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금속산화물이 코팅된 마이카 티타니아 진주광택 안료의 제조 및 색차변화

Preparation and Chrominance of Metal Oxide Coated Titania/Mica Pearlescent Pigment

  • 이관식 (충북대학교 공과대학 공업화학과) ;
  • 강국현 (충북대학교 공과대학 공업화학과) ;
  • 이진희 (충북대학교 공과대학 공업화학과) ;
  • 이동규 (충북대학교 공과대학 공업화학과)
  • Lee, Kwan-Sik (Department of Engineering Chemistry, Chungbuk National University) ;
  • Kang, Kuk-Hyoun (Department of Engineering Chemistry, Chungbuk National University) ;
  • Lee, Jin-Hee (Department of Engineering Chemistry, Chungbuk National University) ;
  • Lee, Dong-Kyu (Department of Engineering Chemistry, Chungbuk National University)
  • 투고 : 2013.04.18
  • 심사 : 2013.06.27
  • 발행 : 2013.06.30

초록

무지개 빛을 내는 무기진주광택안료는, 내광성, 내용제성 및 내열성 등이 물리적 화학적 안정성이 우수하여 다양한 분야에서 응용되고 있다. 본 연구는 수열합성방법을 사용하여 마이카 티타니아에 파란색 코팅 안료인 염화코발트를 기본으로 화장품 안료로 사용되는 진주광택안료를 합성하였다. 코발트에 의한 안료의 색상을 보완하고자 코발트와 금속 염의 비를 달리하여 안료를 코팅하고, 이를 통해 금속염의 종류에 따라 다양한 색차값을 구현하는 진주광택 안료를 합성하였다. 코발트와 첨가된 금속 염 전구체의 조성비와, 금속 염의 종류에 따라 코팅 특성과 색상을 조절할 수 있었고, 안료의 다양한 색상변화 특성을 색차계를 통해 확인 하였다. 합성된 안료는 SPM, SEM, XRD, EDS 기기를 통해 특성을 분석하였다.

The inorganic pearlescent pigment have high physical and chemical stability, thus it is used in a variety field, which has better light stability, solvent resistance and thermostability. In this paper, we were synthesized the pearlescent pigment for cosmetics which was coated cobalt chloride for base of blue color metal oxide on mica titania substrate using hydrothermal synthesis method. To complement the color of the pigment by cobalt, pearl pigment were coated by different metal salt and cobalt ratio, to implement a variety of color value, depending on the kind of metal salts were synthesized. Synthesized pearlescent pigments appear various color as kind of added metal salt precursor and molar ration of cobalt and other metals. We controlled coating and color by composition of metal salt and type of metal salts, and that confirm the pigment characteristics of color changes through the analysis of color difference meter. Synthesized pigment was characterized by SPM, SEM, XRD, and EDS.

