• Title/Summary/Keyword: metal products

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Heavy Metal Adsorption Characteristics and Produced of Food Waste Activated Carbon (음식물류 폐기물 활성탄의 제조 및 중금속 흡착특성)

  • Lee, Jun-Hee;Lee, Seung-Chul;Ju, Min;Kim, Ji-Hye;Lee, Don-Gil
    • Journal of Environmental Science International
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    • v.24 no.12
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    • pp.1601-1608
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    • 2015
  • This study evaluates heavy metal(Cu and Cr) adsorption characteristics produced from food waste charcoal extracted in an optimal operation condition after analyzing activated charcoal of iodine adsorption and heavy metals that derived from an activation process of carbide by the developed by-products of food waste treatment facility using the methods from previous studies. As experiment apparatus, this study used a tube-shaped high temp furnace. The mixing ratio of by-products of food waste treatment facility, carbide, and activation component($ZnCl_2$) was 1:1. The experiment was proceeded as adjusting the activation temperature from 400 to $800^{\circ}C$ and activation time from 30 to 120 minutes. The optimal activation condition for iodine absorption was 90 minutes at $700^{\circ}C$ and by using the produced food waste charcoal, this study conducted an experiment on absorption of heavy metals (Cu and Cr) as changing pH of artificial wastewater and stirring time. As a result, pH 7 showed the highest heavy metal decontamination ratio and in terms of stirring time, it revealed balance adsorption after 10 minutes. This result can be particularly applied as basic data for recyclability of high concentration organic waste, by-products of food waste treatment facility, as an food waste charcoal.

Comparative Study of Hazardous Heavy Metal Contents by Cosmetic Type (화장품 유형별 유해 중금속 함량 비교 연구)

  • Lee, Jin hee;Kim, Ji Yeon;Park, Sang Gyu;Lee, Jae Ho;Yoon, Jong Ho;Kim, Gyoung Tae;Kim, Hae Jung
    • Journal of Environmental Health Sciences
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    • v.45 no.2
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    • pp.154-163
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    • 2019
  • Objectives: The hazardous heavy metal contents of cosmetics were investigated and the resulting values were compared by type of cosmetics: skin care preparations (SCP), hair preparations (HP), makeup preparations (MP), and eye makeup preparations (EMP). Methods: The hazardous heavy metal contents (Pb, As, Cd, Sb, Ni and Hg) were analyzed for 358 cosmetics products (187 SCP, 82 HP, 56 MP, and 33 EMP). Hg was measured by the amalgamation method, and other hazardous heavy metals were measured by inductively coupled plasma optical emission spectrometer (ICP-OES) after decomposition using the microwave method. Results: The mean contents of Pb, As, Cd, Sb, Ni, and Hg in cosmetics were 0.424, 0.068, 0.024, 0.398, $0.567{\mu}/g$, and Not Detected, respectively. All of the hazardous heavy metals were detected in most products, but below the recommended maximums of the Ministry of Food and Drug Safety. The level of Cd was the lowest at 14.8%, and Sb was the highest at 41.2%. Pb, Sb and Ni showed the highest mean value and detection rate in EMP. As, Cd, and Hg showed the highest in SCP, HP, and MP, respectively. Conclusion: Hazardous heavy metals were detected in most products. In particular, Pb, Sb, and Ni were broadly detected in EMP, meaning more stringent quality control is required.

A Study on Heavy Metal and Selenium Levels in Dried Seafoods (건조수산물의 중금속 및 셀레늄 함량)

