• 제목/요약/키워드: melting rates

검색결과 92건 처리시간 0.022초

제철 소결기 배드 내 연소 및 열전달 모델링;인자 변화에 의한 계산 결과 평가 (Modeling of Combustion and Heat transfer in the Iron Ore Sintering Bed;Evaluation of the Calculation Results for Various Cases)

  • 양원;류창국;최상민
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2002년도 제24회 KOSCO SYMPOSIUM 논문집
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    • pp.171-178
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    • 2002
  • Numerical simulations of the condition in the iron ore sintering bed are performed for various parameters. The sintering bed is modelled as an unsteady one-dimensional progress of solid material, containing cokes and iron ore. Bed temperature, solid mass and gas species distributions are predicted for various parameters of moisture contents, cokes contents and air suction rates, along with the various particle diameters of the solid for sensitivity analysis. Calculation results show that influences of these parameters on the bed condition should be carefully evaluated for achievement of the self-sustaining combustion without the high temperature section, which can cause the excessive melting in the bed. It suggests that the model should be extended to consider the bed structural change and multiple solid phase, which can treat the inerts and fuel particles separately.

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다관형 잠열축열장치의 축열특성연구 -물을 매체로 한 축열 및 방열과정 분석- (Study on the Thermal Storage Characteristics of a Multi-capsule type LTES System -Analysis for Heat Charging and Discharging Process for Water Flow-)

  • 김영복
    • Journal of Biosystems Engineering
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    • 제19권1호
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    • pp.62-69
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    • 1994
  • This study was designed to seek information on the heat charging and discharging characteristics of a multi-capsule type LTES(Latent Heat of Fusion Thermal Energy Storage) system, and especially prediction equation of outlet water temperature from the system. During heat charging process, the water temperature in the LTES tank increased very slowly in comparison with a predicted one and was kept near the melting point of the PCM for about 25 minutes. During heat discharging process, the latent heat discharging period of the outlet water temperature became longer as the inlet water temperature became higher and/or mass flow rate became lower. The dimensionless temperature of the outlet water was predicted by linking three equations of ${\theta}=1.1Exp(-{\tau}/0.82)$, ${\theta}=-0.06{\tau}+0.3$, ${\theta}=0.8Exp(-{\tau}/1.4)$ ($r^2{\leq}0.88$) depending on discharging period regardless of mass flow rates on the case of the inlet water temperature at $21.5^{\circ}C$.

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Studies on thermal and swelling properties of Poly (NIPAM-co-2-HEA) based hydrogels

  • Shekhar, Suman;Mukherjee, M.;Sen, Akhil Kumar
    • Advances in materials Research
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    • 제1권4호
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    • pp.269-284
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    • 2012
  • Thermoresponsive hydrogels based on N-Isopropylacrylamide (NIPAM) and 2-Hydroxyethylacrylate (HEA) were prepared by free radical polymerization. The hydrogels were characterized by elemental (CHN) analysis, differential scanning calorimetry (DSC) and thermo gravimetric analysis (TGA). DSC thermogram showed two endothermic transitions which are due to hydration of water present in different environments. One near $0^{\circ}C$ called melting transition of ice and was used to calculate the quantitative determination of the amounts of freezing and non freezing water. The other transition above the ambient temperature was due to the combination of hydrophobic hydration and hydrophilic hydration which changes with the copolymer compositions. Swelling and deswelling studies of the hydrogels were carried out using the aqueous media, salt and urea solutions. The experimental results from swelling studies revealed that copolymers have lower rates of swelling and deswelling than the homopolymer.

전자부품의 인쇄회로기판 부착시 적외선 Reflow Soldering과정 열전달 해석 (Heat Transfer Analysis of Infrared Reflow Soldering Process for Attaching Electronic Components to Printed Circuit Boards)

  • 손영석
    • Journal of Welding and Joining
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    • 제15권6호
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    • pp.105-115
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    • 1997
  • A numerical study is performed to predict the thermal response of a detailed card assembly during infrared reflow soldering. The card assembly is exposed to discontinuous infrared panel heater temperature distributions and high radiative/convective heating and cooling rates at the inlet and exit of the oven. The convective, radiative and conduction heat transfer within the reflow oven as well as within the card assembly are simulated and the predictions illustrate the detailed thermal responses. The predictions show that mixed convection plays an important role with relatively high frequency effects attributed to buoyancy forces, however the thermal response of the card assembly is dominated by radiation. The predictions of the detailed card assembly thermal response can be used to select the oven operating conditions to ensure proper solder melting and minimization of thermally induced card assembly tresses and warpage.

