• 한국자기공명학회논문지
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• 제10권2호
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• pp.175-187
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• 2006

Binding interactions between a positively charged porphyrin derivative TMAP(meso-tetra(p-trimethylanilinium-4-yl)porphyrin) and triple helical $(dT)_{12}{\cdot}(dA)_{12}{\cdot}(dT)_{12}$, as well as double helical $(dA)_{12}{\cdot}(dT)_{12}$ have been studied with NMR, UV and CD spectroscopy to obtain the detailed information about the binding mode and binding site. UV melting studies showed both DNA duplex and triple helix represented very similar UV absorption patterns upon binding TMAP, but the presence of third strand of triple helical $(dT)_{12}{\cdot}(dA)_{12}{\cdot}(dT)_{12}$, inhibited improvement in thermal stability in terms of melting temperature, $T_m$. In addition, the TMAP molecule is thought to bind to the major groove, according to CD and NMR data. But absence of the clear isosbestic point in UV absorption spectra represented that binding of TMAP to DNA duplex as well as DNA triplex did not show a single binding mode, rather complex binding modes.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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• pp.73-76
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• 2004

High-temperature Superconductor(HTS) tubes were fabricated in term of different processing variables such as preheating temperature, speed of mold rotation and cooling rate by centrifugal forming method. For powder melting by induction the optimum range of melting temperatures and preheating temperature were $1050^{\circ}C{\sim}1100^{\circ}C$ and $550^{\circ}C$ for 30min, respectively. The mould roating speed was 1000rpm. A tube was annealed at $840^{\circ}C$ for 72hours in oxygen atmosphere. The plate-like grains were well developed along the roating direction and typical grain size was about more than $40{\mu}m$. It was found that Ic values increased with increasing the preheating temperature and speed of mold rotation. While Ic decreased with increasing the cooling rate. The measured Ic in $50mm{\times}70mm{\times}2.5mm$ tube was about 896Amp.

• 한국진공학회:학술대회논문집
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• 한국진공학회 1998년도 제14회 학술발표회 논문개요집
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• pp.18-18
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• 1998

F First I will introduce our works how to improve the crystal growth t technique for Rare earth pnictides and chalcogenides. All these substances h have hi양1 vapor pressure and high melting print up to 3$\alpha$)()C. 까len we employ m the tungsten or molybden crucibles and enclose the sample by 빼e welding of m the lid with high current electron beam. We cannot elevate the temperature up t to 3$\alpha$)()C without suitable radiation shield because rate of radiation loss r rapidly increase in such a high temperature regions. There were no good r radiation shield but we discovered that the p-BN could work as an excellent r radiation shield after checking of the many substances. S Secondly I will show several interesting and unusual 뻐ysical properties of obtained crystals under high magnetic field, hi양1 pressure and also i including angle resolve photoemission spectroscopy. I will stress the p properties of the low carrier concentration with strong correlation on C댐, U USb and Yb4As3

• Transactions on Electrical and Electronic Materials
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• 제5권2호
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• pp.55-60
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• 2004

High-temperature Superconductor(HTS) tubes were fabricated in terms of different chemical compositions and various SrSO$_4$additions by centrifugal forming method. For powder melting by induction the optimum range of melting temperatures and preheating temperature were 1050$^{\circ}C$, 1100$^{\circ}C$ and 550$^{\circ}C$ for 30 min, respectively. The mould rotating speed was 1000 rpm. A tube was annealed at 840$^{\circ}C$ for 72 hours in oxygen atmosphere. The plates like grains more than 20 $\mu\textrm{m}$ were well developed along the rotating direction of mould regardless of initial chemical compositions and the amounts of SrSO$_4$in Bi2212. The specimen with Bi2212 composition exhibited T$\_$c/ of 83 K, while the specimens fabricated with other compositions are lower than 60 K. The measured I$\_$c/ and J$\_$c/ at 77 K(B = 0 T) in Bi2212 with 7 % SrSO$_4$ composition were about 680 A and 380 A/$\textrm{cm}^2$.

