• Title/Summary/Keyword: membrane orientation

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Effects of membrane orientation on permeate flux performance in a submerged membrane bioreactor

  • Lee, Tsun Ho;Young, Stephanie
    • Membrane and Water Treatment
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    • v.3 no.3
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    • pp.141-149
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    • 2012
  • The aeration provided in a Submerged Membrane Bioreactor (SMBR) improves membrane filtration by creating turbulence on the membrane surface and reducing membrane resistance. However, conventional hollow fiber membrane modules are generally packed in a vertical orientation which limits membrane scouring efficiency, especially when aeration is provided in the axial direction. In the present research, 3 innovative hollow-fiber membrane modules, each with a different membrane orientation, were developed to improve membrane scouring efficiency and enhance permeate flux. Pilot testing was performed to investigate the permeate flux versus time relationship over a 7-day period under different intermittent modes. The results indicated that the best module experienced an overall permeate flux decline of 3.3% after 7 days; the other two modules declined by 13.3% and 18.3%. The lower percentage of permeate flux decline indicated that permeate productivity could be sustained for a longer period of time. As a result, the operational costs associated with membrane cleaning and membrane replacement could be reduced over the lifespan of the module.

Dynamic Motion of Polyelectrolyte in a Composite Membrane: II. Molecular Study (막에서 전하고분자의 동적 현상 II. 미시적 연구)

  • Park, Young;Lim, Hwa A.
    • Membrane Journal
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    • v.4 no.2
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    • pp.96-105
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    • 1994
  • Theoretical model for membrane transport of large polye!ectroiyte is presented. When the electric field is applied, the molecular conformation quickly orients in the field direction showing overshooting orientation. the predicted dependence of overshoot time and orientation upon field intensity and molecular size aids to understand the dynamic motion of molecules in membrane transport. The dynamics of the overshoot is associated with self-trapping conformations of molecule. The understanding of these effects supports evidences for the electrophoretic filtration of polydectrolyte in the polymeric membrane. This paper shows one example for molecular study in the theoretical review paper of membrane transport.

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Effect of Natural Convection Instability on Reduction of Fouling and Increasing of Critical Flux in Constant-flow Ultrafiltration (정유량 한외여과에서 자연대류 불안정성의 막오염 감소 및 임계 플럭스 증가 효과)

  • Jang, A-Rum;Nam, Sang-Won;Youm, Kyung-Ho
    • Membrane Journal
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    • v.22 no.5
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    • pp.332-341
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    • 2012
  • We studied the effects of induction of natural convection instability flow (NCIF) according to the gravitational orientation (inclined angle) of the membrane cell on the reduction of membrane fouling in the constant-flow ultrafiltration (UF) of colloidal silica solutions. Five colloidal silica solutions with different silica size (average size = 7, 12, 22, 50 nm and 78 nm) were used as UF test solutions. The silica particles in colloidal solutions form cakes on the membrane surface thereby causing severe membrane fouling. The constant-flow UF performance according to the gravitational orientation of the membrane cell (from $0^{\circ}$ to $180^{\circ}$ inclined angle), was examined in an unstirred dead-end cell. We evaluate the effects of NCIF on the suppression of fouling formation by measuring the variation of transmembrane pressure (TMP) and the increase of critical flux by using the flux-stepping method. In the constant-flow dead-end UF for the smaller size (7, 12 nm and 22 nm) silica colloidal solutions, changing the gravitational orientation (inclined angle) of the membrane cell above the $30^{\circ}$ angle induces NCIF in the membrane module. This induced NCIF enhances back transport of the deposited silica solutes away from the membrane surface, therefore gives for the reduction of TMP. But in the constant-flow UF for the more larger size (50 nm and 78 nm) silica colloidal solutions, NCIF effects are not appearing. The critical flux is increased as increasing the module angle and decreasing the silica size. Those results show that the intesity of NCIF occurrence in membrane module is more higher as increasing the module angle and decreasing the silica size.