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Dilatometric 분석에 의한 나노구조 W-30 wt%Cu 복합분말의 소결거동연구 (A Study on the Sintering Behavior of Nanostructured W-30 wt%Cu Composite Powder by Dilatometry)

  • 류성수
    • 한국분말재료학회지
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    • 제7권2호
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    • pp.93-101
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    • 2000
  • In order to clarify the enhanced sintering behavior of nanostructured(NS) W-Cu powder prepared by mechaincal alloying, the sintering behavior during heating stage was analysed by a dilatometry with various heating rates. The sintering of NS W-Cu powders was characterized by the densification of two stages, having two peaks in shrinkage rate curves. The temperature at which the first peak appear was much lower than Cu melting point, and dependent on heating rate. On the basis of the shrinkage rate curves and the microstructural observation, the coupling effect of nanocrystalline W-grain growth and the liquid-like behavior of Cu phase was suggested as a possible mechanism for the enhanced sintering of NS W-Cu powder in the state.

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인공치관용(人工齒冠用) Glass-Ceramics의 결정화(結晶化)에 관(關)한 연구(硏究) (A Study on the Crystallization of Glass-Ceramics for Dental Crown)

  • 정인성
    • 대한치과기공학회지
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    • 제14권1호
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    • pp.95-118
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    • 1992
  • Glass ceramics for crown were prepared by adding 3$\sim$11 wt% TiO2 to the weight percent composition of 34.7 CaO, 27.8 SiO2, 18.3P2O5, 12.6MgO and 6.6 TiO2. The starting glasses were prepared by melting the powdered batch in alumina crucible at 1350$\sim$1400 for 1 hr and then quenching into a distilled water. The nucleation and crystallization of the crystalline glass ceramics for crown were studied by DTA, SME and X-ray diffraction analysis. Frit containing 9.11 wt% TiO2 had crystallization temperature of 850$\sim$1075 and major crystalline phase was identified by X-ray diffraction as diopside(CaO-MgO-2SiO2). Activation energies for the crystallization processes were obtained from DTA by varing rates for the fits, and were calculated from modified Ozawa and Kissinger equations. Activation energy for the crystallization processes of the S-4 frit was 489.6 KJ/mol.

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(Cd+Te)막의 소결조건이 CdS/CdTe 태양전지의 특성에 미치는 영향 (Effects of sintering conditions of (Cd+Te) films on the properties of sintered CdS/CdTe solar cells)

  • 노재성;임호빈
    • E2M - 전기 전자와 첨단 소재
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    • 제1권1호
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    • pp.26-34
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    • 1988
  • Sintered CdS/CdTe solar cells have been farbricated by coating a (Cd+Te) slurry on sintered CdS films followed by the sintering at 625.deg.C for one hour with various heating rates. When cadmium and tellurinm powders are used instead of CdTe powder to form CdS/CdTe junction, CdTe is formed in the temperature range of 290.deg.C-400.deg.C. The microstructure of the CdTe films depends strongly on the heating rate of the sintering due to the low melting temperature and the high vapor pressure of the elemental Cd and Te. An optimum heating rate obtain CdTe films with uniform and dense microstructure which, in turn, improves the efficiency of the sintered CdS/CdTe solar cells. All-polycrystalline CdS/CdTe solar cells with an efficiency of 9.57% under 50mW/cm$^{2}$ tungsten light have been farbricated by using a heating rate of 14.deg.C/min.