• Elastomers and Composites
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• 제54권1호
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• pp.61-69
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• 2019

Poly(ethylene-co-vinyl acetate) (EVA) is a copolymer of ethylene and vinyl acetate (VA). It is important to determine the VA content of EVA, since the properties of EVA depend highly on the VA content. EVA copolymers have been used in a wide range of applications appropriate for the different VA contents. IR, NMR, and TGA are generally used for determination of the VA content of EVA copolymers. Of these, TGA is the most reliable method and can be applied to cured EVAs. Analytical methods for determination of the VA content and properties of EVA copolymers via TGA were herein reviewed. Thermal behaviors of EVA copolymers (glass transition temperature ($T_g$), melting point ($T_m$), and crystallization temperature ($T_c$)) determined by DSC were also reviewed. Analysis of the related literature revealed that the $T_g$, $T_m$, and $T_c$ decrease by about 0.46, 1.36, and $2.08^{\circ}C$, respectively, for every 1 wt% in VA content. A method for determining the degree of crosslinking of cured EVA copolymers was also reviewed, and the degree of crosslinking tends to increase with the decrease in the VA content.

• Current Applied Physics
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• 제18권12호
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• pp.1523-1527
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• 2018

The thermal stability, magnetic and magnetocaloric properties of $Gd_{55}Co_{35}M_{10}$ (M = Si, Zr and Nb) melts-pun ribbons were studied. The relatively high reduced glass transition temperature ($T_{x1}/T_m$ > 0.60) and low melting point ($T_m$) resulted in excellent glass forming ability (GFA). The Curie temperatures ($T_C$) of melt-spun amorphous ribbons $Gd_{55}Co_{35}M_{10}$ for M = Si, Zr and Nb were 166, 148 and 173 K, respectively. For a magnetic field change of 2 T, the values of maximum magnetic entropy change $(-{\Delta}S_M)^{max}$ for $Gd_{55}Co_{35}Si_{10}$, $Gd_{55}Co_{35}Zr_{10}$ and $Gd_{55}Co_{35}Nb_{10}$ were found to be 2.86, 4.28 and $4.05J\;kg^{-1}K^{-1}$, while the refrigeration capacity (RC) values were 154, 274 and $174J\;kg^{-1}$, respectively. The $RC_{FWHM}$ values of amorphous alloys $Gd_{55}Co_{35}M_{10}$ (M = Si, Zr and Nb) are comparable to or larger than that of $LaFe_{11.6}Si_{1.4}$ crystalline alloy. Large values of $(-{\Delta}S_M)^{max}$ and RC along with good thermal stability make $Gd_{55}Co_{35}M_{10}$ (M = Si, Zr and Nb) amorphous alloys be potential materials for magnetic cooling operating in a wide temperature range from 150 to 175 K, e.g., as part of a gas liquefaction process.

• 한국식품과학회지
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• 제27권3호
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• pp.306-312
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• 1995

저온적습$(5^{\circ}C$, 65%)과 고온다습($30^{\circ}C$, 85%) 조건에서 16주 동안 저장한 쌀로부터 분리한 전분의 이화학적 성질은 다음과 같다. 물결합력은 저장 8주까지는 약간씩 증가하다가 그 이후는 감소하였으며, 저장기간이 같은 경우 저온적습보다 고온다습에서 저장하였을 때 더 높은 경향을 보였다. 팽윤력, 용해도, 광투과도, 요오드반응 및 총아밀로오스 함량은 저장기간이 길어짐에 따라 각각 감소되었고, 저장기간이 같은 경우 저온적습에서보다 고온다습에서 저장하였을 때 약간 낮은 값을 보였다. 전분입자의 크기는 $2{\sim}6{\mu}m$ 정도이며 저장기간과 조건에 따른 입자의 크기나 표면형태의 변화는 나타나지 않았다. X-ray 회절도에 의한 상대적 결정화도는 저장 4주째부터 크게 낮아졌으며 그 이후는 약간씩 감소되었고, 저장기간이 같은 경우 저온적습보다 고온다습에서 더 낮았다. DSC분석 결과 저장기간이 길어짐에 따라 호화온도는 약간 상승되었으나, 호화온도 범위는 차이가 없었고 호화 엔탈피는 약간 낮았다. 저장기간이 같은 경우 저온적습보다 고온다습에서 변화정도가 더 크게 나타났다. 고온에서 나타나는 amylose-lipid complex melting peak는 저장기간이 길어짐에 따라 융해되는 온도범위가 다소 넓어졌고 정점온도도 약간 상승되었으며, 엔탈피도 증가되었다. 동일한 저장기간인 경우 저온적습보다 고온다습에서 저장하였을 때 위와 같은 경향이 뚜렷하게 나타났다.

