• Title/Summary/Keyword: metal working

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Gas Sensing Characteristics and Doping Effect of $MoO_3$ Thin Films prepared by RF magnetron sputtering (RF magnetron sputtering법으로 제조한 $MoO_3$ 박막의 가스 감지 특성 및 첨가물의 영향)

  • Hwang, Jong-Taek;Jang, Gun-Eik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.460-463
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    • 2002
  • $MoO_3$ thin films were deposited on electrode and heater screen-printed alumina substrates in $O_2$ atmosphere by RF reactive sputtering using Molybdenum metal target. The deposition was performed at $300^{\circ}C$ with 350W of a forward power in an $Ar-O_2$ atmosphere. The working pressure was maintained at $3{\times}10^{-2}mtorr$ and all deposited films were annealed at $500^{\circ}C$ for 5hours. To investigate gas sensing characteristics of the addition doped $MoO_3$ thin film, Co, Ni and Pt were used as adding dopants. The sensing properties were investigated in tenn of gas concentration under exposure of reducing gases such as $H_2$, $NH_3$ and CO at optimum working temperature. Co-doped $MoO_3$ thin film shows the maximum 46.8% of sensitivity in $NH_3$ and Ni-doped $MoO_3$ thin film exhibits 49.7% of sensitivity in $H_2$.

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Incorporation of Manganese Oxide Nanoparticles Into Polyaniline Hollow Nanospheres and Its Application to Supercapacitors

  • Kwon, Hyemin;Ryu, Ilhwan;Han, Jiyoung;Yim, Sanggyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.295-295
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    • 2013
  • Supercapacitors with higher energy and power density are attracting growing attention for their wide range of potential applications such as portable electronic equipments, hybrid vehicle and cellular devices. In various classes of materials for supercapacitors, the redox pseudocapacitive materials such as conducting polymers and metal oxides have been most widely studied recently. The nanostructuring of the electrode surface has also been focused on since it can provide large surface area and consequently easy diffusion of ions in the capacitors. Among the active materials, in this work, we have used polyaniline (PANi) and manganese oxide ($MnO_2$). PANi is one of the promising electrode and active materials due to its desirable properties such as high electrochemical activity, high doping level and stability. $MnO_2$ is also widely studied material for supercapacitors since it is relatively cheap and environmentally friendly. In this work, we fabricated PANi hollow nanospheres by polymerizing aniline monomers on the polystyrene (PS) nanospheres and then dissolving the inner PS spheres. This nanostructuring of the PANi surface can provide large surface area and hence easy diffusion of electrolyte ions. We also incorporated $MnO_2$ nanoparticles into the PANi hollow nanospheres and investigated its electrochemical properties. It is expected that the combination of these two active materials with slightly different working potential windows show synergetic effects such as broader working potential range and enhanced specific capacitance.

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Gas Sensing Characteristics and Doping Effect of MoO3Thin Films Sensor (박막형 MoO3가스센서의 가스 감지 특성 및 첨가물의 영향)

  • 황종택;장건익;윤대호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.8
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    • pp.705-710
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    • 2003
  • MoO$_3$thin films were deposited on electrode of alumina substrates in $O_2$atmosphere by RF reactive sputtering using molybdenum metal target. The deposition was performed at 30$0^{\circ}C$ with 350 W of a forward power in an Ar-O$_2$atmosphere. The working pressure was maintained at 3$\times$10$^{-2}$ torr and all deposited films were annealed at 50$0^{\circ}C$ for 5 hours. The surface morphology of films was observed by using a SEM and crystalline phases were analyzed by using a XRD. To investigate gas sensing characteristics of the doped MoO$_3$thin film, Co, Ni and Pt were used as dopants. The sensing properties were investigated in term of gas concentration under exposure of reducing gases such as H$_2$, NH$_3$and CO at optimum working temperature. Co-doped MoO3 thin film shows the maximum 46.8 % of sensitivity in NH$_3$ and Ni-doped MoO$_3$thin film exhibits 49.7 % of sensitivity in H$_2$.

