• Title/Summary/Keyword: metal stability

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A substrate bias effect on the stability of a-Si:H TFT fabricated on a flexible metal substrate

  • Han, Chang-Wook;Nam, Woo-Jin;Kim, Chang-Dong;Kim, Ki-Yong;Kang, In-Byeong;Chung, In-Jae;Han, Min-Koo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.257-260
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    • 2007
  • Hydrogenated amorphous silicon thin film transistors were fabricated on a flexible metal substrate. A negative voltage at a floated gate can be induced by a negative substrate bias through a capacitor between the substrate and gate electrode. This can recover the shifted-threshold voltage to an original value.

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Evaluation of Convection Schemes for Thermal Hydraulic Analysis in a Liquid Metal Reactor (액체금속로 내부 열유동해석을 위한 대류항처리법 평가)

  • Choi Seok-Ki;Kim Seong-O;Kim Eui-Kwang;Eoh Jae-Hyuk;Choi Hoon-Ki
    • 한국전산유체공학회:학술대회논문집
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    • 2002.10a
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    • pp.64-69
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    • 2002
  • A numerical study has been peformed for evaluation of convection schemes for thermal hydraulic analysis in a liquid metal reactor Four convection schemes, HYBRID, QUICK, SMART and HLPA included in the CFX-4 code are considered. The performances of convection schemes are evaluated by applying them to the five test problems. The accuracy, stability and convergence are tested. It is shown that the HYBRID scheme is too diffusive, and the QUICK scheme exhibits overshoots and undershoots, and the SMART scheme shows convergence oscillations, and the HLPA scheme preserves the boundedness without causing convergence oscillations. The accuracies of SMART, QUICK and HLPA schemes are comparable. Thus, the use of HLPA scheme is highly recommended for thermal hydraulic analysis in a liquid metal reactor.

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A Study on the Reliability of Ru-Zr Metal Gate with Thin Gate Oxide (박막 게이트 산화막에 대한 Ru-Zr 금속 게이트의 신뢰성에 관한 연구)

  • 이충근;서현상;홍신남
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.4
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    • pp.208-212
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    • 2004
  • In this paper, the characteristics of co-sputtered Ru-Zr metal alloy as gate electrode of MOS capacitors have been investigated. The atomic compositions of alloy were varied by using the combinations of relative sputtering power of Ru and .Zr. C-V and I-Vcharacteristics of MOS capacitors were measured to find the effective oxide thickness and work function. The alloy made of about 50% of Ru and 50% of Zr exhibited an adequate work function for nMOS. C-V and I-V measurements after 600 and $700^{\circ}C$ rapid thermal annealing were performed to prove the thermal and chemical stability of the Ru-Zr alloy film. Negligible changes in the accumulated capacitance and work function before and after annealing were observed. Sheet resistance of Ru-Zr alloy was lower than that of poly-silicon. It can be concluded that the Ru-Zr alloy can be a possible substitute for the poly-silicon used as a gate of nMOS.

Effect of the Pressure Formation at the Tip of the Melt Delivery Tube in Close-coupled Nozzles in Gas Atomization Process

  • Unal, Rahmi
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.477-478
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    • 2006
  • Close-coupled atomizers are of great interest and controlling their performance parameters is critical for metal powder producing and spray forming industries. In this study, designed close-coupled nozzle systems were used to investigate the effect of the nozzle types and protrusion length of the melt delivery tube on the pressure formation at the melt delivery tube tip. The observed metal flow rate was not behaving as what was earlier assumed, namely that, deeper aspiration enhanced metal flow rate. Higher aspiration pressure at the tip of the melt delivery tube increases the stability of atomization process.

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Nanostructured Ni-Mn double hydroxide for high capacitance supercapacitor application

  • Pujari, Rahul B.;Lee, Dong-Weon
    • Journal of Sensor Science and Technology
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    • v.30 no.2
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    • pp.71-75
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    • 2021
  • Recently, transition-metal-based hydroxide materials have attracted significant attention in various electrochemical applications owing to their low cost, high stability, and versatility in composition and morphology. Among these applications, transition-metal-based hydroxides have exhibited significant potential in supercapacitors owing to their multiple redox states that can considerably enhance the supercapacitance performance. In this study, nanostructured Ni-Mn double hydroxide is directly grown on a conductive substrate using an electrodeposition method. Ni-Mn double hydroxide exhibits excellent electrochemical charge-storage properties in a 1 M KOH electrolyte, such as a specific capacitance of 1364 Fg-1 at a current density of 1 mAcm-2 and a capacitance retention of 94% over 3000 charge-discharge cycles at a current density of 10 mAcm-2. The present work demonstrates a scalable, time-saving, and cost-effective approach for the preparation of Ni-Mn double hydroxide with potential application in high-charge-storage kinetics, which can also be extended for other transition-metal-based double hydroxides.

