• Journal of Soil and Groundwater Environment
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• v.21 no.6
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• pp.169-178
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• 2016

The Standards, Measurement and Testing Programme (SM&T-formerly BCR) extraction procedure was applied to fractionate Cr, Cu, Ni, Pb and Zn in 23 top soil samples into: (i) exchangeable phase; (ii) reducible phase; (iii) oxidisable(sulfides and organics bound) phase; and (iv) residual phase. Fractions of Cr and Ni were in the order of residual > oxidisable > reducible > exchangeable phase. The oxidisable phase was identified as dominant for Cu and Pb. Zn had the highest ratio of exchangeable phase in comparision to the other metals. The bioavailability and mobility were assessed to be the greatest for Zn, followed by a decreasing order of Pb, Cu, Ni and Cr. All metal average concentrations in topsoil samples was higher in industrial sites than in agricultural sites. Our results revealed higher concentrations in topsoil samples (0~15 cm) than in sub soils (15~30 cm, 30~60 cm) for most metals at six sites (No. 5, 6, 17, 19, 20, 23). The fractions of exchangeable, reducible ad oxidisable phases showed relatively high correlation with soil pH, Fe/Mn oxide concentrations and organic matter contents, respectively.

• Journal of Korea Soil Environment Society
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• v.2 no.1
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• pp.45-50
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• 1997

The change of industrial structure has brought the sharp declination of mine products, and has made many mines closed, which results in environmental pollution by untreated acid mine drainage(AMD). AMD with low pH and high concentration of heavy metals could severely destroy the ecosystem. Many researches have been carried out for the treatment of AMD. In this study, we have treated AMD with oak compost, mushroom compost, sludge cake and cow manure which usually used in AMD treatment systems, and compared the capability of each organic matter. Cow manure and oak compost have been most effective among 4 organic materials. Oak compost removed the heavy metals by ion exchange between Ca-rich particles and soluble heavy metal ions. It also captured the heavy metals using bound functional groups like -OH and -COO-. Sulfate reducing bacteria existing in the cow manure removed effectively heavy metals by producing metal sulfide compound. Therefore, it is effective to use both organic materials in mixture on the treatment of AMD.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.5
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• pp.738-743
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• 2012

Topographic conditions of agricultural fields work as a important factor to identify different soil properties. This study was conducted to investigate the selected soil chemical properties and the concentrations of heavy metals, Cd, Cr, Pb, Cu, Ni, and Zn, in the paddy fields of different topographic areas at four year intervals from 1999 to 2011. Three-hundred soil sampling sites in the paddy fields were selected from the different topographic areas that were local valley and fans, fluvio-marine deposits, alluvial plains, and diluvial terraces. The mean values of soil pH ranged 5.7~5.8 that were within optimal range for rice cultivation. The mean values of other properties such as soil organic matter (SOM) content, the concentrations of exchangeable cations, $K^+$, $Ca^{2+}$, and $Mg^{2+}$, and available silicate concentration were lower or close to the optimal values, but the mean concentrations of available phosphorus were exceeded the range of optimal value, $80{\sim}120mg\;kg^{-1}$, in many paddy fields. In particular, The concentrations of available phosphorus in the paddy fields of local valley and fans, alluvial plains, and fluvio-marine plains were mostly declined. However, in diluvial terrace areas, the phosphorus concentrations unexpectedly increased; furthermore, they were significantly higher than those in other topographic areas. The mean concentrations of 0.1 M HCl-extractable heavy metals, Cd, Cr, Pb, Cu, Ni, and Zn, in the paddy fields were slightly and gradually declined during the study years, but the Pb concentrations were not statistically changed. In addition, the concentrations of heavy metals were widely ranged depending on the different sampling sites. Nevertheless, the concentrations of heavy metals were significantly lower than the levels of Soil Contamination Warning Standard (SCWS) for agricultural lands (1-region) presented in Soil Environment Conservation Law (SECL).

