• 분석과학
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• 제18권2호
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• pp.154-162
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• 2005

최근 국내 일부 정수장에서 검출된 것으로 보도되어진 바 있어 우리나라의 하천 수의 오염이 우려되고 있고, 일부 오염정도가 높은 하천수의 정화과정에서 제거가 완전히 이루어지지 않는 것으로 사료되는 1,4-dioxane은 그 독성과 음용수의 섭취량을 고려할 때 음용수 섭취로 인한 인체효과가 문제화 될 것으로 판단된다. 따라서 본 연구에서는 활성탄과 멤브레인으로 구성된 다단계 필터시스템에서 음용수 중에 존재하는 1,4-dioxane에 대한 제거효과에 대하여 연구하였다. 확인방법은 MTBE을 이용한 액체-액체 추출방법을 사용하였으며 제거실험은 압력별 필터단계별로 30 L마다 300 L 까지 실시하였다. 그 결과 초기에는 1차 활성탄 필터이후 70% 이상의 제거효과를 나타내었으며 멤브레인 이후 95%이상 그리고 2차 활성탄 이후 100% 제거되는 결과를 나타내었다. 그러나 통수량이 증가할수록 각 단계별 제거율은 점차 감소하였으며 300 L 통수 후 1차 활성탄에서 30%, 멤브레인 이후 88% 그리고 최종 활성탄 이후 99%의 제거율을 나타내었다.

• 상하수도학회지
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• 제22권1호
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• pp.79-86
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• 2008

In Korea, most of the drinking water treatment relied upon the availability of the surface water, of which the raw water quality varied significantly by season and location. Therefore, the comparison of two operation modes (Pressurized type and Submerged type membrane system) must be estimated before the long-term establishment of two systems. In this study, two pilot-scale microfiltration systems with the capacity of $50m^3/day$ were installed and operated in two different modes, and the applicability of the system was determined based on the results such as the TMP (Trans-Membrane Pressure) and flux. For quantitatively comparing the two systems, a new concept, DRF (Differential Resistance Fraction) was introduced. The accumulated sum of the permeate after each cycle of chemical cleaning was also used as a tool for the system comparison.

• Korean Membrane Journal
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• 제7권1호
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• pp.34-41
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• 2005

The wastewater discharged from a paper plant was filtrated by 3 kinds of tubular carbon ceramic UF and MF membranes with $N_2$-backflushing. The filtration time (FT) was fixed at 8 min or 16 min, and $N_2$-backflushing time (BT) was changed in 0${\~}$60 sec. The optimal condition was discussed in the viewpoints of total permeate volume ($V_T$), dimensionless permeate flux (J/Jo) and resistance of membrane fouling ($R_f$). In the viewpoints of $V_T$, J/Jo and $R_f$, the optimal $N_2$-BT was 40 sec at both FT for M9 (MWCO: 300,000 Daltons) and C005 ($0.05{\mu}m$) membranes. However, for C010 ($0.1{\mu}m$) it was 10 sec at FT=8 min, and 20 sec at FT=16 min in the viewpoints of J/Jo and $R_f$, and 5 sec at both FT in the viewpoints of $V_T$. It means that the short $N_2$-BT could reduce the membrane fouling and recover the permeate flux sufficiently for MF membrane having a large pore size as C010. Average rejection rates of pollutants were higher than $99.0\%$ for turbidity and $22.8{\~}59.6\%$ for $COD_{cr}$, but rejection rates of total dissolved solid (TDS) were lower than $8.9\%$. Therefore, the low turbidity water purified in our system could be reused for paper process.

• Membrane and Water Treatment
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• 제1권3호
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• pp.193-206
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• 2010

Organic fouling and biofouling pose a significant challenge to the membrane filtration process. Photocatalysis-membrane hybrid system is a novel idea for reducing these membranes fouling however, when $TiO_2 photocatalyst nanoparticles are used in suspension, catalyst recovery is not only imposes an extra step on the process but also significantly contributes to increased membrane resistance and reduced permeate flux. In this study, $TiO_2$ photocatalyst has been immobilized by coating on the microfiltration (MF) membrane surface to minimize organic and microbial fouling. Nano-sized $TiO_2$ was first synthesized by a sol-gel method. The synthesized $TiO_2$ was coated on a Poly Vinyl Difluoride (PVDF) membrane (MF) surface using spray coating and dip coating techniques to obtain hybrid functional composite membrane. The characteristics of the synthesized photocatalyst and a functional composite membrane were studied using numerous instruments in terms of physical, chemical and electrical properties. In comparison to the clean PVDF membrane, the $TiO_2$ coated MF membrane was found more effective in removing methylene blue (20%) and E-coli (99%).