키워드

참고문헌

  1. D. Thetford, A.P. Chorlton, J. Mason, "Investigation of 1,1',5,1" -trianthrimide as a potential high pearformance pigment", Dyes and Pigm., 62, 235 (2004). https://doi.org/10.1016/j.dyepig.2003.12.009
  2. M. Robert, Christie, D. Bruce, Howie, "Potential alternatives for 3,3'-dichlorobenzidine as tetrazo componentsfor diarylide yellow and orange pigments, Part 1: p-phenylenediamine and its derivatives", Dyes and Pigm., 80, 245 (2009). https://doi.org/10.1016/j.dyepig.2008.07.006
  3. V. S. Vishnu, G. Giable, V. Divya, M. L. P. Reddy, "Synthesis and characterization of mew environmentally benign tantalumdoped $Ce_{0.8}Zr_{0.2}O_{2} $yellow pigment: Application in coloring of plastics", Dyes and Pigm., 82, 53 (2009). https://doi.org/10.1016/j.dyepig.2008.11.001
  4. Y. C. Zhang, H. Q. Ye, H. Liu, "Preparation and characterization of blue color aluminium pigments $Al/SiO_{2}/PB $ with double-layer structure", Powder Technol., 217, 614 (2012). https://doi.org/10.1016/j.powtec.2011.11.035
  5. H. A. Kwak, E. Y. Choi, B. S. Chang, "Characteristics of pearlescent Pigment using in Make-up Cosmetics", Korean J. Microscopy, 39, 41 (2009).
  6. M. Patricia, C. C. Tenorio, D. Michele, G. R. Guia, M. Fernanda, Barros, B. D. L. Adao, "Ceramic application of mica titania pearlescent pigments", Dyes and Pigm., 74, 1 (2007). https://doi.org/10.1016/j.dyepig.2006.01.026
  7. D. K. Lee, J. H. Lee, S. Y. Park, "Preparation and Characteristics of Carmine coated Mica Pearlescent Pigment", J. of the Korean Oil Chemists' Soc., 25, 511 (2008).
  8. J. R. Tan, Fu, Xiansong, W. X. Hou, X. Z. Chen, L. Wang, "The preparation and characteristics of a multi-cover-layer type, blue mica titania, pearlecsent pigment", Dyes and Pigm., 56, 93 (2003). https://doi.org/10.1016/S0143-7208(02)00103-1
  9. H. W. Lee, S. H. Kang, D. K. Nam, "Characteristics of Inorganic Pigments Used for Cosmetics", J. of the Korean Oil Chemists' Soc., vol. 11, 2 7 (1994)
  10. C. Jing, S. X. Hanbing, "The prearation and characteristics of cobalt blue colored mica titania pearlescent pigment by microemulsions", vol. 75, 3 766 (2007). https://doi.org/10.1016/j.dyepig.2006.08.020
  11. J. W. Jun, J. H. Min, K. H. Kim, C. H. Kwak, T. S. Suh, "Preparation on the pearlescent pigment $TiO_{2}$coated mica and their optical properties", Theories and Application of chem. Eng., 1, 903 (1995).
  12. B. B. Topuz, Gunduz, B. Mavis, U. Colak, "The effect of thin dioxide($SnO_{2}$) on the anatase-rutile phase transformation of titania ($TiO_{2}$) in mica-titania pigments and their use in paint", Dyes Pigm., 90, 123 (2011). https://doi.org/10.1016/j.dyepig.2010.12.013
  13. M. R. Tohidifar, E. Taheri-Nassaj, P. Alizadeh, "Optimization of the synthesis of a nano-sized mica-hematite pearlescent pigment", Mater. Chem. Phys., 109, 137 (2008). https://doi.org/10.1016/j.matchemphys.2007.11.004
  14. P. M. T. Cavalcante, M. Dondi, G. Guarini, M. raimondo, G. Baldi, "Colour performance of ceramic nano-pigments", Dyes Pigm., 80, 226 (2009). https://doi.org/10.1016/j.dyepig.2008.07.004
  15. J. S. Choi, K. H. Kang, D. K. Lee, "Preparation of cobalt blue coated titania/mica pearlescent pigment by microemulsion method", Industrial Science and Technology Institute, 25, 77 (2011).
  16. K. S. Lee, D. K. Lee, "Synthesis and Characteristic of Ferric Ferrocyanide Coated Titania/Mica Pearlescent Pigments by Hydrothermal Synthesis Method", J. of the Korean Oil Chemists' Soc., 3, 335 (2011).
  17. J. R. Tan, L. Z. Shen, X. S. Fu, W. X. Hou, X. Z. Chen, "Preparation and Conductive Mechanism of Mica Titania Conductive Pigment", Dyes and Pigments 62, 107 (2004). https://doi.org/10.1016/j.dyepig.2003.08.001
  18. H. Y. Du, C. X. Liu, J. Y. Sun, Q. R. Chen, "An investigation of andgle-dependent optical properties of multi-layer structure pigments formed by metal-oxide-coated mica", Powder Technol., 185, 291 (2008). https://doi.org/10.1016/j.powtec.2007.10.031

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  2. 산화마그네슘을 코팅한 마이카의 헤이즈 특성 vol.16, pp.1, 2015, https://doi.org/10.5762/kais.2015.16.1.888
  3. 무기안료를 이용한 인공진주 코팅 및 제조 vol.32, pp.3, 2013, https://doi.org/10.12925/jkocs.2015.32.3.528
  4. CVD법을 이용한 적색 인조진주 코팅 및 제조 vol.35, pp.3, 2018, https://doi.org/10.12925/jkocs.2018.35.3.857