• International Journal of Concrete Structures and Materials
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• v.7 no.3
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• pp.215-223
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• 2013

This study presents the effect of incorporating metakaolin (MK) on the mechanical and durability properties of high strength concrete for a constant water/binder ratio of 0.3.MK mixtures with cement replacement of 5, 10 and 15 % were designed for target strength and slump of 90 MPa and $100{\pm}25mm$. From the results, it was observed that 10 % replacement level was the optimum level in terms of compressive strength. Beyond 10 %replacement levels, the strength was decreased but remained higher than the control mixture. Compressive strength of 106 MPa was achieved at 10 % replacement. Splitting tensile strength and elastic modulus values have also followed the same trend. In durability tests MK concretes have exhibited high resistance compared to control and the resistance increases as the MK percentage increases. This investigation has shown that the local MK has the potential to produce high strength and high performance concretes.

• Journal of The Korean Society of Agricultural Engineers
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• v.50 no.5
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• pp.51-60
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• 2008

This study is to relate the bond characteristics of CFRP rebar in high strength concrete incorporated with silica fume(SF) and metakaolin(MK). An direct bond test were performed to evaluate the effect of SF and MK on bond properties of high-strength concrete and CFRP rebar. The high strength concrete mix included four SF and MK mixes with 0%, 5%, 10% and 15%. Results of bond performance experiment in relation to pullout vs slip behavior of FRP rebar and high strength showed better performance of SF than MK. Also, the results showed the improved bond strength as replacement ratio of SF and MK increased. The relative bond strength in which $1.3{\sim}3.2$ of estimated values were obtained.

• Advances in concrete construction
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• v.5 no.1
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• pp.31-48
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• 2017

Supplementary cementitious materials (SCM) have turned out to be a vital portion of extraordinary strength and performance concrete. Metakaolin (MK) is one of SCM material is acquired by calcinations of kaolinite. Universally utilised as pozzolanic material in concrete to enhance mechanical and durability properties. This study investigates the fresh and hardened properties of conventional concrete (CC) and self compacting concrete (SCC) by partially replacing cement with MK in diverse percentages. In CC and SCC, partial replacement of cement with MK varies from 5-20%. Fresh concrete properties of CC are conducted by slump test and compaction factor tests and for SCC, slump flow, T500, J-Ring, L-Box, V-Funnel and U-Box tests. Hardened concrete characteristics are investigated by compressive, split tensile and flexural strengths at age of 7, 28 and 90 days of curing under water. Carbonation depth, water absorption and density of MK based CC and SCC was also computed. Fresh concrete test results indicated that increase in MK replacement increases workability of concrete in a constant w/b ratio. Also, outcomes reveal that concrete integrating MK had greater compressive, flexural and split tensile strengths. Optimum replacement level of MK for cement was 10%, which increased mechanical properties and robustness properties of concrete.

• Structural Engineering and Mechanics
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• v.31 no.1
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• pp.1-10
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• 2009

An experimental investigation was conducted to evaluate the performance of mortars with and without Metakaolin (MK) exposed to elevated temperatures $200^{\circ}C$, $400^{\circ}C$, $600^{\circ}C$ and $800^{\circ}C$ for two hours. The binder to sand ratio was kept constant (1:5.23). The ordinary Portland cement (OPC) was replaced with MK at 0%, 5%, 10% 20% and 30%. All mixtures were designed to have a flow of $94{\pm}5%$. The compressive strength of mortars before and after exposure to elevated temperature was determined. The formation of various decomposition phases were identified using X-ray diffractometry (XRD) and differential thermal analysis (DTA). The microstructure of the mortars was examined using scanning electron microscope (SEM). Test results indicated that MK improves the compressive strength before and after exposure to elevated temperature and that the 20% cement replacement of MK is the optimum percentage.

• Advances in concrete construction
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• v.5 no.3
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• pp.241-255
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• 2017

Concrete is known to be the most used construction material worldwide. The environmental and economic aspects of Ordinary Portland Cement (OPC) containing concrete have led research studies to investigate the possibility of incorporating supplementary cementitious materials (SCMs) in concrete. Metakaolin (MK) is one SCM with high pozzolanic reactivity generated throughout the thermal activation of high purity kaolinite clay at a temperature ranging from $500^{\circ}C$ to $800^{\circ}C$. Although many studies have evaluated the effect of MK on mechanical properties of concrete and have reported positive effects, limited articles are considering the effect of MK on durability properties of concrete. Considering the lifetime assessment of concrete structures, the durability of concrete has become of particular interest recently. In the present work, the influences of MK on mechanical and durability properties of concrete mixtures are evaluated. Various experiments such as slump flow test, compressive strength, water permeability, freeze and thaw cycles, rapid chloride penetration and surface resistivity tests were carried out to determine mechanical and durability properties of concretes. Concretes made with the incorporation of MK revealed better mechanical and durability properties compared to control concretes due to combined pozzolanic reactivity and the filler effect of MK.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.639-642
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• 2005

