• Journal of the Korean institute of surface engineering
• /
• v.54 no.6
• /
• pp.365-370
• /
• 2021

In this research, we proceeded with research on plasma resistance of the cleaning process of APS(Atmospheric Plasma Spray)-Y₂O₃ coated parts used for semiconductor and display plasma process equipment. CF₄, O₂, and Ar mixed gas were used for the plasma environment, and respective alconox, surfactant, and piranha solution was used for the cleaning process. After APS-Y₂O₃ was exposed to CF₄ plasma, the surface changed from Y₂O₃ to YF₃ and a large amount of carbon was deposited. For this reason, the plasma corrosion resistance was lowered and contamination particles were generated. We performed a cleaning process to remove the defect-inducing surface YF₃ layer and carbon layer. Among three cleaning solutions, the piranha cleaning process had the highest detergency and the alconox cleaning process had the lowest detergency. Such results could be confirmed through the etching amount, morphology, composition, and accumulated contamination particle analysis results. Piranha cleaning process showed the highest detergency, but due to the very large thickness reduction, the base metal was exposed and a large number of contaminated particles were generated. In contrast, the surfactant cleaning process exhibit excellent properties in terms of surface detergency, etching amount, and accumulated contamination particle analysis.

• Progress in Superconductivity and Cryogenics
• /
• v.23 no.4
• /
• pp.14-18
• /
• 2021

The Mg-Powder-Compaction (MPC) process is proposed to fabricate the MgB₂ superconducting wires. Mg powder wall, similar to the Mg metal tube, inside the Nb outer sheath has been made and the stochiometric B powder was inserted into the wall. Even though the very high MgB₂ core density of 2.53 g/cm³ is obtained, the superconducting area fraction of MgB₂ is not high enough for the applications. In this work, an advanced MPC process was adopted by adding Mg powder into B powder. The Mg powder wall in the initial wire was fabricated by controlling the wall thickness while maintaining a constant density, and the mixture of B and Mg powder was filled into the Mg powder wall with the same filling density. It is found that the reduction in the area of the Mg powder wall proceeds similar to the wire, and the Mg powder wall is well maintained at the final wire diameter, which is advantage for the fabrication of long wires. With the advanced MPC process, as the added Mg is increased the densities of MgB₂ core is decreased and the porous structure is formed, it is found that the area fraction of superconducting MgB₂ increase up to the 37.7 % with the improved high critical current density (J_c) and the engineering critical current density (J_e).

• Resources Recycling
• /
• v.30 no.1
• /
• pp.77-82
• /
• 2021

Reduction of CO2 emissions is an important issue in the steel industry, and the research on carbon materials that can partially replace cokes is necessary to reduce CO2 emissions. Meanwhile, the biomass fuel contains some fixed carbon, and the carbon content in the biomass can be increased by torrefaction. As one of the biomass fuels, coffee grounds contains about 55 mass% of carbon, and its about 270,000 tons are landfilled and incinerated annually in Korea. In addition, research on the recycling process due to the increase in annual coffee consumption is required. In this study, the effect of temperature on the concentration of fixed carbon in coffee grounds was investigated during torrefaction. Moreover, the effects of mixing ratio of torrefied coffee grounds with cokes on the carbon concentration and dissolution efficiency in the metal sample were investigated.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.32 no.1
• /
• pp.78-85
• /
• 2019

The effect of various lithium sources such as LiCl, LiOH, and Li-metal on the microstructure and electrochemical properties of granulated $SiO_x$ powders were investigated. Various lithium sources were metallurgically added for a passive pre-lithiation of $SiO_x$ to improve its low initial coulombic efficiency. In spite of using the same amount of Li in various sources, as well as the same process conditions, different lithium silicates were obtained. Moreover, irreversible phases were formed without reduction of $SiO_x$, which might be from additional oxygen incorporation during the process. Accordingly, there were no noticeable electrochemical enhancements. Nevertheless, the $Li_4SiO_4$ phase changes the initial electrochemical reaction, and consequently the relationship between the microstructure and electrochemical properties of metallurgically pre-lithiated $SiO_x$ could provide a guideline for the optimization of the performance of lithium ion batteries.

