• 제목/요약/키워드: methyl methacrylate

검색결과 586건 처리시간 0.029초

STRUCTURAL MORPHOLOGY AND DIELECTRIC PROPERTIES OF POLYANILINE-EMERALDINE BASE AND POLY METHYL METHACRYLATE THIN FILMS PREPARED BY SPIN COATING METHOD

  • Shekar, B. Chandar;Yeon, Ji;Rhee, Shi-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.1081-1084
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    • 2003
  • Structural morphology, annealing behavior and dielectric properties of polyaniline-emeraldine base (Pani-EB) and poly methyl methacrylate (PMMA) thin films prepared by spin coating technique have been studied. MIM and MISM structures were used to investigate annealing and dielectric behavior. The XRD and AFM spectrum of as grown and annealed thin films indicates the amorphous nature. The observed amorphous phase, low loss, dielectric behavior and thermal stability even at high temperatures implies the feasibility of utilizing PMMA and Pani-EB thin films as gate dielectric insulator layer in organic thin film transistors which can find application in flat panel display.

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PMMA 보호막을 이용한 용액 공정 기반의 인듐-이티륨-산화물 트랜지스터에 관한 연구 (Study on Solution Processed Indium-Yttrium-Oxide Thin-Film Transistors Using Poly (Methyl Methacrylate) Passivation Layer)

  • 김한상;김성진
    • 한국전기전자재료학회논문지
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    • 제30권7호
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    • pp.413-416
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    • 2017
  • We investigated solution-processed indium-yttrium-oxide (IYO) TFTs using apoly (methyl methacrylate) (PMMA) passivation layer. The IYO semiconductor solution was prepared with 0.1 M indium nitrate hydrate and 0.1 M yttrium acetate dehydrate as precursor solutions. The solution-processed IYO TFTs showed good performance: field-effect mobility of $13.13cm^2/Vs$, a threshold voltage of 8.2 V, a subthreshold slope of 0.93 V/dec, and a current on-to-off ratio of $7.2{\times}10^6$. Moreover, the PMMA passivation layers used to protectthe IYO active layer of the TFTs, did so without deteriorating their performance under ambient conditions; their operational stability and electrical properties also improved by decreasing leakage current.

MWNT/PMMA 나노복합재료 제작시 MWNT의 분산에 관한 연구 (A Study on the Dispersion of Multi-walled Nanotube of MWNT/PMMA Nanocomposites)

  • 김현철;이상의;김천곤;이정주
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2003년도 추계학술발표대회 논문집
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    • pp.29-32
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    • 2003
  • Multi -walled carbon nanotube(MWNT)/poly(methyl methacrylate) composites were fabricate d through film casting. Manufacturing process was established using a ultrasonic cleaner and a homogenizer. Acetone was used as a solvent to melt PMMA and mix with MWNT. The ultrasonic cleaner performed an important role in producing MWNT/MMA nanocomposites. Ultrasonic energy was utilized to disperse MWNT in acetone. Also, melting PMMA in acetone and mixing MWNT and PMMA were achieved using the homogenizer. It was confirmed that the nanohlbes were well dispersed in PMMA according to SEM images.

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측면 연마 광섬유를 이용한 가변 광 감쇠기 (Variable Optical Attenuator based on Side Polished Fiber Technique)

  • 구숙영;정치섭
    • 한국광학회지
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    • 제15권3호
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    • pp.222-228
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    • 2004
  • 측면 연마 광섬유를 이용하여 가변 광 감쇠기를 실험적으로 구현하였다. 오버레이 물질로는 poly(vinylidene fluoride)와 poly (methyl methacrylate) 고분자 혼합체를 사용하였다. 혼합고분자의 온도를 변화시켜 오버레이의 굴절률을 조절하였고, 그로 인한 소산장 결합정도를 변화시켜 광섬유로부터 추출되는 광량을 조절하였다. 삽입손실은 0.1 ㏈ 이하였으며 30㏈이상의 감쇠를 실현하였다.

에스테르 교환반응(交換反應)의 촉매활성(觸媒活性)에 관(關)한 연구(硏究) (Catalytic Activity Studies in Transesterification Reaction)

  • 박근호;김동식;정순욱
    • 한국응용과학기술학회지
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    • 제7권1호
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    • pp.71-76
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    • 1990
  • Transesterification reactions (methyl methacrylate with monoethanolamine, methyl methacrylate with n-butyl alcohol, dimethylphthalate with ethylene glycol, dimethyl phthalate with monoethanolamine) were kinetically investigated in the presense of various metal acetate catalysts at $110^{\circ}C$. The amount of reactants was measured by gas and liquid chromatography, and the reaction rates also measured from the amount of reaction products and reactants upon each catalyst. The transesterification reactions were carried out under the first order conditions respect to the concentration of reactants, respectively. The overall reaction order was 2nd, Maximum reaction rates were appeared at the range of 1.4 to 1.6 in electronegativity of metal ions and maximum catalytic activities were obserbed at the range of 1.5 to 1,8 in instability constant of metal acetates.