• 한국염색가공학회지
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• 제3권3호
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• pp.23-28
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• 1991

Poly(1, 4-cyclohexanedimethylene/ethylene terephthalate), PCET was prepared by condensing 1, 4-cyclohexanedimethanol(CHDM) and ethylene glycol with dimethylterephthalate(DMT), and some thermal properties of PCET were studied by DSC at a heating rate $20^{\circ}C$min. On increasing the CHDM content in PCET up to 20 mole%/DMT, the glass transition temperature(Tg) decreased a little and the crystallizability reduced sharply, and from 20 to 50 mole %/DMT the $T_g$ did not changed and the crystallization temperature was not detected. But on increasing the CHDM content above 70 mole %/DMT the TEX>$T_g$/ and the melting temperature increased.

• 한국농업기계학회:학술대회논문집
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• 한국농업기계학회 1993년도 Proceedings of International Conference for Agricultural Machinery and Process Engineering
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• pp.443-452
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• 1993

Direct freezing tests of soybean seed by liquid nitrogen were carried out at various moisture contents and the following important conclusions were drawn from the results of temperature measurements of soybean seed and photographs of bubbles generated on its surface : 1) Assuming that the temperature gradient in a soybean seed is negligible because of its small seed size and the freezing ratio is followed the Heiss's formula, and a differential equation based on the heat energy balance was introduced . The equation was easily solved by the Runge-Kutta-Gill method and the predicted values of the temperature were in good agreement with the observed data. 2) The photographs of bubble generation during freezing showed the boiling mode was nucleate, and then the most suitable formula on the nucleate boiling heat transfer was introduced from many formulate proposed up to now by fitting the calculated values based on the formula to the observed data. The formula used for the predict on of the seed temperature was as follows: $\frac{{\partial}T_s}{\partial\theta}\;=\;-\frac{{\alpha}(T_s\;-\;T_L)^{3.3}}{W(C_s\;-\;\frac{{\delta}m(CT_s\;+\;{\sigma})}{T_s^2})}$ where C = difference of the specific heat between pure ice and water m=moisture content of soybean seed $T_s$ = seed temperature $T_L$ = Temperature of liquid nitrogen W = mass of soybean seed $\alpha$ = proportional constant $\delta$ = constant depends on variety or the type of seed $\theta$ = time $\sigma$ = latent heat of melting of pure ice This study will give important information in the hydro-freezing technique by liquid nitrogen, available as a new technique of processing agricultural products in the near future.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2001년도 추계학술발표회 초록집
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• pp.67-67
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• 2001

The structure zone model has been used to provide an overview of the relationship between the microstructure of the films deposited by PVD and the most prominent deposition condition.s. B.AMovchan and AV.Demchishin have proposed it firstls such model. They concluded that the general features of the resulting structures could be correlated into three zones depending on $T/T_m$. Here T m is the melting point of the coating material and T is the substrate temperature in kelvines. Zone 1 ($T/Tm_) is dominated by tapered macrograins with domed tops, zone 2 ($O.3) by columnar grains with denser boundaries and zone 3 ($T/T_m>O.5$) by equiaxed grains formed by recrystallization. J.AThomton has extended this model to include the effect of the sputtering gas pressure and found a fourth zone termed zone T(transition zone) consisting of a dense array of poorly defined fibrous grains. R.Messier found that the zone I-T boundary (fourth zone of Thorton) varies in a fashion similar to the film bias potential as a function of gas pressure. However, there has not nearly enough model for explaining the change in morphology with crystal orientation of the films. The structure zone model only provide an information about the morphology of the deposited film. In general, the nucleation and growth mechanism for granular and fine structure of the deposited films are very complex in an PVD technique because the morphology and orientation depend not only on the substrate temperature but also on the energy of deposition of the atoms or ions, the kinetic mechanism between metal atoms and argon or nitrogen gas, and even on the presence of impurities. In order to clarify these relationship, AI and Mg thin films were prepared on SPCC steel substrates by PVD techniques. The influence of gas pressures and bias voltages on their crystal orientation and morphology of the prepared films were investigated by SEM and XRD, respectively. And the effect of crystal orientation and morphology of the prepared films on corrosion resistance was estimated by measuring polarization curves in 3% NaCI solution.