Optimization of MIL-53 Metal-organic Framework Coatings for Enhanced Durability in Carbon Dioxide Capture (이산화탄소 포집 성능 향상을 위한 MIL-53 금속-유기 골격체 코팅의 최적화)

  • Dae-Hyeon Kim;Sung-Jun Lee;Dong-Gyu Ahn;Chang-Lae Kim
    • Transactions of Materials Processing
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    • v.33 no.4
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    • pp.261-269
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    • 2024
  • This study aimed to optimize the MIL-53 metal-organic framework coatings for enhanced durability in carbon dioxide capture applications. We synthesized MIL-53 powders using a hydrothermal method and deposited them on stainless-steel substrates by spin coating at various speeds, ranging from 300 to 2,000 rpm. The microstructure, surface properties, and tribological characteristics of the coatings were analyzed systematically. The results indicated that the spin speed significantly impacted the coating uniformity and defect formation. Coatings prepared at moderate speeds of 500 to 1,000 rpm exhibited optimal thickness and density, resulting in superior wear resistance. The tribological tests revealed that the coatings prepared at 700 to 1000 rpm had the lowest wear rates. These findings offer valuable insights for the development of durable MOF-based coatings for carbon dioxide capture and other applications requiring long-term stability under mechanical stress.

Thermo-Physical Properties of Some Coumarin Complexes

  • M. G. Abd El Wahed;K. El Manakhly;N. El Khososy;A. El Farargy
    • Bulletin of the Korean Chemical Society
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    • v.18 no.6
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    • pp.594-599
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    • 1997
  • A number of complexes of transition metal ions with some coumarin derivatives have been prepared and their structures were elucidated with the help of conductometric, photometric and infrared studies. The stability constants of various complexes were determined, in aqueous medium, at different temperatures potentiometrically. The thermodynamic characteristics, ΔG, ΔH and ΔS, were calculated. The electrical behaviour of prepared compounds was followed.

Preparation and Pore-Characteristics Control of Nano-Porous Materials using Organometallic Building Blocks

  • Oh, Gyu-Hwan;Park, Chong-Rae
    • Carbon letters
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    • v.4 no.1
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    • pp.1-9
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    • 2003
  • Recently, the control of pore-characteristics of nano-porous materials has been studied extensively because of their unique applications, which includes size-selective separation, gas adsorption/storage, heterogeneous catalysis, etc. The most widely adopted techniques for controlling pore characteristics include the utilization of pillar effect by metal oxide and of templates such as zeolites. More recently, coordination polymers constructed by transition metal ions and bridging organic ligands have afforded new types of nano-porous materials, porous metal-organic framework(porous MOF), with high degree and uniformity of porosity. The pore characteristics of these porous MOFs can be designed by controlling the coordination number and geometry of selected metal, e.g transition metal and rare-earth metal, and the size, rigidity, and coordination site of ligand. The synthesis of porous MOF by the assembly of metal ions with di-, tri-, and poly-topic N-bound organic linkers such as 4,4'-bipyridine(BPY) or multidentate linkers such as carboxylates, which allow for the formation of more rigid frameworks due to their ability to aggregate metal ions into M-O-C cluster, have been reported. Other porous MOF from co-ligand system or the ligand with both C-O and C-N type linkage can afford to control the shape and size of pores. Furthermore, for the rigidity and thermal stability of porous MOF, ring-type ligand such as porphyrin derivatives and ligands with ability of secondary bonding such as hydrogen and ionic bonding have been studied.

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Shape Optimization for Lightweight of the Metal 3D Printing Based Hybrid Machining Center (금속 적층 기반 하이브리드 머시닝센터의 경량화를 위한 형상 최적화에 관한 연구)

  • Jeong, Won-Young;Jeong, Ho-In;Lee, Choon-Man
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.2
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    • pp.80-85
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    • 2021
  • In the fourth industrial revolution, the demand for metal three-dimensional (3D) printing technology is rapidly increasing. Metal 3D printing is an efficient method for manufacturing products because the method reduces material waste compared to subtractive manufacturing. In addition, products with complex shapes, such as turbine blades, can be easily produced using metal 3D printing because the method offers a high degree of freedom. However, due to the long production time of metal 3D printing, mass production is impossible, and post-processing is necessary due to its low precision. Therefore, it is necessary to develop a new hybrid process that can efficiently process metals and to develop a metal 3D-printing-based hybrid processing system technology to secure high processing precision and manufacture complex shapes. In this study, the structural stability of a metal 3D printer based hybrid machining center was analyzed through structural analysis before its development. In addition, we proposed a design modification that can reduce the weight and increase the stiffness of the hybrid machining center by performing shape lightning based on the structural analysis results.