• 제목/요약/키워드: membrane modification

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Fabrication and characterization of polysulfone ultrafiltration membrane using polyethylene glycol and tartaric acid: morphology and performance in protein separation

  • Sharma, N.;Purkait, M.K.
    • Membrane and Water Treatment
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    • v.8 no.6
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    • pp.591-612
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    • 2017
  • Increase in the hydrophilicity (HPCT) of polysulfone (PS) membrane and subsequently decrease in fouling can be achieved by surface modification of PS based membranes. Therefore, in this work, ultrafiltration membranes with increased HPCT were prepared using the enantiomeric tartaric acid (D-TA) and racemic tartaric acid (DL-TA). Phase inversion technique was used for the preparation of polyethylene glycol and TA blended PS membrane. Morphological analysis of the fabricated membranes was done by scanning electron microscope and atomic force microscopy. Bovine serum albumin (BSA) solution was taken for finding the permeation and rejection behavior of prepared membranes. Maximum BSA rejection was increased by 70.5% for the modified membrane.

Numerical Analysis and Experimental Evaluation on Formability of Membrane for LNG Storage Tank (LNG 저장탱크용 멤브레인 성형공정에 관한 해석적·실험적 연구)

  • Noh, H.G.;Jung, J.Y.;Ku, T.W.;Kang, B.S.
    • Transactions of Materials Processing
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    • v.20 no.6
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    • pp.409-419
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    • 2011
  • Membrane structures are widely used for LNG(Liquefied Natural Gas) storage tanks. This study presents a membrane structure based on the Mark-III type. For its development, a series of numerical simulation was conducted using ABAQUS and experimental investigation was carried out. The manufacturing process of the membrane was simulated. The thickness distribution predicted by the numerical approach agreed well with the experimental results.

Stabilization of photosynthetic machinery against low-temperature photoinhibition by fatty acid unsaturation of membrane lipids in plants

  • Moon, Byoung-Yong
    • Proceedings of the Botanical Society of Korea Conference
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    • 1999.08a
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    • pp.68-82
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    • 1999
  • CHilling tolereance of plants are closely correlated with the degree of fatty acid unsaturation of membrane lipids. We studied the effects of low-temperature photoinhibition on the photochemical efficiency of photosystem II in terms of fatty acid unsaturation of thylakoid membranes lipids isolated from chilling -sensitive plants and chilling -resistant ones. To directly test the chilling tolerance of photosynthetic machinery in relation to membrane lipids, we further compared wild type tobacco plants with that of transgenic tobacco plants, in which the sensitivity to chilling had been enhanced by genetic modification of fatty acid unsaturation of chloroplast membrane lipids. The transgenic tobacco plants were found to contain reduced levels of unsaturated membrane fatty acids after being transformed with cDNA for glycerol-3-phophate acyltransferase from squash. The functional integrity of photosystem II during and recovery of photosynthesis from low-temperature photoinhibition will be discussed in connection with the degree of fatty acid unsaturation of chlorophast membranes lipids.

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PREPARATION AND CHARACTERIZATION OF THE CHIRAL STATIONARY PHASE BASED ON THE CHITOSAN

  • Son, Seung-Hee;Jonggeon Jegal;Lee, Kew-Ho
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.103-105
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    • 2003
  • A chiral stationary phase (CSP) was synthesized by the modification of the chitosan using N-nicotinoyl phenylalanine and 3, 5-dimethylphenylisocyanate . The CSP based on the chitosan was then characterized in terms of their chemical structure and physical properties. To test its performance as a CSP, the silica powder with 5 ${\mu}{\textrm}{m}$ of diameter were coated with the CSP to pack a column for High Performance Liquid Chromatograph (HPLC). Using the packed column, several racemates were tried to separate under various separation conditions with different compositions of eluents.

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Progress in the modification of reverse osmosis (RO) membranes for enhanced performance

  • Otitoju, T.A.;Saari, R.A.;Ahmada, A.L.
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.52-71
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    • 2018
  • RO membranes, the core elements for RO process formed using polyamide, have found prominent space in membrane technology. RO membranes with better application perspective could be achieved by precise controlling the kinetics of IP reaction and surface modification strategy. Despite huge progresses, great challenges still exist in trade-off between flux, rejections and fouling. More works are necessary to enhance the performance and stability of RO membranes via surface modification. Further insights into the use of natural monomers are necessary. It is anticipated that this article can provide clues for further in-depth evaluation and research in exploring more advanced RO membranes.

