Separation Purification Characteristics of Rinsing Solution in Semiconductor Process using High Performance Polymer Membranes( II )

기능성 고분자막을 이용한 반도체 공정 세정액의 분리정제특성( II )

  • Lee Jae-Dal (Dept. of Textile Hyjeon Junior College) ;
  • Hong Young-Ki (Sun Jin. Inc.) ;
  • Ro Duck-Kil (Dept. of Fashion Design & Textile Eng., Chungwoon Univ.) ;
  • Bae Kie-Seo (Dept. of Textile Engineering, Chungnam National University)
  • 이재달 (혜전대학 패션섬유과) ;
  • 홍영기 ((주)선진인더스트리) ;
  • 노덕길 (청운대학교 패션디자인섬유공학과) ;
  • 배기서 (충남대학교 섬유공학과)
  • Published : 2005.08.01

Abstract

A combination separation system is composed of three parts, simple microfiltration unit for the pretreatment of real waste IPA, pervaporation unit with plate and frame type module(the effective membrane area 9,040$cm^2$), and simple ultrafiltration unit as a refiner. Utrafiltration module with hollow fiber membrane(MWCO 10,000) used to purify waste aqueous IPA solution. In addition, the flux of $CMPA-K^+$ composite membrane for waste aqueous IPA solution was very steady-state with long experiment time(30 days). And the standard deviation($\sigma$) was 0.152 and then the coefficient of variation($CV\%$)was 10.82 The IPA concentration on the membrane performance using pervaporation module system could be increased from $89.85wt(\%)$ to more than $99.90wt\%$ in about 8hr at operation temperature of $70^{\circ}C$ using the pervaporation module system. Therefore, a combination separation process system of simple filtration and pervaporation was very effective for the purpose of the IPA purification and reuse front industrial electronic components cleaning process.

Keywords

References

  1. B.Berger, 'Control of organic susbstances in water and waste water', Noyes Data Corporation, New Jersey, 1987
  2. R.W.Baker, E.L.Cussler, W.Eykamp, W.J.Koroe, R.L.Riley, and H. Strathmann, 'Membrane separation system', Noyes, Data Corporation, New Jersey, 1991
  3. M.C.Porter, 'Handbook of Industrial membrane Technology', Noyes Pub. Co., New Jersey, 1990
  4. The Membrane Society of Korea, 'Membrane separation', 自由 academy, 99-101(1996)
  5. 大失晴彦, '膜利用技術 ハンドブック 逆浸透法, 限外濾過法, II 應用', 辛書房, 東京(1978)
  6. M. Cheryan, 'Ultrafiltration and microfiltration handbook', TECHNIMIC Publishing Co. Inc., 1-28, 146-147(1998)
  7. L. Nelson and M.C. Porter, 'Recent developments in separation science', Vol II Li. N. N. Ed., CRC Press, Boca Raton, Florida, 227(1972)
  8. E. Flaschel, C. wandrey and M.R. Kula, 'In advances in bio-chemical engineering and biotechnology', Fiechter, A., Ed., Springerverlag, Berlin, 73(1983)
  9. M.Ghazali, M.Nawawi and R.Y.M.Huang, Pervaporation dehydration of isopropanol with chitosan me!TIbranes, J. Memb., Sci., 124, 53-62 (1997) https://doi.org/10.1016/S0376-7388(96)00216-5
  10. K.M.Song and W.H.Hong, Dehydration of ethanol and isopropanol using tubular type cellulose acetate membrane with ceramic support in perva poration process, J. Memb. Sci., 123, 27-33(1997) https://doi.org/10.1016/S0376-7388(96)00198-6
  11. Y. M. Lee, S. Y. Nam, B. K. Oh, B. R. Lee, D. J. Woo, K. H. Lee, J. M. Won, and B. H. Ha, 'Dehy­dration of alcohol solutions through crosslinked chitosan composite membranes - I. Preparation of chemically corsslinked chitosan composite membranes and ethanol dehydration', The Membrane Journal, The Membrane Society of Korea, 6, pp 37-43(1996)
  12. G.H.Koops, J.A.Nolten, M.H.V.Mulder, and C.A.Smolders, Poly(vinylchloride) polyacrylo­nitrile composite membranes for the dehydration of acetic acid, J. Memb. Sci., 81, 57-70(1993) https://doi.org/10.1016/0376-7388(93)85031-Q
  13. L.Liang and E.Ruckenstein, Polyvinyl alcohol-polyacrylamide interpenetrating polymer network membranes and their pervaporation characteristics for ethanol-water mixtures, J. Memb. Sci., 106, 167-182(1995) https://doi.org/10.1016/0376-7388(95)00137-2
  14. 三菱化學, 三菱電機, 三菱化成 Engineering 第21回 優秀環境裝置 'IPA 回收精製system', 日本産業機械工業會發行 産業機械, 9月(1996)
  15. Jae-Dal Lee, Young-Ki Hong and Kie-Seo Bae, Separation Purification Characteristics of Rinsing Solution in Semiconductor Process using High Performance Polymer Membranes(I), J. Korean soc. Dyers & Finishers, in press, (2003)