• Steel and Composite Structures
• /
• v.32 no.5
• /
• pp.571-582
• /
• 2019

This study aimed to assess the feasibility on the wide and long 9%Ni steel plate for use in the LNG storage inner tank shell. First, 5-m-wide and 15-m-long 9%Ni steel plates were test manufactured from a steel mill and specimens taken from the plates were tested for strength, toughness, and flatness to verify their performance based on international standards and design specifications. Second, plates with a thickness of 10 mm and 25 mm, a width of 4.8~5.0 m, and a length of 15 m were test fabricated by subjecting to pretreatment, beveling, and roll bending resulting in a final width of 4.5~4.8 m and a length of 14.8m with fabrication errors identical to conventional plates. Third, welded specimens obtained via shield metal arc welding used for vertical welding of inner tank shell and submerged arc welding used for horizontal welding were also tested for strength, toughness and ductility. Fourth, verification of shell plate material and fabrication was followed by test erection using two 25-mm-thick, 4.5-m-wide and 14.8-m-long 9%Ni steel plates. No undesirable welding failure or deformation was found. Finally, parametric design using wide and long 9%Ni steel plates was carried out, and a simplified design method to determine the plate thickness along the shell height was proposed. The cost analysis based on the parametric design resulted in about 2% increase of steel weight; however, the construction cost was reduced about 6% due to large reduction in welding work.

• Design & Manufacturing
• /
• v.13 no.1
• /
• pp.5-12
• /
• 2019

In this paper, we studied the micro tool deflection, micro cutting with low temperature, and deformation of micro ribs caused by cutting forces. First, we performed an integrated machining error compensation method based on captured images of tool deflection shapes in micro cutting process. In micro cutting process, micro tool deflection generates very serious problems in contrast to macro tool deflection. To get the real images of micro tool deflection, it is possible to estimate tool deflection in cutting conditions modeled and to compensate for machining errors using an iterative algorithm correcting tool path. Second, in macro cutting fields, the cryogenic cutting process has been applied to cut the refractory metal but, the serious problem may be generated in micro cutting fields by the cryogenic environment. However, if the proper low temperature is applied to micro cutting area, the cooling effect of cutting heat is expected. Such effect can make the reduction of tool wear and burr formation. For verifying this passibility, the micro cutting experiment at low temperature was performed and SEM images were analyzed. Third, the micro pattern was deformed by the cutting forces and the shape error occurred in the sidewall multi-step cutting process were minimized. As the results, the relationship between the cutting conditions and the deformation of micro-structure during micro cutting process was investigated.

• Transactions of Materials Processing
• /
• v.27 no.6
• /
• pp.347-355
• /
• 2018

This study investigated the effects of the processing number of multi-axial diagonal forging (MADF) on the microstructural changes of OFC fabricated by MADF processes. The as-extruded OFC was cut to $25mm^3$ cube for the MADF processes. The MADF process consists of plane forging with a thickness reduction of 30% and diagonal forging with a diagonal forging angle of $135^{\circ}$. In order to analyze the microstructural evolutions according to the number of repetitions, 1, 2, 3 and 4 cycles of the MADF process were performed. OFC specimens were successfully deformed without surface cracking for up to 4 cycles of MADF. The grain size, average misorientation and average grain orientation spread (GOS) of MADF processed materials were analyzed using EBSD technique and their Vicker's hardness were also measured. The results showed that MADF process effectively refined the microstructure of OFC with initial average grain size of $84.2{\mu}m$. The average grain sizes of specimens MADF processed for 1, 2, 3, 4 cycles were refined to be $8.5{\mu}m$, $2.2{\mu}m$, $1.5{\mu}m$, $1.1{\mu}m$, respectively. The grain refinement seemed to be saturated when OFC was MADF processed over 2 cycles. In the case of specimens subjected to two or more cycles of MADF, the degree of decrease in average grain size was drastically reduced as the number of cycles increased due to softening phenomena such as dynamic recovery or dynamic recrystallization during processing. The degree of increase in average Vicker's hardness was also dramatically reduced as the number of cycles increased due to the same reason.