Effect of the Droplets on the Wear Characteristics of Steel for the Cold Working Roller (Droplet가 냉연 롤러용 강의 마모 특성에 미치는 영향)

  • 문봉호
    • Tribology and Lubricants
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    • v.20 no.3
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    • pp.145-151
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    • 2004
  • A modified surface layer by ion implantation is very thin (under 1 $\mu\textrm{m}$) but has superior mechanical characteristics. therefore ion implantation has been used successfully as a surface treatment technology to improve the wear, fatigue, and corrosion resistances of materials. MEVVA which is a kind of ion beam apparatus has merits of low cost and is usable to various metals, but occurs a droplet ranging from micron to tens of micron on the implanted surface at ion implantations. wear is a dynamic phenomenon on interacting surfaces with rotative motion. Since wear changes in condition of the surface, we should control to surface. In order to improve a wear resistance of Ti ion implanted 1C-3Cr steel(material for roller in the cold working process), it is essential to investigate the effect of the droplets on the wear characteristics. In this study, we investigate the effect of the droplets on the wear characteristics of 1C-3Cr steel using SEM Tribosystem as in-situ system. Results show that the droplet occurred at ion implantation becomes the cause of severe wear. Therefore, the ion-implanted surface should be removed the droplet to improve wear resistance.

Analysis of Properties and Fabrication of $1000{\AA}$ silicon nitride MIM capacitor with High Breakdown Electric Field for InGaP/GaAs HBT Application (InGaP/GaAs HBT 적용을 위한 높은 절연강토의$1000{\AA}$ 실리콘 질화막 MIM capacitor제작과 특성 분석)

  • So, Soon-Jin;Oh, Doo-Suk;Sung, Ho-Kun;Song, Min-Jong;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.693-696
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    • 2004
  • For InGaP/GaAs HBT applications, we have developed characterized MIM capacitors with thin $1000{\AA}$ PECVD silicon nitride which were deposited with $SiH_4/NH_3$ gas mixing rate, working pressure, and RF power of PECVD at $300^{\circ}C$ and had the capacitance density of 600 pF/$mm^2$ with the breakdown electric fields of 3073 MV/cm. Three PECVD process parameters were designed to lower the refractive index and then lower the deposition rate of silicon nitride films for the high breakdown electric field. At the PECVD process condition of gas mixing rate (0.92), working pressure (1.3 Torr), RF power (53 W), the AFM Rms value of about $1000{\AA}$ silicon nitride on the bottom metal was the lowest of 0.662 nmand breakdown electric fields were the highest of about 73 MV/cm.

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Evaluation of Exposure Dose and Working Hours for Near Surface Disposal Facility

  • Yeseul Cho;Hoseog Dho;Hyungoo Kang;Chunhyung Cho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.4
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    • pp.511-521
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    • 2022
  • Decommissioning of nuclear power plants generates a large amount of radioactive waste in a short period. Moreover, Radioactive waste has various forms including a large volumes of metal, concrete, and solid waste. The disposal of decommissioning waste using 200 L drums is inefficient in terms of economics, work efficiency, and radiation safety. Therefore, The Korea Radioactive Waste Agency is developing large containers for the packaging, transportation, and disposal of decommissioning waste. Assessing disposability considering the characteristics of the radioactive waste and facility, convenience of operation, and safety of workers is necessary. In this study, the exposure dose rate of workers during the disposal of new containers was evaluated using Monte Carlo N-Particle Transport code. Six normal and four abnormal scenarios were derived for the assessment of the dose rate in a near surface disposal facility operation. The results showed that the calculated dose rates in all normal scenarios were lower than the direct exposure dose limitation of workers in the safety analysis report. In abnormal scenarios, the work hours with dose rates below 20 mSv·y-1 were calculated. The results of this study will be useful in establishing the optimal radiation work conditions.

Recycling Industry of Urban Mines by Applying Non-Ferrous Metallurgical Processes in Japan (비철제련(非鐵製鍊) 프로세스를 이용한 일본(日本)의 도시광산(都市鑛山) 재자원화산업(再資源化産業))