Improvement of Membrane Performance by Natural Convection Instability Flow in Ultrafiltration of Colloidal Solutions (콜로이드 용액의 한외여과에서 자연대류 불안정 흐름의 막성능 개선 효과)

  • Cho, Youn-Joo;Youm, Kyung-Ho
    • Membrane Journal
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    • v.21 no.1
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    • pp.84-90
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    • 2011
  • We studied the effects of induction of natural convection instability flow (NCIF) according to the gravitational orientation (inclined angle) of the membrane cell on the reduction of membrane fouling in ultrafiltration (UF) of colloidal silica solutions. Five colloidal silica solutions with different silica size (average size = 7, 12, 22, 50 and 78 nm) were used as UF test solutions. The silica particles in colloidal solutions form cakes on the membrane surface thereby causing severe reduction in the flux. The UF performance according to the gravitational orientation of the membrane cell (from 0 to $180^{\circ}$ inclined angle), was examined in an unstirred dead-end cell. We evaluate the effects of NCIF on membrane performance as the flux enhancement ($E_i$). In the dead-end UF of smaller size (7, 12 and 22 nm) silica colloidal solutions, changing the gravitational orientation (inclined angle) of the membrane cell induces NCIF in the membrane module and higher inclined angle and smaller size silica colloidal solution offer more stronger NCIF. This induced NCIF enhances back transport of the deposited silica solutes away from the membrane surface, therefore gives for the improvement of permeate flux. But in UF of more larger size (50 and 78 nm) silica colloidal solutions, NCIF effects are not appearing. These results suggest that the size of colloidal particle affects the extent of NCIF occurrence.

Si Micromachining for MEMS-lR Sensor Application (결정의존성 식각/기판접합을 이용한 MEMS용 구조물의 제작)

  • 박흥우;주병권;박윤권;박정호;김철주;염상섭;서상의;오명환
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.411-414
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    • 1998
  • In this paper, the silicon-nitride membrane structure for IR sensor was fabricated through the etching and the direct bonding. The PT layer as a IR detection layer was deposited on the membrane and its characteristics were measured. The attack of PT layer during the etching of silicon wafer as well as the thermal isolation of the IR detection layer can be solved through the method of bonding/etching of silicon wafer. Because the PT layer of c-axial orientation rained thermal polarization without polling, the more integration capability can be achieved. The surface roughness of the membrane was measured by AFM, the micro voids and the non-contacted area were inspected by IR detector, and the bonding interface was observed by SEM. The polarization characteristics and the dielectric characteristics of the PT layer were measured, too.

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Molecular Dynamics Simulations of Hemolytic Peptide δ-Lysin Interacting with a POPC Lipid Bilayer

  • Lorello, Kim M.;Kreutzberger, Alex J.;King, Allison M.;Lee, Hee-Seung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.783-792
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    • 2014
  • The binding interaction between a hemolytic peptide ${\delta}$-lysin and a zwitterionic lipid bilayer POPC was investigated through a series of molecular dynamics (MD) simulations. ${\delta}$-Lysin is a 26-residue, amphipathic, ${\alpha}$-helical peptide toxin secreted by Staphylococcus aureus. Unlike typical antimicrobial peptides, ${\delta}$-lysin has no net charge and it is often found in aggregated forms in solution even at low concentration. Our study showed that only the monomer, not dimer, inserts into the bilayer interior. The monomer is preferentially attracted toward the membrane with its hydrophilic side facing the bilayer surface. However, peptide insertion requires the opposite orientation where the hydrophobic side of peptide points toward the membrane interior. Such orientation allows the charged residues, Lys and Asp, to have stable salt bridges with the lipid head-group while the hydrophobic residues are buried deeper in the hydrophobic lipid interior. Our simulations suggest that breaking these salt bridges is the key step for the monomer to be fully inserted into the center of lipid bilayer and, possibly, to translocate across the membrane.

Etching-Bonding-Thin film deposition Process for MEMS-IR SENSOR Application (MEMS-IR SENSOR용 식각-접합-박막증착 기반공정)

  • Park, Yun-Kwon;Joo, Byeong-Kwon;Park, Heung-Woo;Park, Jung-Ho;Yom, S.S.;Suh, Sang-Hee;Oh, Myung-Hwan;Kim, Chul-Ju
    • Proceedings of the KIEE Conference
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    • 1998.07g
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    • pp.2501-2503
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    • 1998
  • In this paper, the silicon-nitride membrane structure for IR sensor was fabricated through the etching and the direct bonding. The PTO layer as a IR detection layer was deposited on the membrane and its characteristics were measured. The attack of PTO layer during the etching of silicon wafer as well as the thermal isolation of the IR detection layer can be solved through the method of bonding/etching of silicon wafer. Because the PTO layer of c-axial orientation raised thermal polarization without polling, the more integration capability can be achieved. The surface roughness of the membrane was measured by AFM, the micro voids and the non-contacted area were inspected by IR detector, and the bonding interface was observed by SEM. The polarization characteristics and the dielectric characteristics of the PTO layer were measured, too.

