• 한국초전도학회:학술대회논문집
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• 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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• pp.229-232
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• 1999

We have measured the temperature dependence of thermoelectric power (TEP) and resistivity for the Sr$_{1-x}K_xBiO_3$ superconductor (x=0.45-0.6). At T=10.2K, the resisitivity starts to increase from zero and a rather broad superconducting phase transition (${\Delta}$T ${\sim}$ 2.3K) is observed. TEP at room temperature has a small negative value ( S =-1.96${\mu}$V/K), characteristic of metallic-like TEP. The temperature dependence of TEP shows two distinct features. With decreasing temperature from room temperature, the absolute value of TEP decreases and the sign of TEP changes from negative to positive around 200k. Also, the negative slope of TEP(dS/dT) decreases substantially and becomes rather flat at around 160k, which is a feature already noted in Ba$_{1-x}K_xBiO_3$[1].

• Journal of Mechanical Science and Technology
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• 제17권12호
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• pp.2053-2065
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• 2003

The current trend in automotive finishing industry is to use more electrostatic rotating bell (ESRB) need space to their higher transfer efficiency. The flow physics related with the transfer efficiency is strongly influenced by operating parameters. In order to improve their high transfer efficiency without compromising the coating quality, a better understanding is necessary to the ESRB application of metallic basecoat painting for the automobile exterior. This paper presents the results from experimental investigation of the ESRB spray to apply water-borne painting. The visualization, the droplet size, and velocity measurements of the spray flow were conducted under the operating conditions such as liquid flow rate, shaping airflow rate, bell rotational speed, and electrostatic voltage setting. The optical techniques used in here were a microscopic and light sheet visualization by a copper vapor laser, and a phase Doppler particle analyzer (PDPA) system. Water was used as paint surrogate for simplicity. The results show that the bell rotating speed is the most important influencing parameter for atomization processes. Liquid flow rate and shaping airflow rate significantly influence the spray structure. Based on the microscopic visualization, the atomization process occurs in ligament breakup mode, which is one of three atomization modes in rotating atomizer. In the spray transport zone, droplets tend to distribute according to size with the larger drops on the outer periphery of spray. In addition, the results of present study provide detailed information on the paint spray structure and transfer processes.

• 반도체디스플레이기술학회지
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• 제9권1호
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• pp.29-33
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• 2010

Recently, the growth of ZnO thin film on glass substrate has been investigated extensively for transparent thin film transistor. We have studied the phase transition of ZnO thin films from metal to semiconductor by changing RF power in the deposition process by RF magnetron sputtering system. The structural, electric, and optical properties of the ZnO thin films were investigated. The film deposited with 75 watt of RF power showed n-type semiconductor characteristic having suitable resistivity $-3.56\;{\times}\;10^{+1}\;{\Omega}cm$, carrier concentration $-2.8\;{\times}\;10^{17}\;cm^{-3}$, and mobility $-0.613\;cm^2V^{-1}s^{-1}$ while other films by 25, 50, 100 watt of RF power closed to metallic films. From the surface analysis (AFM), the number of crystal grain of ZnO thin film increased as RF power increased. The transmittance of the film was over 88% in the visible region regardless of the change in RF power.

• Advances in nano research
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• 제2권2호
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• pp.77-88
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• 2014

Solvothermal treatment of late transition metal acetylacetonates in a novel medium composed either of pure acetophenone or acetophenone mixtures with amino alcohols offers a general approach to uniform hydrophilic metal nanoparticles with high crystallinity and low degree of aggregation. Both pure metal and mixed-metal particles can be accesses by this approach. The produced materials have been characterized by SEM-EDS, TEM, FTIR in the solid state and by Nanoparticle Tracking Analysis in solutions. The chemical mechanisms of the reactions producing nanoparticles has been followed by NMR. Carrying out the process in pure acetophenone produces palladium metal, copper metal with minor impurity of $Cu_2O$, and NiO. The synthesis starting from the mixtures of Pd and Ni acetylacetonates with up to 20 mol% of Pd, renders in minor yield the palladium-based metal alloy along with nickel oxide as the major phase. Even the synthesis starting from a mixed solution of $Cu(acac)_2$ and $Ni(acac)_2$ produces oxides as major products. The situation is improved when aminoalcohols such as 2-aminoethanol or 2-dimethylamino propanol are added to the synthesis medium. The particles in this case contain metallic elements and pairs of individual metals (not metal alloys) when produced from mixed precursor solutions in this case.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.478.2-478.2
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• 2014

Atomic layer deposition (ALD) provides self-limiting processes based on chemisorption-based reactions. Such unique features allow for superior step coverage, atomic-scale control in thickness, and surface-dependent reaction controls. Furthermore, the surface-limited deposition enables the artificial deposition of oxide and/or metallic materials onto the porous systems as long as the supply is guaranteed in terms of time in providing reactant species and removing the byproducts and redundant reactants. The unique feature of atomic layer deposition is applied to solid oxide fuel cells whose incorporates two porous cathode and anode compartments in addition to the ionic electrolyte. Specific materials are deposited to the surface sites of porous electrodes, with the aim to controlling the triple phase boundaries crucial for the optimized SOFC performances. The effect of ALD on the SOFC performance is characterized using current-voltage characteristics in addition to frequency-dependent impedance spectroscopy. The pros and cons of ALD-controlled SOFCs are discussed toward high-performance SOFC systems.