  • Oh, Jae-Hyun;Kim, Joon-Soo;Moon, Suk-Min;Min, Ji-Won
    • Resources Recycling
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    • v.20 no.3
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    • pp.12-27
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    • 2011
  • DOWA group has been working on metal recycling applying the smelting and refining process of KOSAKA Smelter. DOWA has developed it's metal recycling technologies through the treatment of black ore(complex sulfide ores) that contain many kinds of non-ferrous metals. In addition to these special technologies, DOWA has strengthened its hydrometallurgical process of precious metals and ability to deal with low-grade materials such as used electrical appliances or vehicles. On the other hand, JX Nippon Mining & Metals Corporation(JX-NMMC) carries out its metal recycling and industrial waste treatment businesses employing advanced separation, extraction and refining technologies developed through its extensive experience in the smelting of non-ferrous metals. JX-NMMC collects approximately 100,000t/y of copper and precious metal scraps from waste sources such as electronic parts, mobile phones, catalytic converters, print circuit boards and gold plated parts. These items are recycled through the smelting and refining operations of Saganoseki smelter and Hitachi Metal-recycling complex(HMC). In this like, metal recycling industries combined with environmental business service in Japan have been developed through excellent technologies for mineral processing and non-ferrous smelting. Also, both group, Dowa and JX-NMMC, were contributed to establish Japan's recycling-oriented society as the typical leading company of non-ferrous smelting. Now. it is an important issue to set up the collection system for e-waste.

Effects of Minor Alloying Elements on the Mechanical Properties and Formability of Mg-3%Zn-0.5%Sn Base Sheet Alloys (Mg-3%Zn-0.5%Sn계 판재합금의 기계적 성질과 성형성에 미치는 미량합금원소의 영향)

  • Kim, Jeong-Min;Park, Joon-Sik;Kim, Ha-Young;Kim, Ki-Tae
    • Journal of the Korean Society for Heat Treatment
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    • v.21 no.2
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    • pp.87-93
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    • 2008
  • A variety of minor alloying elements such as Zr, Sr, Y, and Gd were added to Mg-3%Zn-0.5%Sn base alloy to form various fine precipitates and their effects on the microstructure, tensile properties, and sheet metal formability were investigated. Various very fine precipitates along with fine second phases were observed by the additions. It was found that Zr or Gd additive has a role to suppress the grain coarsening of alloy sheets during the hot working process. The Zr-added alloy showed the highest tensile elongation at $250^{\circ}C$ whereas the Gd-added alloy exhibited the best sheet metal forming characteristics in terms of CCV (conical cup value) and spring-back tendency.

A Study on Corrosive Behavior of Spring Steel by Shot-Peening Process (쇼트피닝 가공을 통한 스프링강의 부식거동에 관한 연구)

  • An, Jae-Pil;Park, Keyung-Dong
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.325-330
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    • 2004
  • Recently, the request for the high strength of material is more and more increased in the area of industrial environment and machinery. To accomplish the high strength of materials, carbonizing treatment, nitrifying treatment, shot-peening method are representatively applied, however, shot-peening method is generally used among the surface processes. Shot peening is a cold working process used to impact Compressive residual stressed in the exposed surface layers. Benefits due to shot peening are increase in resistance to fatigue, stress corrosion cracking, fretting, galling, erosion and closing of pores. In this study, the influence of shot peening on the corrosion was investigated on spring steel immersed in 3.5% NaCl. The immersion test as performed on the two kinds of specimens. Corrsion potential, polarization curve, residual stress and etc, were investigated from experiment results. From test result the effect of shot peening on the corrosion was evaluated. The important results of the experimental study on the effects of shot peened on the environment corrosion of spring steels are as follows; In case of corrosion potential, shot peened specimen shows more activated negative direction as compared with parent mental. Surface of specimen, which is treated with the shot peened is placed as more activated state against inner base metal. It can cause t도 anti-corrosion effect on the base metal.

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Assessment of the fit of partial frame fabricated by SLS 3D printer (국부상의치의 전해연마에 따른 SLS 3D 프린터의 적합성 평가)

  • Park, Young-Dae;Kang, Wol
    • Journal of Korean society of Dental Hygiene
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    • v.19 no.6
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    • pp.1067-1075
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    • 2019
  • Objectives: The present study aimed to compare the accuracy of removable partial denture (RPD) frameworks fabricated by selective laser sintering (SLS) before and after electropolishing. Methods: A partially edentulous mandibular model was used as the working model. Scanning of the model was performed using a dental scanner. The framework was designed using CAD software. The metal framework was formed using an SLS 3D printer. 3D scans of the two fabricated prototypes produced before and after electropolishing were overlapped with reference data. The fit was calculated based on Root Mean Square (RMS). Fabrication accuracy was verified using the paired t-test to compare the discrepancy before and after electropolishing. Results: The mean (SD) values of RMS before and after electropolishing were 126.6 (34.19) and 75.86 (21.36), respectively. There was a statistically significant difference before and after electropolishing (p<0.05). Conclusions: Metal frameworks made with SLS 3D printers showed clinically acceptable fit after electropolishing.