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Surfactant enhanced filtration performances of monochlorophenol isomers through low-pressure membrane

  • Kumar, Yogesh;Brahmbhatt, H.;Trivedi, G.S.;Bhattacharya, A.
    • Membrane and Water Treatment
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    • v.2 no.3
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    • pp.137-145
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    • 2011
  • Membrane processes are major breakthrough for the removal of organic pollutants in water remediation. The separations of solutes depend on nature of the membranes and solutes. The separation performance depends on the nature of the solutes (i.e., molecular volume, polarity, and hydrophobicity) for the same membrane. As 4-chlorophenol is of more dipolemoment compared to 2-chlorophenol, the orientation of the molecule enables it pass through the pores of the membrane, which is of negatively charged and thus separation order follows: 2-chlorophenol > 4-chlorophenol. Hydrophobicity factor also supports the order. Addition of sodium dodecyl sulfate (SDS) to chlorophenol solution shows remarkable increase in separation performance of the membrane. The improvement in separation is 1.8 and 1.5 times for 4- and 2- chlorophenol consecutively in case of 0.0082 M SDS (1cmc = 0.0082 M) in the solution. 4-chlorophenol has better attachment tendency with SDS because of its relatively more hydrophobic nature and thus reflects in performance i.e. the separation performance of 4-chlorophenol with SDS through the membrane is better compared to 2-chlorophenol.

Forward Osmosis Based Seawater Desalination using Liquid Fertilizer as Draw Solution (액상 비료를 유도 용액으로 사용하는 정삼투 기반의 해수 담수화)

  • Park, Seong-Jik;An, Hee-Kyung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.2
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    • pp.21-27
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    • 2013
  • The present study explored the way to desalinate seawater for agricultural irrigation using forward osmosis (FO) process using liquid fertilizer as draw solution. FO experiments were performed in a cross flow mode using flat sheet FO membrane. The effect of membrane orientation, flow rate, and draw solution concentration on the performance of forward osmosis was investigated by measuring water flux of forward osmosis membrane. The water flux when the draw solution was placed against the membrane active layer was lower than the water flux when the feed solution was placed against the membrane active layer. This results indicated that the decrease of effective osmotic pressure by dilutive internal concentration polarization was less than that by concentrative internal concentration polarization. Increasing flow rate from 66.7 to 133.1 $cm^3$/min resulted in increase of the water flux when the membrane active layer orient to draw solution and feed solution, respectively. The reduction of resistance to water flow increased water flux at higher flow rate. The water flux of FO membrane increased with increasing draw solution concentration from 10000 to 30000 mg/L. The water flux for $KH_2PO_4$ draw solution was similar to that for commercial fertilizer. Optimization of FO process would contribute to economically desalinate brackish water for agricultural use.

Orientation Study and Functional Design of Synthetic Phosphate Bilayer as Biomombrane Model

  • ;Kunitake, T.
    • Proceedings of the Membrane Society of Korea Conference
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    • 1992.10a
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    • pp.1-4
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    • 1992
  • 생체막은 많은 생물학적인 과정에서 중요한 역할을 차지한다. 막의 주된 성분은 지질과 단백질이고, 막의 기본적인 구조는 2개의 지질분자가 소수성기를 안쪽으로 서로 마주보며 이차원으로 배열된 Bilayer구조이다. 막의 두께는 약 50A 전후로 지구상에 존재하는 막중에서 가장 얇은 막이라 할 수 있다. 막의기능성은 근본적으로 이 Bilayer구조특성에서 나온다고 할 수 있다. 생체막의 대표적인 물질로 Lecithin은 Phosphatidyl Choline을 친수성기로, 2개의 긴 알킬체인이 소수성영역으로 된 양친매성 화합물이다.

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