• 환경위생공학
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• 제12권2호
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• pp.65-74
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• 1997

The purpose of this study was to investigate the removal effect and variation of contaminated water by various water treatment processes using sediment filter, activated carbon, photocatalysis, reverse osmosis, ultra violet sterilizer and ultra filtration. The removal effect of chloride and trace metal was low by activated carbon and ultra filter but high in reverse osmosis. The removal effect of bacteria and E. coli was low by activated carbon and membrane filter system using activated carbon but high in impregnated activated carbon. The removal effect of TCE was low in sand and ultra filter system as compared with activated carbon. Ultra filtration process was effective for purify agricultural water without E.coli. Reverse osmosis was effective to remove heavy metal and activated carbon was effective to remove halogenated organic chemical compound. The flux and the removal effect of COD in spiral wound ultrafilter were higher than the hollow fiber ultrafilter.

• 멤브레인
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• 제23권1호
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• pp.45-53
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• 2013

현재 분리막 여과 공정은 정수처리에서 많은 관심을 받고 있다. 하지만, 분리막의 효율적인 운영을 위하여 '혼화/응집(/침전)' 등의 전처리 시설 설치로 인한 부지면적 및 비용증가와 5~10%의 배출수 문제가 추가적으로 발생한다. 그래서 본 연구에서는 전처리 공정 없이 지표수(한강)에 대하여 가압식 PVDF 분리막[(주)에코니티]으로 운전하여 성능을 검토하였으며 그 결과 1년 동안 화학적 세정 없이 여과 flux가 1~2.4 m/d (at $25^{\circ}C$)로 운전되었고, 유입원수의 탁도와 상관없이 분리막 처리수의 탁도는 0.05 NTU 이하로 안정되게 유지되었다. 또한, 회수율 제고를 위하여 1개월 동안 가압식 배출수(역세수 + 배수)를 침지식 PE 분리막[(주)에코니티]으로 연계하여 2단 막여과 운영을 한 결과 전체 공정 회수율을 99.5%까지 증가시킬 수 있었다.

• 한국축산시설환경학회지
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• 제6권3호
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• pp.175-184
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• 2000

Lab-scale의 실험을 통하여 축산폐수의 액비화에 있어서 막 분리 기술의 도입에 따른 막 오염 특성과 투과특성에 대해 살펴본 결과 다음과 같은 결론을 얻을 수 있었다. 1. System의 안정적 운전을 위해서는 낮은 투과유속에서의 운전이 효과적이라 사료되며, Tmax가 지수 함수적으로 투과유속에 대해 감소하였다. 이를 통해서 예측식을 수립하여 운전에 있어서의 막 세정 시기를 결정할 수 있을 것으로 사료된다. 2. 전반적인 막 자체에 대한 순수투과저항을 관찰해본 결과 막 오염은 비가역적 영역보다는 가역적 영역에 의해 이루어진다고 사료된다. 3. 투과유속이 낮을 경우 막면 부착물에 의한 여과저항의 상승이 막 오염의 주된 원인이 되는 반면, 투과유속이 증가할수록 농도분극현상이 막 오염의 주된 원인이 된다고 사료된다. 따라서 높은 투과유속에서의 운전을 위해서는 이러한 농도 분극현상을 최소화 하기 위해서는 이러한 농도 분극현상을 최소화 하기 위하여 높은 전단응력을 제공하거나 막표면에 물리적 충격을 주어 농도 분극현상을 제어하는 방법이 추가되어야 할 것이라 사료된다. 4. 중력여과 및 간헐여과를 통한 막 분리 특성을 살펴본 결과 중력여과의 경우 별도의 흡입압력을 부여하지 않고 단지 수위차에 의해 생성되는 위치에너지에 의한 여과에서도 1.7LMH에서 약 3.5일간 안정되게 유지된 것을 확인할 수 있었으며, 간헐여과를 통해 농도 분극현상을 감소시킴으로 해서 연속여과보다 안정된 운전이 이루어졌다. 종합적으로 고찰해 봤을 때, 축산폐수의 액비화에 있어서 막 분리 기술의 도입은 그 유출수의 성상에 있어서 원수의 성상에 상관없이 일정한 질을 보이고 있음을 확인할 수 있었고, 공정의 안정적 유지를 위해서는 낮은 투과유속의 흡입과 정지의 간격이 비교적 긴 간헐여과 방식이 적합하다고 사료되며, 높이차를 이용한 중력여과 또한 추가적인 연구가 진행된다면 동력의 소모면에서 이점이 있을 것이라 사료된다.기는 축사의 난방 보조열원으로서 양호한 열효율을 나타내어 우리나라 축사시설에 적용가능성을 제시하였다. 본 지열교환기 시스템은 지열을 이용하는 환경보전형 에너지 시스템으로서 시설하기 간편하고 경제적이며 반영구적인 냉난방 및 환기시스템이다. 따라서, 우리나라 축산시설에 실용화될 경우에 우수한 대체에너지원으로 에너지 절감효과에도 크게 기여하리라고 전망된다.ble amount of acid mucin, Most of the medium sized and small mucous cells contained neutral mucin and sialomucin, but a few mucous cells contained neutral mucin and strongly sulfomucin or neutral combined with strongly sulfomucin and sialomucin. Most of the esophageal mucous cells pf Bryzoichthys lysimus contained small amount of neutral mucin, while on the other hand a feww mucous cells contained small amount of neutral mucin and minimal amount of sialomucin. But the esophageal mucous cells of Takifugu pardalis contained considerable amount of neutral mucin only.분해가 더욱 촉진되었으며, 30℃에서 교반 처리를 행한 경우가 10℃에서 교반 처리를 행한 경우 보다 지방분해가 더욱 촉진되었다. 산양유 원유는 30℃에서 교반 처리 시간이 연장되어도 지방분해는 뚜렷한 증가를 나타내지 않았다.와 표준체중군 여자에게서 가장 높게 나타났다. 5. 남자의 53.9%, 여자의 83.2%가 체중 조절에 관심이 있다

