• Title/Summary/Keyword: methyl 11

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Studies on the Chemical Constituents of Acanthopanax koreanum(ll)

  • Kim, Young-Ho;Chung, Bo-Sup;Ko, Young-Su;Han, Hee-Ja
    • Archives of Pharmacal Research
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    • v.11 no.2
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    • pp.159-162
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    • 1988
  • From the root bark of Acanithopanax koreanum, two polyacetylene compounds and one lignan compound were isolated and identified as falcarinon, falcarindiol and ariensin. Furthermore the steam bark also afforded methyl n-hexacosanoate, methyl linoleate and coniferin.

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Simple Synthesis of Novel 1',4'-Dimethyl Branched Carbovir Analogues

  • Kim, Ai-Hong;Hong, Joon-Hee
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1767-1770
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    • 2005
  • Novel 1',4'-dimethyl branched carbocyclic nucleosides were synthesized from acetol. The 4'-methyl group was installed via a Claisen rearrangement reaction, and the carbonyl addition of methylmagnesium bromide was used to introduce the 1'-methyl group. The coupling of nucleosidic bases and desilylation was used to produce a series of novel nucleosides.

Characteristics of Samjangs Prepared with Different Doenjangs As a Main Material (원료된장을 달리하여 제조한 쌈장의 품질특성)

  • Kim, Hye-Lim;Lee, Taik-Soo;Noh, Bong-Soo;Park, Jung-Suk
    • Korean Journal of Food Science and Technology
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    • v.30 no.1
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    • pp.54-61
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    • 1998
  • Samjangs (Korean-style mixture of soybean paste) were prepared using magjang, traditional doenjang (Korean style soybean paste), and mixture of traditional doenjang and magjang (a kind of Korean style soybean paste) as a main composition. Charateristics including volatile compounds were investigated. Total sugar in samjang by using magjang was higher than that of other treatment while reducing sugar of the mixed treatment was high. Glutamic acid $(230.6{\sim}310.9\;mg/100\;g)$ was highest among free amino acids. Hunter color values of samjang with magjang was lower than those of others. Volatitle flavor components of smajang were identified with GC and GC-MSD. Fifty four components including 11 alcohols, 7 esters, 13 acids, 3 aldehydes, 4 alkanes, 4 phenols, 3 pyrazine and others were found in samjangs. Ethanol, acetic acid ethyl ester, 3-methyl butanoic acid, 2,4-hexadienoic acid and acetic acid might be major volatile components considering of high peak area. Pentanoic acid methyl ester and 4-methoxy-2-buten-1-ol were higher than other components in samjang with magjang while 2-methyl-1-propanol, butanoic acid and 3-methyl butanoic acid were in samjang with traditional doenjang and ethanol, acetic acid ethyl ester and 2,4-hexadienoic acid were in the mixed treatment.

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Characteristics of MTBE for unleaded gasoline (무연 가솔린의 옥탄가 향상제인 MTBE의 특성)

  • 정석진
    • Journal of the korean Society of Automotive Engineers
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    • v.11 no.6
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    • pp.24-27
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    • 1989
  • MTBE(Methyl Tertiary Butyl Ether)는 PMMA(Poly Methyl Methacrylate)를 생산하기 위한 석유화학 중간원료로 사용되는 것이 일반적이나, 무연휘발유 사용의 세계적인 추세에 힘입어 (정유산업에 있어서 그 수요가 날로 증가하고 있으며) 정유산업의 옥탄가 문제를 해결해 주는 유효적절한 수단으로 보급이 확대되고 있는 실정이다. 여기에서는 MTBE의 전반적인 특성 및 사용에 따른 효과 및 장단점을 소개하고자 한다.

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Kinetics and Mechanism of Pyridinolyses of Ethyl Methyl and Ethyl Propyl Chlorothiophosphates in Acetonitrile

  • Barai, Hasi Rani;Lee, Hai Whang
    • Bulletin of the Korean Chemical Society
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    • v.34 no.11
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    • pp.3372-3376
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    • 2013
  • The kinetic studies on the reactions of ethyl methyl (2) and ethyl propyl (4) chlorothiophosphates with X-pyridines have been carried out in acetonitrile at $35.0^{\circ}C$. The free energy correlations with X show biphasic concave upwards with a break point at X = H (2) and 3-Ph (4), respectively. A stepwise mechanism with a rate-limiting leaving group expulsion from the intermediate is proposed based on the magnitudes of selectivity parameters for both substrates. The considerably large values of ${\beta}_X$ = 1.50(2) and 1.44(4) with strongly basic pyridines and relatively small values of ${\beta}_X$ = 0.43(2) and 0.36(4) with weakly basic pyridines are interpreted as a change of the attacking direction of the X-pyridines from a frontside to a backside attack toward the chloride leaving group.