• Journal of Animal Environmental Science
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• v.15 no.1
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• pp.59-68
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• 2009

This study investigated the evaluation of maturity, stability, nutrient and heavy metal from rotating drum composter of food waste amended with poultry manure composting inoculated with effective microorganisms(EM). Composting were performed for the first, drying reactor($15m^3$) 3 hours and the second, composting reactor($30m^3$) 24 hours, and parameters monitored this period included moisture content, NaCl, pH, electrical conductivity(EC), C/N ratio, organic matter(OM), nutrient content and heavy metal. Changes in compost temperature during composting were maintained constantly in the range of $60{\sim}80^{\circ}C$ using firewood boiler(450 MJ/h). We examined physicochemical parameters and heavy metals in order to assess their effectiveness as stability and maturity, nutrient and harmful indicators such as seed germination rate<60%, potassium 1>%, dm and NaCl>1%, dm at the end of the final compost. The finished compost obtained after decomposition phase at the end of the 2nd composter could not be utilized for land improvement or reclamation.

• Journal of Hydrogen and New Energy
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• v.28 no.5
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• pp.536-544
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• 2017

The effects of catalysts addition on the pyrolysis reaction of biomass have been studied in a thermogravimetric analyzer (TGA). The sample biomasses were Bamboo, Pine and Hinoki. The catalysts tested were K, Zn, Cu metal compounds. The pyrolysis reactions were tested in the nonisothermal condition from the room temperature to $550^{\circ}C$ at a heating rate $50^{\circ}C/min$ on the flowing of $N_2$ purge gases. Cellulose contents of Bamboo was higher than that of Pine and Hinoki. As the results, the pyrolysis reaction of volatile matter was finished near the temperature $450^{\circ}C$. The initial decomposition temperatures of the volatile matters ($T_i$) were $165^{\circ}C$ for Bamboo, $190^{\circ}C$ for Pine, and $193^{\circ}C$ for Hinoki. $T_i$ decreased with increasing the catalyst amounts in the sample biomasses. The temperature of maximum reaction rate ($T_{max}$) were $338^{\circ}C$ for Bamboo, $378^{\circ}C$ for Pine, and $377^{\circ}C$ for Hinoki. The effects of catalysts addition on the $T_{max}$ were to decreased it. The reducing effects about $T_{max}$ was the most effective for K metal compounds catalyst. The char amounts remained after pyrolysis at $550^{\circ}C$ were 26.2% for Bamboo, 20.7% for Pine, and 20.9% for Hinoki. The char amounts increased with the catalyst amounts.

• Journal of Soil and Groundwater Environment
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• v.27 no.5
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• pp.10-17
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• 2022

Inorganic acids such as HCl, HNO₃, and H₂SO₄ have been commonly applied to soil washing of heavy metals-contaminated soil due to their cost-effectiveness. However, implementing the 'Chemical Substance Control Act' requires off-site risk assessment of the chemicals used in the soil washing. Therefore, in this study, organic acids or Fe(III)-based washing agents were evaluated to replace commonly used inorganic acids. Ferric removed heavy metals via H⁺ generated by hydrolysis, which is similar to the HCl used in the control group. Oxalic acid and citric acid were effective to remove Cu, Zn, and Cd from soil. Organic acids could not remove Pb because they could form Pb-organic acid complexes with low solubility. Furthermore, Pb could be adsorbed onto the iron-organic acid complex on the soil surface. Ferric could remove exchangeable-carbonate, Fe-Mn hydroxide, and organic matter and sulfides bound heavy metals (F1, F2, and F3). Organic acids could remove the exchangeable-carbonate and Fe-Mn hydroxide bound metals (F1&F2). Therefore, this research shows that the fractionation of heavy metals in the soil and the properties of washing agents should be considered in the selection of agents in the process design.

• Journal of Korean Society for Atmospheric Environment
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• v.2 no.3
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• pp.57-63
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• 1986

Atmospheric particulate matter (A.P.M.) was collected on quartz fiber filters from March 1985 to May 1986 according to particle size using Andersen high-volume air sampler, and 6 heavy metals (Fe, Mn, Cu, Ni, Zn, Pb) in these particulates were analyzed by atomic absorption spectrophotometry. The arithmetic mean concentration of A.P.M. was 195.57$\mug/m^3$. The arithmetic mean concentrations of 6 metals (Fe, Mn, Cu, Ni, Zn and Pb) were 3385.04, 1451.67, 897.94, 159.68, 127.14 and 59.49 $ng/m^3$ respectively. The order of heavy metals contributing to A.P.M. was as follows: Fe > Zn > Pb > Cu > Mn > Ni. These heavy metals were devided into 3 groups according to their particle size distribution. The contents of heavy metals belonging to the 1st group (Fe, Mn) were increased with the particle size. On the contrary, the content of Pb belonging to the 2nd group (Pb) was increased with the decrease in the particle size. The heavy metal contents in the 3rd group (Ni, Cu, Zn) were lowest in the particle size range of 2.0-3.3 $\mum$ compared with particles larger or smaller tha this range. The seasonal variation of heavy metal concentration were as follows: Fe and Mn contents were highest in spring, but Ni and Pb contents were highest in winter. Statistical analysis showed that there was a significant correlation between A.P.M. and Fe in coarse particles, meanwhile between A.P.M. and Pb in the case of fine particles.