제제설계(製劑設計)에서의 생체내(生體內) 이용솔(利用率)에 관(關)한 연구(硏究) (Bioavailability Study on Design of Preparations)

  • 이철우
    • Journal of Pharmaceutical Investigation
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    • 제5권4호
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    • pp.7-16
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    • 1975
  • The drug release property from the coated tablets which contain 291mg of acetylsalicylic acid were estimated from comparison of the blood level and the urinary excretions after oral ingestion of coated tablets and noncoated tablet in human. The coating materials are 2-methyl-5-vinylpyridine-methylacrylic acid copolymer(MPM), dimethyl aminoethyl methacrylate methyl methacrylate copolymer(EE), polyvinyl acetal diethyl aminoacetate(AEA), and shellac. Each of 7 subjects ingested 873mg of acetylsaliylic acid. All tablets are coated approximately $3.5{\pm}0.5%(w/w)$ per tablet with each of the coating materials and met K.P.II. standard for potency and disintegration time. The availability was decreased in the following order:MPM coated tablets>EE coated tablets>AEA coated tablets>> shellac coated tablets.

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플라즈마중합 PPMMA의 전기전도 기구에 관한 연구 (The study on electrical conduction mechanism of plasma-polymerized methyl methacrylate (PPMMA))

  • 박재윤;박광현;한상욱;이덕출
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1987년도 정기총회 및 창립40주년기념 학술대회 학회본부
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    • pp.283-285
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    • 1987
  • Transient conduction current (I - t characteristics) were measured in thin PPMMA (plasma-polymerized methyl methacrylate) films over the temperature range $60^{\circ}C-140^{\circ}C$ and the applied voltage range 3V - 30V. The current, which increased with temperature rise at constant applied voltage, showed less absorption current (current decay with time) at higher temperature region compared with those at lower temperature region. And the current, which increased with applied voltage rise at the constant temperature, showed less absorption current at higher voltage compared with those at lower voltage. The electric field current density characteristic curves were abtained from the conduction current values were after applying voltage for 30 minutes. And transient conduction currents were analyzed with high field conduction theories.

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PMMA IPN계 겔폴리머전해질을 채용한 리튬이온폴리머전지의 전기화학적 특성 (Electrochemical Properties of Lithium-Ion Polymer Battery with PMMA IPN-Based Gel Polymer Electrolyte)

  • 김현수;신정한;나성환;엄승욱;문성인;김상필
    • 한국전기전자재료학회논문지
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    • 제16권11호
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    • pp.994-1000
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    • 2003
  • In this study, gel polymer electrolytes (GPE) with semi-interpenerating network of poly (methyl methacrylate) and hexanediol dimethacrylate were synthesized and their electrochemical performances were evaluated. LiCoO$_2$/GPE/graphite cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing 5 vol% curable mixture had a low viscosity relatively. GPE showed good electrochemical stability up to potential of 4.8 V vs. Li/Li$\^$+/. Ionic conductivity of the gel polymer electrolyte at room temperature and -20$^{\circ}C$ was ca. 5.9 and 1.4${\times}$10$\^$-3/ Scm$\^$-1/, respectively. LiCoO$_2$/GPE/graphite cells showed good rate capability, low-temperature performance and cycleability.

UV 개질된 PMMA 미세유체 장치의 열가소성 폴리머 용융 접합 (Thermoplastic Fusion Bonding of UV Modified PMMA Microfluidic Devices)

  • 박태현
    • 한국정밀공학회지
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    • 제31권5호
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    • pp.441-449
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    • 2014
  • Thermoplastic fusion bonding is widely used to seal polymer microfluidic devices and optimal bonding protocol is required to obtain a successful bonding, strong bonding force without channel deformation. Besides, UV modification of the PMMA (poly-methyl methacrylate) is commonly used for chemical or biological application before the bonding process. However, study of thermal bonding for the UV modified PMMA was not reported yet. Unlike pristine PMMA, the optimal bonding parameters of the UV modified PMMA were $103^{\circ}C$, 71 kPa, and 35 minutes. A very low aspect ratio micro channel (AR=1:100, $20{\mu}m$ depth and $2000{\mu}m$ width) was successfully bonded (over 95%, n>100). Moreover, thermal bonding of multi stack PMMA chips was successfully demonstrated in this study. The results may applicable to fabricate a complex 3 dimensional microchannel networks.

Acrolein과 Vinyl Compounds의 共重合에 關한 硏究 (Studies on Copolymerization of Acrolein with Styrene, Methyl methacrylate and Vinyl acetate)

  • 심정섭;전영승
    • 대한화학회지
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    • 제13권4호
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    • pp.373-377
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    • 1969
  • In order to determine the monomer reactivity ratio in copolymerization of acrolein, the copolymerization of acrolein with styrene, methyl methacrylate and vinyl acetate respectively was studied. The Q and e value of acrolein in each copolymerization were also calculated from those of monomer reactivity ratios, but the calculated values were slightly different from each other. The Q and e of acrolein for the system of acrolein-styrene copolymerization were Q = O.64 and e = O.62 respectively. Relations among the Q and e value, the composition and structure of copolymers and the mean sequence length in copolymerization were also discussed for acrolein copolymers.

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