  • Kwon, Hye-Jung;Kim, Ki-Cheol;Kim, Kyung-A;Kim, Young-Su;Kang, Suk-Ho;Kwak, Shin-Hye;Kang, Kyung-Ja;Lee, Pil-Suk;Cho, Wook-Hyun;Moh, Ara;Park, Yong-Bae
    • Journal of Food Hygiene and Safety
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    • v.34 no.6
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    • pp.562-570
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    • 2019
  • The heavy metal concentrations in dried seafoods commonly consumed in Gyeonggi-do were analyzed. Concentrations of lead (Pb), cadmium (Cd), mercury (Hg) and selenium (Se) were measured in 95 samples with an inductively-coupled plasma-mass spectrometer (ICP-MS) and an Hg analyzer. The average concentration [mean±SD(minimum-maximum) mg/kg] of heavy metals were as follows: Pb 0.062±0.071(0.002-0.428), Cd 0.083±0.100(0.004-0.540), Hg 0.012±0.012(N.D-0.054) and Se 0.839±0.371(0.362-2.124). All the levels were below the recommended standards of the MFDS (Ministry of Food and Drug Safety). In the comparison of heavy metal content by anchovy size, it was shown that mercury was significantly higher in large anchovy (P<0.05). Selenium levels were found to differ significantly in small anchovy and large anchovy (P<0.05). Pb, Cd and Hg were significantly higher in Tiger prawn among shrimp (P<0.05). The heavy metal and selenium levels of anchovy and shad were highest in the intestine. However, the heavy metal and selenium levels of shrimp were highest in the head. In addition, weekly (monthly) intake of mercury and cadmium from dried seafoods was found to be 0.712% and 2.978% of PTW(M)I (Provisional Tolerable Weekly(Monthly) Intake) respectively. Therefore, it was found that dried seafoods were safe for consumption.

A Study on Metal Concentrations in the Air of Metal Products Manufacturing Industry (금속제품 제조 산업장내 공기중 금속농도에 관한 연구)

  • Kang, Yong Seon;Kim, Se Dong;Ku, Tae Hyeong;Yoon, Hyeong Ryeol;Moon, Deog Hwan;Han, Yong Soo
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.6 no.2
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    • pp.249-264
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    • 1996
  • This study was conducted for the purpose of obtaining the fundamental data on improvement of working environment and contributing to health improvement of workers who dealed with metal by assessing the metal concentration in air of industries located in Chang-Won Industrial Complex. Authors measured the concentration of metals(Al, Cd, Cr, Cu, Mn, Ni, Pb, Sn and Zn) is the air to 25 working processes of 73 industries by flame atomic absorption spectrometry from February to December 1994. Personal air sampler was used for air sampling with mixed cellulose-ester membrane filter. The results were as follows : 1. The geometric means(range) of metal concentration; 1) Al: $0.1505mg/m^3$ ($0.0147-18.6100mg/m^3$) 2) Cd: $0.0077mg/m^3$ ($0.0003-7.0710mg/m^3$) 3) Cr: $0.0163mg/m^3$ ($0.0013-1.1510mg/m^3$) 4) Cu: $0.0097mg/m^3$ ($0.0009-0.4950mg/m^3$) 5) Mn: $0.0412mg/m^3$ ($0.0006-4.7877mg/m^3$) 6) Ni: $0.0088mg/m^3$ ($0.0001-1.0170mg/m^3$) 7) Pb: $0.0152mg/m^3$ ($0.0015-0.4499mg/m^3$) 8) Sn: $0.0486mg/m^3$ ($0.0037-0.1500mg/m^3$) 9) Zn: $0.1911mg/m^3$ ($0.0122-8.2920mg/m^3$) 2. The geometric mean of lead exceeded TWA in assembling process of other general purpose machinery not elsewhere classified products manufacturing industries.

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Novel solvothermal approach to hydrophilic nanoparticles of late transition elements and its evaluation by nanoparticle tracking analysis

  • Dutilleul, Marion Collart;Seisenbaeva, Gulaim A.;Kessler, Vadim G.
    • Advances in nano research
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    • v.2 no.2
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    • pp.77-88
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    • 2014
  • Solvothermal treatment of late transition metal acetylacetonates in a novel medium composed either of pure acetophenone or acetophenone mixtures with amino alcohols offers a general approach to uniform hydrophilic metal nanoparticles with high crystallinity and low degree of aggregation. Both pure metal and mixed-metal particles can be accesses by this approach. The produced materials have been characterized by SEM-EDS, TEM, FTIR in the solid state and by Nanoparticle Tracking Analysis in solutions. The chemical mechanisms of the reactions producing nanoparticles has been followed by NMR. Carrying out the process in pure acetophenone produces palladium metal, copper metal with minor impurity of $Cu_2O$, and NiO. The synthesis starting from the mixtures of Pd and Ni acetylacetonates with up to 20 mol% of Pd, renders in minor yield the palladium-based metal alloy along with nickel oxide as the major phase. Even the synthesis starting from a mixed solution of $Cu(acac)_2$ and $Ni(acac)_2$ produces oxides as major products. The situation is improved when aminoalcohols such as 2-aminoethanol or 2-dimethylamino propanol are added to the synthesis medium. The particles in this case contain metallic elements and pairs of individual metals (not metal alloys) when produced from mixed precursor solutions in this case.