• 소성∙가공
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• 제8권3호
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• pp.283-283
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• 1999

In the present study, the effect of microporosity on the tensile properties of as-cast AZ91D magnesium alloy was investigated through experimental observation and numerical prediction. The test specimens were fabricated by die-casting and gravity-casting. For gravity-casting, the inoculation and use of various metallic moulds were applied to obtain a wide range of microporosity. The deficiency of the interdendritic feeding of the liquid phase acted as d dominant mechanism on the formation of the micropores in the Mg-Al-alloys, rather than the evolution of hydrogen gas. Although tensile strength and elongation has a nonlinear and very intensive dependence upon microporosity, the yield strength appeared to have a linear relationship with microporosity. However, it was possible to quantitatively estimate the linear contribution of microporosity on the individual tensile property far a range of microporosity, which was below about B %. The numerical prediction suggests that the effect of microporosity on fractured strength and elongation decreased as the strain hardening exponent increased. Furthermore. the shape and distribution of micropores may play a more dominant role than local plastic deformation on the tensile behavior of AZ9lD alloy.

• Applied Microscopy
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• 제44권1호
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• pp.34-39
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• 2014

Electron backscatter diffraction (EBSD) is widely used for quantitative microstructural analysis of the crystallographic nature of variety of materials such as metals, minerals, and ceramics. EBSD can provide a wide range of information on materials including grain size, grain orientation, texture, and phase identity. In the case of metallic alloys, EBSD now has become an essential technique to analyze the texture, particularly when severe deformation is applied to the alloys. In addition, EBSD can be one of the very useful tools in identification of twin, particularly in Mg alloys. In Mg alloys different type of twin can occur depending on the c/a ratio and stacking fault energy on the twinning plane. Such an occurrence of different type of twin can be most effectively analyzed using EBSD technique. In this article, the recent development of Mg alloys and occurrence of twin in Mg are reviewed. Then, recently published example for identification of tension and compression twins in AZ31 and ZX31 is introduced to explain how EBSD can be used for identification of twin in Mg.

• 공업화학
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• 제1권1호
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• pp.100-105
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• 1990

칼륨과 티타니아 담체가 일산화탄소 수소화 반응에서 분자량이 큰 불포화 탄화수소의 합성에 유리할 것으로 예상하여, 칼륨염이 첨가된 티타니아 담지 코발트 촉매를 제조하여 일산화탄소 수소화 반응에 사용하였다. 칼륨과 티타니아 담체는 일산화탄소 수소화 반응에서 분자량이 큰 불포화 탄화수소 화합물을 합성하는 데 있어 중요한 역할을 하였을 뿐 아니라, 탄소 누적에 의한 촉매의 비활성화 방지에도 기여하였다. 이는 티타니아 담체가 코팔트 금속과 강한 상호작용을 하고, 칼륨은 코발트 금속에 전자를 풍부하게 하는 전자 공급자로 작용하여 일산화탄소의 흡착력을 증가시켰기 때문으로 믿어진다.

• 한국표면공학회지
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• 제44권5호
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• pp.220-225
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• 2011

304 stainless steel plate was colored by hot dip and electrochemical treatment in a solution containing sulphuric and chromic acids. In the process, treatment variables such as operating time and methode were changed. The surface characteristics that changed by the treatment of the samples such as surface composition, oxide film thickness, color, surface roughness and reflectivity were studied. Surface composition was varied as follows. Fe was decreased, but Cr and O were increased. Ni was increased until 20 min, but reveals decreasing tendency as time passed after that. These means the surface film becomes chrome rich oxide phase as the treatment times increase. The thickness of film was about 220 nm at 30 min by dip treatment and it reduced as the treatment times increased. On the other hand, the thickness was about 150 nm at 10 min by electrochemical method and it doesn't increased with time. Surface color changed from metallic white of the base plate to gray, black, red, and green-blue, gradually, as the treating time increased. The reflectivity of colored surface measured by UVVIS-NIR spectrophotometer was reduced from max 38% of basis metal to min 3.5%.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2014년도 추계학술대회 논문집
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• pp.112-113
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• 2014

The submicron-rods of $Cu_2O$ with diameters of 100-700 nm and lengths of $2-8{\mu}m$ were synthesized by radio frequency magnetron sputtering. The abundance of Cu species, which is modulated by the $Ar/O_2$ ratio during the sputtering process affect directly to the growths of the $Cu_2O$ branches on the bodies of the submicron-rods. Transmission electron microscopy and elemental mapping reveal that metallic Cu are existed on the heads of the $Cu_2O$ rods. The growth rate, catalyst phase and shape reveal that vapor-quasiliquid-solid was the growth mechanism of the formations of those structures.