회논문지
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• 제25권10호
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• pp.779-785
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• 2012

The epoxy/micro-and nano-mixed silica composites(EMNC) systems were prepared and the AC insulation breakdown strength was evaluated. Glass transition temperature (Tg) and crosslink density were also measured by dynamic mechanical analyzer(DMA) in order to correlate them with the electrical and mechanical properties, and the effect of silane coupling agent on the electrical properties was also studied. Electrical properties and crosslink density of epoxy/micro-silica composite were noticeably improved by addition of nano-silica and silane coupling agent, and the highest breakdown strength was obtained by addition of 0.5~5 phr of nano-silica and 2.5 phr of silane coupling agent, and the highest tensile and flexural strength were obtained by addition of 2.5 phr of nano-silica.

• 한국세라믹학회지
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• 제54권3호
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• pp.222-227
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• 2017

Flake-type micro hollow silica was synthesized by precipitation method using an $Mg(OH)_2$ inorganic template and sodium silicate and ammonium sulfate as the silica precursors. We investigated the effects of the silica precursor concentration on the shape, shell thickness, and surface of the hollow silica. When the concentration of the silica precursor was 0.5 M, the hollow silica had a smooth and translucent thin shell, but the shell was broken. On the other hand, the shell thickness of the hollow silica changed in the range of 12 nm to 18 nm with the increase of the precursor concentration from 0.7 M to 1.1 M. Simultaneously, unintended spherical silica satellites were created on the shell surface. The number of satellites and the size rose according to the increased concentration of silica precursor. The reason for the formation of spherical silica satellites is that the $NH_4OH$ nucleus generated in the synthesis of hollow silica acted as another silica reaction site.

• 한국세라믹학회지
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• 제46권1호
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• pp.69-73
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• 2009

We report the preparation of nanocrystalline cobalt ferrite, $CoFe_2O_4$ particles and their surface coating with silica layers using micro emulsion method. The cobalt ferrite nanoparticles with the size 7nm are firstly prepared by thermal decomposition method. Hydrophobic nanoparticles were coated with silica using micro-emulsion method with surfactant, $NH_4OH$, and tetraethylorthosilicate (TEOS). Monodispersed and spherical silica coated cobalt ferrite nanoparticles have average particle diameter of 38 nm and narrow sized distribution.

• 한국재료학회지
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• 제21권2호
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• pp.100-105
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• 2011

The relative viscosity was measured at different filler loadings for a cycloaliphatic epoxy resin and hexahydro-4-methylphthalic anhydride hardener system filled with micro/nano hybrid silica. Various empirical models were fitted to the experimental data and a fitting parameter such as critical filler fractions (${\phi}_{max}$) was estimated. Among the models, the Zhang-Evans model gave the best fit to the viscosity data. For all the silica loadings used, ln (relative viscosity) varied linearly with filler loadings. Using the Zhang-Evans model and the linearity characteristics of the viscosity change, simple methods to predict the relative viscosity below ${\phi}_{max}$ are presented in this work. The predicted viscosity values from the two methods at hybrid silica fractions of $\phi$ = 0.086 and 0.1506 were confirmed for a micro:nano = 1:1 hybrid filler. As a result, the difference between measured and predicted values was less than 11%, indicating that the proposed predicting methods are in good agreement with the experiment.

• 한국수산과학회지
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• 제1권2호
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• pp.73-79
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• 1968

Silica Gel, Hyflo super-Cel, 및 Micro-Cel C 박층을 이용한 xanthophyll 분리를 위한 chromatography의 실험결과를 요약하면 1) 색소분리능력은 Micro-Cel C 박층이 가장 좋고 Silica Gel 박층에서도 만족할만한 하였다. 그러나 Silica Gel 박층은 자체의 산성때문에 조작중 epoxy xanthophyll의 furanoid 이성화를 초래하였다. 2) $CaSO_4$ 등의 binder는 접착보조효과 보다는 오히려 분리능력을 방해하였다. 3) 전개조건은 차광하의 불포화용기내에서 $15\~20$분간의 전개에 $13\%$ acetone-petroleum ether 용매를 쓰는 것이 적당하였다. 4) Band의 형상 및 trailing을 정상화하는데는 양편 가장자리의 박층을 $0.2\~0.3cm$ 폭으로 제거하는 것이 효과적 이였다. 5) 박층의 두께는 10g의 Micro-Cel C 분말을 75ml의 증유수에 현탁시켜 그중 3ml 취하여 한개의 $2\times20cm$ glass slide에 도포한것이 적당하였다. 7) 이상의 결과에서 Micro-Cel C thin-layer는 미량의 시료로서 단시간내에 빠른 조작으로 artifact 생성없이 xanthophyll을 분리 할 수 있고 band는 손쉽게 긁어내어 흡광도법에 의해 정량적인 목적에도 이용할 수 있었다.

• 전기학회논문지
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• 제65권11호
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• pp.1840-1847
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• 2016

The surface of nanosilica and microsilica was modified in order to develop a high voltage insulation material for outdoor application. The modified silicas were well dispersed in an aliphatic cyclic epoxy resin. Dielectric properties were studied for 8 kinds of specimens: 1 kind of neat epoxy, 3 kinds of epoxy/microsilica composites, and 4 kinds of epoxy/microsilica/nanosilica composites. Complex dielectric constants were measured in the range of 10-2~1.2 Hz at room temperature.