Microstructure and Mechanical Properties of TiC-Co/Al Composites Prepared by Reaction-Bonded Sintering (반응결합 소결에 의한 TiC-Co/Al 복합체의 미세구조 및 기계적 특성)

  • 한인섭;남기웅;정윤중
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.257-269
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    • 1995
  • The TiC-Co/Al reaction-sintered products were prepared by the infiltration of various Co/Al metal mixture into the preform, and their microstructure, phases, and mechanical properties were investigated. With increasing the atomic ratio of Co/Al, tiC grain shape was changed from spherical to platelet particles, and the grain size increased. The crystalline phases found in the liquid matrix formed by the infiltration of Co/Al metal mixture were determined to be Al5Co2 and AlCo by EDS and XRD, and the two crystalline phases were located dominantly between TiC grains, when the Co/Al atomic ratio was lower than an unity. There was a tendency that the density, bending strength and fracture toughness increase with Co/Al atomic ratio until the infiltrated metal was 100% Co. The maximum value was achieved by the composition containing 100% Co infiltrated metal. The Vickers hardness decreased as Co/Al atomic ratio increased.

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The Research of Scratch Characteristics For Non-Vinyl Pre-Coated Metal Sheet (Non-Vinyl Pre-Coated Metal의 스크래치 특성에 관한 연구)

  • 김동환;조형근;김병민
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.05a
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    • pp.874-877
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    • 2000
  • Pre-coated sheet materials are a cost-effective and environmentally attractive alternative to conventional sheet materials coated after forming. At present but the high scratch sensitivity of coating used for pre-coated metal sheet is a major limitation to use of these materials. Because of high scratch sensitivity, products made by pre-coated metal sheet are not formed by conventional design method. This study has been performed to investigate scratch characteristic of non-vinyl pre-coated metal (PCM) sheet. Using the simple U-bending test equipment, three non-vinyls PCM's were tested. This paper provides the results of bending tests showing the influence of sheet surface texture, tool material and process conditions. It was found that the influence of punch, die clearance and tool material had an effect upon the scratch characteristic.

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Mechanical Characteristics Evaluation of Metal Matrix Composites Cylinder Linear Fabricated by Thixoforging Process (Thixoforging Process에 의하여 제조한 금속복합재료 실린더라이너 부품의 기계적 특성 평가)

  • 허재찬;이승후;강충길
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.2
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    • pp.58-65
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    • 2003
  • The conventional forming process such as squeeze casting or die casting for fabricating metal matrix composites products have a disadvantage such as non homogenous distribution of reinforcement, weak bonding between matrix and reinforcement and cost increase in parts fabrication. Thixoforming process has been accepted as a new method for fabricating the net shaped metal matrix composites with lightweight and wear resistance. In this paper, the effect of volume fraction and reinforcement sizes on mechanical properties in cylinder liner part of metal matrix composites has been investigated with processes parameters such as pressure and velocity. Moreover, the methods to obtain the thixoforged composites cylinder liner with high quality has been proposed. To evaluate the composites cylinder linear fabricated at the conditions proposed in this study, mechanical properties of fabricated composites cylinder linear were compared with those of commercial composites cylinder linear.

A Study on the Design of a Rotational Force Generator for Molten Metal (용탕 회전력 생성장치의 설계에 관한 연구)

  • Lee, Jun-Ho
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.21 no.3
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    • pp.493-501
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    • 2012
  • A rotational force generator for molten metal is developed using a linear motor design technology. Also, the developed device is applied to reproduce aluminum scraps and easy to control the rotate, stop, and forward and reverse rotation of molten metal. In addition, the developed device improves the melting speed and reproduction rate about 250 (%) and 96-99 (%), respectively, compared to the conventional handmade methods. Because it generates almost no dusts, it can improve working environments in a factory. Also, it has no losses in energy because it directly melts scraps. The device generates small amounts of the loss in refractory materials and aluminum caused by its oxidation because the molten metal is continuously rotated in which the loss and oxidized aluminum are the problems in the conventional melting and holding furnaces. Thus, it is possible to extend the life of furnaces and to produce high quality aluminum products.