• Journal of Conservation Science
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• v.27 no.3
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• pp.333-344
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• 2011

Cleaning of foreign matter and corrosion products on surface among conservation treatment of iron artifacts is an important part for looking up a original form. The sand blaster is the most popular equipment when it removes the foreign matter and corrosion products on iron artifacts surface. Current foreign matter and corrosion products equipment, which mostly uses, is sand blaster. Glass dust which sprayed from sand blaster is harmful and causing environmental pollution. In order to solve these problems, we investigated the $CO_2$ snow cleaning that use a eco-friendly equipment to apply for cleaning foreign matter and corrosion products on surface of iron artifacts. It examined by using sand blaster and $CO_2$ snow cleaning to aged steel coupon and iron artifacts. In case of aged steel coupon, the result showed that the sand blaster and $CO_2$ snow cleaning methods were similar to the degrees of cleaning foreign matter and corrosion products, through surface roughness, color measurement and SEM. $CO_2$ snow cleaning applied to aged steel coupons weren't worn out the surface in comparison with sand blaster by SEM. When applied to the iron artifacts, power nozzle of the $CO_2$ snow cleaning was an excellent cleaning effect that surface wern't worn out in comparison with sand blaster. And, it showed that internal structure change of metal was no found before and after cleaning by X-ray radiography. Consequently, we confirmed that cleaning of the sand blaster and power nozzle of $CO_2$ snow cleaning were similar to the effect. But, it's very careful to use this method because of high outlet pressure of power nozzle for applying to the iron artifacts. As a result of experiments, it could be found that the cleaning methods should be selected depending on internal state of the artifacts.

• Applied Biological Chemistry
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• v.37 no.6
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• pp.480-486
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• 1994

The present series of investigations have been undertaken to know the effective removal method of some pesticides, heavy metals and detergent when the doses of oxidants and coagulant were changed in the treatment process of drinking water containing organic material. Three pesticides, IBP, diazinon and CNP, were removed by about 68 to 100% by treatment of oxidant, $Cl_2$. Especially, diazinon was completely removed by treatment of $Cl_2$ and other oxidants such as $Cl_2,\;KMnO_4\;and\;O_3$. However, butachlor removal measured only 20.3 to 26.7% due to treatment of all oxidant used. A detergent, sodium dodecylbenzenesulfonate, was effectively removed by treatment of $O_3$ but remained stable in the presence of other oxidants. The heavy metals of Cd, Pb, Cu and Zn in water were not affected by treatment of all oxidants used. By changing the concentration of humic matter and the dosage of coagulant, the removal of heavy metals was increased according to the increase of coagulant dosage, and decreased when increasing the concentration of humic matter, whereas the pesticides and detergent were not effectively removed.

• Journal of Environmental Health Sciences
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• v.28 no.5
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• pp.86-92
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• 2002

This study was performed to assets the operating characteristics of food waste composting and co-composting (food waste + sewage sludge) at a compelling facility. The facility was being operated successfully without being affected by kind of composting feed materials. Partial anaerobic condition was detected during food waste composting and co-com-posting, but these two composting systems were proven to be operated successfully under aerobic condition from the monitoring results of $O_2$, volatile solids reduction rate, temperature, and other parameters. The conductivity and chloride concentrations of compost were gradually increased during two composting periods, but the conductivity and chloride concentrations of co-compelling indicated lower values than those of food waste composting at final point(40 m). As a result, co-composting was turned out to be more desirable than food waste composting, considering salt problem. High correlations ($R^2$= 0.9265 for food waste composting and $R^2$= 0.9685 for co-composting) between CEC and volatile organic matter were found. Quality of composts produced from two composting process satisfied Korean heavy metal standard.