Main components of metakaolin(MK) were $SiO_2\;and\;Al_2O_3$. and specific surface was 2.2 times larger than that of ordinary portland cement(OPC). MK indicated the fine particle and fiber texture. Flow value of mortar with MK was decreased linearly each $13\%$ as the replacement ratio of MK was increased each $5\%$. Compressive strength of mortar with MK was increased more than that of mortar with OPC by 3days. Compressive strength of mortar with $10\%$ MK was about 83MPa at 28 days. When MK was replaced with $10\%$ of cement volume, flexural strength and modulus of elasticity of mortar was indicated the maximum value at 28 days.

• Steel and Composite Structures
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• v.23 no.5
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• pp.543-555
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• 2017

The mechanical properties of steel fiber reinforced high strength concrete (SFRHSC) made with binary and ternary blends of metakaolin (MK) and ground pumice (GP) are investigated in this study. The investigated properties are ultrasonic pulse velocity ($U_{pv}$), compressive strength ($f_c$), flexural strength ($f_f$) and splitting tensile strength ($f_{st}$) of SFRHSC. A total of 16 steel fiber reinforced concrete mixtures were produced by a total binder content of $500kg/m^3$ for determining the effects of MK and GP on the mechanical properties. The design $f_c$ was acquired from 70 to 100 MPa by using a low water-binder ratio of 0.2. The test results exhibit that high strength concrete can be obtained by replacing the cement with MK and GP. Besides, correlations between these results are executed for comprehending the relationship between mechanical properties of SFRHSC and the strong correlations are observed between these properties. Moreover, two models in the gene expression programming (GEP) for predicting the $f_c$ of SFRHSC made with binary and ternary blends of MK and GP have been developed. The results obtained from these models are compared with the experimental results. These comparisons proved that the results of equations obtained from these models seem to agree with the experimental results.

• Steel and Composite Structures
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• v.36 no.6
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• pp.657-669
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• 2020

This study investigates the fire resistance characteristics of reactive powder concrete according to changes in the cement content per unit area, mixing ratio of metakaolin (MK), and content of polypropylene fiber. A fire test was conducted, and the resulting residual strength characteristics were investigated through flexural and compressive strength measurements, as well as condition rating classification based on visual evaluation. MK effectively reduced the initial high content of calcium hydroxide, thereby reducing the water vapor pressure generated during pyrolysis and slowing spalling. Furthermore, the pore structure and loose tissue were effective for relieving the water vapor pressure in the event of a fire.

• Advances in concrete construction
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• v.7 no.3
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• pp.167-174
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• 2019

Metakaolin (MK), which is increasingly being used to produce high performance concrete, is produced by calcining purified kaolinite between 650 and $700^{\circ}C$ in a rotary kiln. The carbonation resistance of metakaolin blended concrete is lower than that of control concrete. Hence, it is critical to consider carbonation durability for rationally using metakaolin in the concrete industry. This study presents microstructure modeling during the carbonation of metakaolin blended concrete. First, based on a blended hydration mo del, the amount of carbonatable substances and porosity are determined. Second, based on the chemical reactions between carbon dioxide and carbonatable substances, the reduction of concrete porosity due to carbonation is calculated. Furthermore, $CO_2$ diffusivity is evaluated considering the concrete composition and exposed environment. The carbonation depth of concrete is analyzed using a diffusion-based model. The proposed microstructure model takes into account the influences of concrete composition, concrete curing, and exposure condition on carbonation. The proposed model is useful as a predetermination tool for the evaluation of the carbonation service life of metakaolin blended concrete.

• Computers and Concrete
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• v.29 no.5
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• pp.347-360
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• 2022

Fiber-reinforced cementitious composites (FRCC) have emerged as a response to the calls for strong, ductile and sustainable concrete mixes. FRCC has shown outstanding mechanical properties and ductility where special fibres are used in the mixes to give it the strength and the ability to exhibit strain hardening. With the possibility of designing the FRCC mixes to include sustainable constituents and by-products materials such as fly ash, FRCC started to emerge as a green alternative as well. To be able to design mixes that achieve these conflicting properties in concrete, there is a need to understand the composition effect on FRCC and optimize these compositions. Therefore, this paper aims to investigate the influence of FRCC compositions on the properties of fresh and hardened of FRCC and then to optimize these mix compositions using factorial design approach. Three factors, water-to-binder ratio (w/b), mineral admixtures (total of fly ash and metakaolin by cement content (MAR)), and metakaolin content (MK), were investigated to determine their effects on the properties of fresh and hardened FRCC. The results show the importance of combining both FA and MK in obtaining a satisfactory fresh and mechanical properties of FRCC. Models were suggested to elucidate the role of the studied factors and a method for optimization was proposed.