• Title/Summary/Keyword: metal salt

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Distribution of Zirconium Between Salt And Bismuth During A Separation From Rare Earth Elements By A Reductive Extraction

  • S. W. Kwon;Lee, B. J.;B. G. Ahn;Kim, E. H.;J. H. Yoo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.02a
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    • pp.165-169
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    • 2004
  • It was studied on the reductive extraction between the eutectic salt and Bi metal phases. The solutes were zirconium and the rare earth elements, where zirconium was used as the surrogate for the transuranic(TRU) elements. All the experiments were performed in a glove box filled with argon gas. Two types of experimental conditions were used -high and low initial solute concentrations in salt. Li-Bi alloy was used as a reducing agent to reduce the high chemical activity of Li. The reductive extraction characteristics were examined using ICP, XRD and EPMA analysis. Zirconium was successfully separated from the rare earth elements by the reductive extraction method. The LiF-NaF-KF system was favorable among the fluoride salt systems, whereas the LiCl-KCl system was favorable among the chloride salt systems. When the solute concentrations were high, intermetallic compounds were found near the salt-metal interface.

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Desulfurization of Sulfur Compounds in City-gas using Metal Salt Impregnated Zeolite (금속이온이 담지 된 제올라이트를 이용한 도시가스 내 부취제 제거)

  • Song, Hirn-Ill;Ko, Chang Hyun;Kim, Jae Chang;Kim, Jong-Nam
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.143-148
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    • 2007
  • In hydrogen production for fuel cell by reforming city-gas, sulfur compounds, odorant in city-gas, are detrimental to reforming catalyst and fuel cell electrodes. We prepared metal salt impregnated ${\beta}-zeolite(BEA)$ to remove sulfur compound in city-gas by adsorption. The sulfur breakthrough adsorption capacity was changed depending on the concentration and species of metal salt. $AgNO_3$ impregnated BEA showed the highest sulfur breakthrough capacity among adsorbents used in this experiment(41.1 mg/g). But metal salt impregnated BEA such as $Ni(NO_3)_2/BEA$, $Fe(NO_3_)_3/BEA$, $Co(NO_3)_2/BEA$ showed a certain amount of sulfur adsorption capacity comparable to $AgNO_3/BEA$. Adsorption temperature effect, desorption study, and x-ray photoelectron spectroscopy analysis revealed that the dominant interaction between metal impregnated adsorbent and sulfur compounds was not chemisorption but physisorption.

Preparation and Chrominance of Metal Oxide Coated Titania/Mica Pearlescent Pigment (금속산화물이 코팅된 마이카 티타니아 진주광택 안료의 제조 및 색차변화)

  • Lee, Kwan-Sik;Kang, Kuk-Hyoun;Lee, Jin-Hee;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.233-243
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    • 2013
  • The inorganic pearlescent pigment have high physical and chemical stability, thus it is used in a variety field, which has better light stability, solvent resistance and thermostability. In this paper, we were synthesized the pearlescent pigment for cosmetics which was coated cobalt chloride for base of blue color metal oxide on mica titania substrate using hydrothermal synthesis method. To complement the color of the pigment by cobalt, pearl pigment were coated by different metal salt and cobalt ratio, to implement a variety of color value, depending on the kind of metal salts were synthesized. Synthesized pearlescent pigments appear various color as kind of added metal salt precursor and molar ration of cobalt and other metals. We controlled coating and color by composition of metal salt and type of metal salts, and that confirm the pigment characteristics of color changes through the analysis of color difference meter. Synthesized pigment was characterized by SPM, SEM, XRD, and EDS.

Technical Trend of Plating & Surface Treatment for Eco-environment (친환경 도금표면처리 기술동향)

  • Kang, Kae-Myung;Kim, Yu-Sang
    • Journal of the Korean institute of surface engineering
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    • v.42 no.6
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    • pp.301-310
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    • 2009
  • Recently, it has been increasing for the eco-environment plating and surface treatment of eco-environment to decrease hazardous materials. Particular eco-environment can be applied to electronics or automotive parts of industry. In the case of mobile phone, if there were fired, the products bearing dye may be contaminated with the hazardous and wasted. we can obtain the original metal color by electro coloring by metal salt, get rid of hazardous gas, decrease the wasted sludges. Now, the industrial patent number is increasing in Korea, we can accomplish the development of green industry by supporting technical trend of the plating and surface treatment in eco-environment.

A Study on the Salt Intake Amounts of Manufacturing Workers in Pusan Area (부산지역 산업장 근로자들의 식염 섭취량에 관한 조사)

  • Kim, Don-Gyun;Lee, Su-Il;Jeong, Gap-Yeol;Lee, Chung-Ryeol;Lee, Yong-Hwan;So, Dong-Jin
    • 산업보건소식
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    • no.47
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    • pp.4-14
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    • 1987
  • The authors investigated estimated amounts of salt intake of workers in manufacturing industries who consisted of 1,506 males in 6 manufacturing fields and 476 females in 3 fields in Pusan area using filter paper method which was developed recently. The obtained results were as follows; 1. Mean excretion amounts of urinary electrolytes were Na 200.7 mEq/l, K 44.2 mEq/l and Cr 1.12g/l in male and Na 190.2 mEq/l, K 44.0 mEq/l and Cr 1.10g/1 in female. 2. Mean daily salt intake amounts were 19.4g in male and l5.3g in female. 3. By the fields of manufacturing industries in male, workers in metal product field had the highest salt intake as 20.0g, and the following were workers in food and tobacco field as 19.7g, workers in textile, wearing apparel and leather field as 19.6g in order. 4. In female, workers in textile, wearing apparel and leather field had the highest salt intake as l5.7g and the next were workers in chemical, coal and rubber products field as l5.0g and workers in fabricated metal products, machinery and equipments as l4.3g, respectively.