Modification of polyethersulfone hollow fiber membrane with different polymeric additives

  • Arahman, Nasrul;Mulyati, Sri;Lubis, Mirna Rahmah;Razi, Fachrul;Takagi, Ryosuke;Matsuyama, Hideto
    • Membrane and Water Treatment
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    • v.7 no.4
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    • pp.355-365
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    • 2016
  • The improvement of fouling resistance of porous polymeric membrane is one of the most important targets in membrane preparation for water purification in many process like wastewater treatment. Membranes can be modified by various techniques, including the treatment of polymer material, blending of hydrophilic polymer into polymer solution, and post treatment of fabricated membrane. This research proposed the modifications of morphology and surface property of hydrophobic membrane by blending polyethersulfone (PES) with three polymeric additives, polyvinylpyrrolidone (PVP), Pluronic F127 (Plu), and Tetronic 1307 (Tet). PES hollow fiber membranes were fabricated via dry-wet spinning process by using a spinneret with inner and outer diameter of 0.7 and 1.0 mm, respectively. The morphology changes of PES blend membrane by those additives, as well as the change of performance in ultrafiltration module were comparatively observed. The surface structure of membranes was characterized by atomic force microscopy and Fourier transform infra red spectroscopy. The cross section morphology of PES blend hollow fiber membranes was investigated by scanning electron microscopy. The results showed that all polymeric additives blended in this system affected to improve the performances of PES membrane. The ultra-filtration experiment confirmed that PES-PVP membrane showed the best performance among the three membranes on the basis of filtration stability.

Emerging membrane technologies developed in NUS for water reuse and desalination applications: membrane distillation and forward osmosis

  • Teoh, May May;Wang, Kai Yu;Bonyadi, Sina;Yang, Qian;Chung, Tai-Shung
    • Membrane and Water Treatment
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    • v.2 no.1
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    • pp.1-24
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    • 2011
  • The deficiency of clean water is a major global concern because all the living creatures rely on the drinkable water for survival. On top of this, abundant of clean water supply is also necessary for household, metropolitan inhabitants, industry, and agriculture. Among many purification processes, advances in low-energy membrane separation technology appear to be the most effective solution for water crisis because membranes have been widely recognized as one of the most direct and feasible approaches for clean water production. The aim of this article is to give an overview of (1) two new emerging membrane technologies for water reuse and desalination by forward osmosis (FO) and membrane distillation (MD), and (2) the molecular engineering and development of highly permeable hollow fiber membranes, with polyvinylidene fluoride (PVDF) and polybenzimidazole (PBI) as the main focuses for the aforementioned applications in National University of Singapore (NUS). This article presents the main results of membrane module design, separation performance, membrane characteristics, chemical modification and spinning conditions to produce novel hollow fiber membranes for FO and MD applications. As two potential solutions, MD and FO may be synergistically combined to form a hybrid system as a sustainable alternative technology for fresh water production.

Study on Stress Transition Mechanism and Uniaxial Tensile Characteristics by Tensile Fractured Test of Clamping Part of Membrane Structures (막구조 정착부의 인장파단시험을 통한 신장특성 및 응력전달체계에 관한 연구)

  • Kim, Hee-Kyun;Jeon, Sang-Hyeon;Ha, Chang-Woo;Kim, Jae-Yeol
    • Journal of Korean Association for Spatial Structures
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    • v.20 no.3
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    • pp.91-98
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    • 2020
  • For form stability of membrane structures, membrane material is required to be in tension. Therefore, in planning and maintenance management, the engineer should consider enough about introduction of stress during construction and re-introduction of stress after completion. Clamping part is an important portion with the function for introducing tension into membrane materials, and the function to transmit stress to boundary structures, such as steel frames. Then, the purpose of this research is to clarify stress condition and stress transfer mechanism including clamping part of membrane structures, and to grasp the changing tendency of membrane structures with the passage of time. In this research, following previous one, we perform well-balanced evaluation by conducting tensile fractured tests of clamping part's specimens, and by measuring individually the amount of displacement of not only overall specimen's length but membrane material and clamping part. Thereby, we consider the influence the difference in the hardness of edge rope and the difference in the direction of thread affect modification and fracture load.

Use of Inner Ionomer Solution in Preparing Membrane-Electrode Assembly (MEA) for Fuel Cells and Its Characterization

  • Seo, Seok-Jun;Woo, Jung-Je;Yun, Sung-Hyun;Park, Jin-Soo;Moon, Seung-Hyeon
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.46-52
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    • 2008
  • Optimization of ionomer solution was conducted in order to improve the performance of MEAs in PEMPC. The interface between membrane and electrodes in MEAs is crucial region determining fuel cell performance as well as ORR reaction at cathode. Through the modification of Nafion ionomer content at the interface between membrane and electrodes, an optimal content was obtained with Nafion 115 membranes. Two times higher current density was obtained with the outer Nafion sprayed MEA compared with the non-sprayed one. In addition, the symmetrical impedance spectroscopy mode (SM) exhibited that the resistances of membrane area, proton hydration, and charge transfer decreased as the outer Nafion is sprayed. From the polarization curves and SM, the highest current density and the lowest resistance was obtained at the outer ionomer content of $0.15\;mg\;cm^{-2}$.