• Journal of Korean Foot and Ankle Society
• /
• v.22 no.3
• /
• pp.95-99
• /
• 2018

Purpose: The purpose of this study was to evaluate the radiologic outcomes of distal fibular fractures and to analyze the risk factors associated with nonunion. Materials and Methods: Between January 2009 and March 2016, 13 patients who had final nonunion with ankle fracture were included. In the control group, 370 patients who had undergone bony union and removed metal implants were included. All patients underwent the same surgical procedure and had the same treatment method, ultimately achieving satisfactory open reduction results with less than 2 mm fracture gap. Surgical treatment of fracture was considered to have the same effect on nonunion, and factors that might be associated with nonunion were evaluated. SPSS ver. 13.0 (SPSS Inc., USA) was used for all statistical analyses. Pearson's chi-square test and multi-variate regression analysis were performed to determine the factors affecting nonunion of distal fibular fracture. A p-value less than 0.05 was considered statistically significant, and relative risk was assessed. Results: The mean age of 13 patients was 46.9 years (range, 16~57 years); there were 8 men and 5 women. Among the 13 patients with nonunion, atrophic was the most common (12 cases). The association between the injury mechanism and the Lauge-Hansen classification and diabetes mellitus was not statistically significant. Distal fibular fractures with tibia shaft fracture (p=0.015) and Danis-Weber type C fracture (p=0.023), open fracture (p=0.011), and smoking (p=0.023) were significantly associated with nonunion. Conclusion: In this study, the combined injury of the ipsilateral tibia shaft fracture, open fracture, and Danis-Weber type C fracture may increase the possibility of nonunion. Therefore, caution is advised to prevent nonunion.

• Transactions of Materials Processing
• /
• v.28 no.2
• /
• pp.63-70
• /
• 2019

This study investigates the effects of multi-axial diagonal forging (MADF) processing number on the microstructures of AA1100 fabricated using MADF processes. The cast AA1100 was annealed at $400^{\circ}C$ for 3hrs in $N_2$ atmosphere and cut into $25mm^3$ cubes for the MADF processes. The MADF process consist of plane forging with a thickness reduction of 30% and a diagonal forging with a diagonal forging angle of 135 degrees. In order to analyze the microstructural variations based on the number of repetitions, 1, 2, 3 and 4 cycles of the MADF process were performed. AA1100 specimens were successfully deformed without cracking of the surface for up to 4 cycles of MADF. The grain size, average misorientation and average grain orientation spread (GOS) of MADF processed materials were analyzed using EBSD technique. The results showed that MADF process effectively refined the microstructure of AA1100 with an initial average grain size of $337.4{\mu}m$. The average grain sizes of specimens which were MADF processed for 2, 3, 4 cycles were refined to be $1.9{\mu}m$, $1.6{\mu}m$, $1.4{\mu}m$, respectively. The grain refinement appeared saturated when AA1100 got MADF processed over 2 cycles. When the specimen was subjected to two or more cycles of MADF, the degree of decrease in the average grain size drastically decreased with an increase in the number of cycle due to the softening phenomena such as dynamic recovery or dynamic recrystallization during processing.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.20 no.5
• /
• pp.69-75
• /
• 2021

Fuel economy has always been a major issue for the automotive industry due to environmental concerns. In particular, it is known that only 5-20% of the energy generated in a car that mainly uses an internal combustion engine is converted to increase fuel efficiency, many methods have been proposed. Among these methods, weight reduction is most commonly used because it is the simplest and cheapest. Weight is always the main reason for energy consumption, therefore, reducing weight is the best way to increase fuel efficiency while simultaneously saving on material costs. To reduce the weight of a compressor, material substitution is used. However, aluminum (a lighter metal substitute) is more fragile than steel, therefore, structural stability must be verified through testing. In this paper, we performed a 3D analysis to investigate whether aluminum can be used without compromising structural stability. Our investigation included static analysis and thermal analysis. As a result, we found that an aluminum swash plate can be safely applied on a shaft instead of steel; it reduces weight while maintaining stability that is equal to or better than steel.