• Title/Summary/Keyword: metal separation

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Influence of counter anions on metal separation and water transport in electrodialysis treating plating wastewater

  • Oh, Eunjoo;Kim, Joohyeong;Ryu, Jun Hee;Min, Kyung Jin;Shin, Hyun-Gon;Park, Ki Young
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.201-206
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    • 2020
  • Electrodialysis (ED) is used in wastewater treatment, during the processing and recovery of beneficial materials, to produce usable water. In this study, sulfate and chlorine ions, which are the anions majorly used for electroplating, were studied as factors affecting the recovery of copper, nickel and water from wastewater by electrodialysis. Although the removal rates of copper and nickel ions were slightly higher with the use of chlorine ions than of sulfate ions, the removal efficiencies were above 99.9% under all experimental conditions. The metal ions of the plating wastewater flowed through the ion exchange membrane of the diluate tank and the concentrate tank while all the water moved together due to electro-osmosis. The migration of water from the diluate tank to the concentrate tank was higher in the presence of a monovalent chloride ion compared to that of a divalent sulfate ion. When sulfate was the anion used, the recoveries of copper and nickel increased by about 25% and 30%, respectively, as compared to the chloride ion. Therefore, when divalent ions such as sulfate are present in the electrodialysis, it is possible to reduce the movement amount of water and highly concentrate the copper and nickel in the plating wastewater.

Fundamental study on volume reduction of heavy metal-contaminated soil by magnetic separation

  • Konishi, Yusuke;Akiyama, Yoko;Manabe, Yuichiro;Sato, Fuminobu
    • Progress in Superconductivity and Cryogenics
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    • v.22 no.2
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    • pp.1-6
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    • 2020
  • Large-scale civil engineering works discharge a large amount of soil suspension contaminated with natural heavy metals. Most of the heavy metal ions due to industrial activities and minings are accumulated in the soils and the sediments of lakes and inner bays through the rivers. It is necessary to remove heavy metals from the soils and the sediments, because some of these heavy metals, such as arsenic and cadmium, have significant biological effects even in small amounts. This study proposes a new volume reduction method of the contaminated soils and sediments by superconducting magnetic separation. Our process can remove the specific minute minerals selectively, which adsorbs heavy metals depending on pH. As a fundamental study, the adsorption behaviors of arsenic and cadmium on minute minerals as a function of pH were investigated, and the adsorption mechanism was discussed based on the crystal structure and pH dependence of surface potential in each minute minerals.

A Study on the Scale-up of Highly Effective Copper Metal Recovery from Waste Jelly-filled Communication Cables (폐 젤리충진 통신케이블로부터 고순도 구리회수를 위한 대형화 방안 연구)

  • Cho, Sungsu;Lee, Sooyoung;Seo, Minhye;Uhm, Sunghyun
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.157-160
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    • 2014
  • We examined and compared the feasibility of vegetable oils with synthetic thermal conductive oils to recover highly purified copper metal from waste jelly-filled communication cables. While polydimethylsiloxane shows relatively poor separation efficiency under entire operating conditions, dibenzyltoluene and waste vegetable oil show the high separation efficiency if the appropriate operating temperature and time were given. By running 50 kg-class equipment with waste vegetable oils, we obtained 100% copper metal recovery with 99.2% purity at $300^{\circ}C$ for 60 min.

Superconducting magnetic separation of ground steel slag powder for recovery of resources

  • Kwon, H.W.;Kim, J.J.;Ha, D.W.;Choi, J.H.;Kim, Young-Hun
    • Progress in Superconductivity and Cryogenics
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    • v.19 no.1
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    • pp.22-25
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    • 2017
  • Steel slag has been considered as an industrial waste. A huge amount of slag is produced as a byproduct and the steel slag usually has been dumped in a landfill site. However the steel slag contains valuable resources such as iron, copper, manganese, and magnesium. Superconducting magnetic separation has been applied on recovery of the valuable resources from the steel slag and this process also has intended to reduce the waste to be dumped. Cryo-cooled Nb-Ti superconducting magnet with 100 mm bore and 600 mm of height was used as the magnetic separator. The separating efficiency was evaluated in the function of magnetic field. A steel slag was ground and analyzed for the composition. Iron containing minerals were successfully concentrated from less iron containing portion. The separation efficiency was highly dependent on the particle size giving higher separating efficiency with finer particle. The magnetic field also effects on the separation ratio. Current study showed that an appropriate grinding of slag and magnetic separation lead to the recovery of metal resources from steel slag waste rather than dumping all of the volume.

The Improvement of Storage Method for Spare Part of Turbine Bearing in Power Plants (발전소 터빈베어링 예비품 보관방법 개선)

  • Lee, Sung-Ho
    • Journal of the Korean Society for Nondestructive Testing
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    • v.12 no.2
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    • pp.30-35
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    • 1992
  • High quality of turbine babbit bearing has to be maintained for smooth operation of power plants. So in the research center of the Korea Electric Power Company, Ultrasonic testing has been peformed on the spare part of babbit bearing during past ten years. Since separation between babbit bearing and base metal was seen for most of the bearings in stock, investigation has begun in order to see the effect on temperature and humidity variation of the separation, and thus searching for the optimum storage method.

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