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SELECTIVE REDUCTION OF ACTIVE METAL CHLORIDES FROM MOLTEN LiCl-KCl USING LITHIUM DRAWDOWN

  • Simpson, Michael F.;Yoo, Tae-Sic;Labrier, Daniel;Lineberry, Michael;Shaltry, Michael;Phongikaroon, Supathorn
    • Nuclear Engineering and Technology
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    • v.44 no.7
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    • pp.767-772
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    • 2012
  • In support of optimizing electrorefining technology for treating spent nuclear fuel, lithium drawdown has been investigated for separating actinides from molten salt electrolyte. Drawdown reaction selectivity is a major issue that requires investigation, since the goal is to remove actinides while leaving the fission products and other components in the salt. A series of lithium drawdown tests with surrogate fission product chlorides was run to obtain selectivity data with non-radioactive salts, develop a predictive model, and draw conclusions about the viability of using this process with actinide-loaded salt. Results of tests with CsCl, $LaCl_3$, $CeCl_3$, and $NdCl_3$ are reported here. Equilibrium was typically achieved in less than 10 hours of contact between lithium metal and molten salt under well-stirred conditions. Maintaining low oxygen and water impurity concentrations (<10 ppm) in the atmosphere was observed to be critical to minimize side reactions and maintain stable salt compositions. An equilibrium model has been formulated and fit to the experimental data. Good fits to the data were achieved. Based on analysis and results obtained to date, it is concluded that clean separation between minor actinides and lanthanides will be difficult to achieve using lithium drawdown.

Studies on Heat Sensitivity of Egg Albumen II. Effects of pH and/or the Addition of Metal ions on Heat Sensitivity of Egg Albumen (난백의 숙감수성에 관한 연구 II. 금속염의 첨가와 pH가 난백의 열감수성에 미치는 영향)

  • 유익종;이성기;김영붕
    • Korean Journal of Poultry Science
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    • v.16 no.1
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    • pp.17-22
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    • 1989
  • In order to dull heat sensitivity of egg albumen, metal ions (aluminium, ferric, ferrous, copper) were added and functional properties or egg albumen were determined before and after heat treatment at $60^{\circ}C$ for 5 minutes. Effect of pH on heat sensitivity of aluminium salt added egg albumen was also determined. Addition of metal ions increased turbidity of egg albumen before and after the heat treatment. Changes of the turbidity were minimized by addition of aluminium salt. The foaming power was markedly increased by addition of ferric salt before the heat treatment and increased by addition of aluminium, ferric and copper salt after the heat treatment. Before the heat treatment the foam was stable by addition of ferric and ferrous salt but after the heat treatment it was stable by addition of aluminium and ferric salt. The turbidity and foaming property of the egg albumen with aluminium salt were not largely changed after the heat treatment at pH range 7 to 8.5. Over pH 9 the turbidity and foaming power were not decreased, but the foam stability was increased before and after the heat treatment. Salmonella typhimurium ATCC 14028 (10$^{6}$ cells/$m\ell$) inoculated in egg albumen at pH range 7 to 8.5 was destructed by the heat treatment.

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Heat Balance during the Electrowinning of Neodymium Metal in Molten Salt (네오디뮴 금속의 전해 채취 중의 열수지)

  • Cho, Sung-Wook;Yu, Jeong-Hyun;Choi, Ho-Gil
    • Resources Recycling
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    • v.31 no.3
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    • pp.81-87
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    • 2022
  • Energy consumption per unit weight of metal (kwh/kg of metal) is one of the most important economic indicators in the process of molten salt electrolysis. It is related to the heat loss of salt bath and the current efficiency of the process. The current efficiency is highly dependent on electrolysis temperature. On the other hand, the temperature of salt bath may increase significantly due to the difference (larger energy input than consumption) in heat balance at the beginning of electrolysis, which may cause different electrolysis temperature from an initially targeted value. This results in a bad effect on current efficiency. Therefore, it will be helpful to the reduction of energy consumption to compare the calculated and measured values of the temperature change of salt bath through the heat balance review at the early stage of electrolysis and to evaluate the energy loss to outside. In this study, based on the authors' experimental data, the heat balance was reviewed at the beginning of the electrolysis, and it was possible to evaluate the energy loss to the outside and the increase of the temperature of the salt bath quantitatively. Through such a method, heat loss reduction plan can be derived and current efficiency can be improved so that energy consumption can be reduced.