• Environmental Engineering Research
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• 제9권5호
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• pp.238-247
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• 2004

The objective of this study was to develop kinetic model for the MBR and investigate kinetic characteristics of the gravitational flow transverse direction MBR system. Kinetic model was derived by mass balance of substratc and biomass combined with empirical membranc filtration rerm for the MBR. To find kinctic values, permeale flux and COD removal were analyzed through the laboratory, MBR operation as different solids retention times. Permeate flux was ranged 2.5-5.0 LMH (L/m$^2$/hr) as sludge characteristics in each run. Although the soluble COD in the bioreactor was changed, the effluent COD was stable as average 99% removal rate during the experimental periods. Y$_g$ of this MBR system was higher than those of cross-flow MBR processes. The kinetics of this MBR showed that smaller k, larger b, and larger K$_s$ values than the conventional activated sludge process. These results indicated that substrate was used for cell maintenance rather than growth in this MBR system.

• 한국염색가공학회지
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• 제17권4호
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• pp.21-26
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• 2005

A combination separation system is composed of three parts, simple microfiltration unit for the pretreatment of real waste IPA, pervaporation unit with plate and frame type module(the effective membrane area 9,040$cm^2$), and simple ultrafiltration unit as a refiner. Utrafiltration module with hollow fiber membrane(MWCO 10,000) used to purify waste aqueous IPA solution. In addition, the flux of $CMPA-K^+$ composite membrane for waste aqueous IPA solution was very steady-state with long experiment time(30 days). And the standard deviation($\sigma$) was 0.152 and then the coefficient of variation($CV\%$)was 10.82 The IPA concentration on the membrane performance using pervaporation module system could be increased from $89.85wt(\%)$ to more than $99.90wt\%$ in about 8hr at operation temperature of $70^{\circ}C$ using the pervaporation module system. Therefore, a combination separation process system of simple filtration and pervaporation was very effective for the purpose of the IPA purification and reuse front industrial electronic components cleaning process.

• Membrane and Water Treatment
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• 제9권1호
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• pp.17-21
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• 2018

A series of laboratory scale experiments were performed to investigate the feasibility of membrane separation technology for natural rubber (NR) wastewater treatment and reuse. Three types of spiral wound membranes were employed in the cross-flow experiments. The NR wastewater pretreated by sand filtration and cartridge filtration was forced to pass through the ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes successively. The UF retentate, which containing abundant proteins, can be used to produce fertilizer, while the NF retentate is rich in quebrachitol and can be used to extract quebrachitol. The permeate produced by the RO module was reused in the NR processing. Furthermore, about 0.1wt% quebrachitol was extracted from the NR wastewater. Besides, the effluent quality treated by the membrane processes was much better than that of the biological treatment. Especially for total dissolved solids (TDS) and total phosphorus (T-P), the removal efficiency improved 53.11% and 49.83% respectively. In addition, the removal efficiencies of biological oxygen demand (BOD) and chemical oxygen demand (COD) exceeded 99%. The total nitrogen (T-N) and ammonia nitrogen (NH4-N) had approximately similar removal efficiency (93%). It was also found that there was a significant decrease in the T-P concentration in the effluent, the T-P was reduced from 200 mg/L to 0.34 mg/L. Generally, it was considered to be a challenging problem to solve for the biological processes. In brief, highly resource utilization and zero discharge was obtained by membrane separation system in the NR wastewater treatment.