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자전연소합성 반응중 속빈 TiC 섬유의 형성 기구 (Forming Mechanism of TiC Hollow Fibers during Self-Propagating High Temperature Synthesis)

  • 윤존도;방환철
    • 한국세라믹학회지
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    • 제37권4호
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    • pp.332-337
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    • 2000
  • Forming mechanism of fibrous TiC during self-propagating high temperature synthetic reaction was analyzed and suggested. It was revealed that critical temperature for the stable fiber formation was not the melting point of TiC, but the eutectic reaction temperature of TiC and C. Minimum amount of TiC diluent addition required to form fibers was calculated to be 25.6%, which was consistent with the experimental result. Synthesized fibers were found hollow tube-like. The morphology was explained by the diffusion rates of C and Ti in TiC, and by the molar volume chnage of C during the reaction. Expanding shell model was suggested for the hollow fiber formation mechanism.

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Measurement of Evaporation Rates for Lanthanum and Neodymium Chlorides

  • Kwon, S.W.;Lee, Y.S.;Jung, J.H.;Chang, J.H.;Kim, S.H.;Lee, S.J.
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2017년도 추계학술논문요약집
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    • pp.74-74
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    • 2017
  • Electrorefining is a key step in pyroprocessing. The electrorefining process is generally composed of two recovery steps - the deposit of uranium onto a solid cathode and the recovery of the remaining uranium and TRU elements simultaneously by a liquid cadmium cathode. Uranium deposit recovered from the solid cathode is a dendritic powder. It is necessary to separate the adhered salt from the deposits prior to the consolidation of uranium deposit. The adhered salt is composed of lithium, potassium, uranium, and rare earth chlorides. Distillation process was employed for the cathode processing. One of the operation methods is distillation of the salt at low temperature ($900^{\circ}C$), and then melting of the deposit at high temperature to avoid a backward reaction. For the development of the salt distiller, the distillation behavior of the low vapor pressure chlorides should be studied. Rare earth chlorides in the adhered salt of uranium deposits have relatively low vapor pressures compared to the process salt (LiCl-KCl). In this study, the evaporation rates of the lanthanum and neodymium chlorides were measured for the salt separation from electrorefiner uranium deposits in the temperature range of $825{\sim}910^{\circ}C$. The evaporation rate of both chlorides increased with an increasing templerature. The evaporation rate of lanthanum chloride varied from 0.12 to $1.68g/cm^2/h$. Neodymium chloride was more volatile than lanthanum chloride. The evaporation rate of neodymium chloride varied from 0.20 to $4.55g/cm^2/h$. The evaporation rate of both chlorides are more than $1g/cm^2/h$ at $900^{\circ}C$. Even though the evaporation rates of both chlorides were less than that of the process salt, the contents of the lanthanide chlorides were small in the adhered salt. Therefore it can be concluded that $900^{\circ}C$ is suitable for the operation temperature of the salt distiller.

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High Resolution Melting Curve Assay for Detecting rs12979860 IL28B Polymorphisms Involved in Response of Iranian Patients to Chronic Hepatitis C Treatment

  • Fateh, Abolfazl;Aghasadeghi, Mohammad Reza;Keyvani, Hossein;Mollaie, Hamid Reza;Yari, Shamsi;Tasbiti, Ali Reza Hadizade;Ghazanfari, Morteza;Monavari, Seyed Hamid Reza
    • Asian Pacific Journal of Cancer Prevention
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    • 제16권5호
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    • pp.1873-1880
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    • 2015
  • Background: A recent genome-wide association study (GWAS) on patients with chronic hepatitis C (CHC) treated with peginterferon and ribavirin (pegIFN-${\alpha}$/RBV) identified a single nucleotide polymorphism (SNP) on chromosome 19 (rs12979860) which was strongly associated with a sustained virological response (SVR). The aim of this study was twofold: to study the relationship between IL28B rs12979860 and sustained virological response (SVR) to pegIFN-${\alpha}$/RVB therapy among CHC patients and to detect the rs12979860 polymorphism by high resolution melting curve (HRM) assay as a simple, fast, sensitive, and inexpensive method. Materials and Methods: The study examined outcomes in 100 patients with chronic hepatitis C in 2 provinces of Iran from December 2011 to June 2013. Two methods were applied to detect IL28B polymorphisms: PCR-sequencing as a gold standard method and HRM as a simple, fast, sensitive, and inexpensive method. Results: The frequencies of IL28B rs12979860 CC, CT, and TT alleles in chronic hepatitis C genotype 1a patients were 10% (10/100), 35% (35/100), and 6% (6/100) and in genotype 3a were 13% (13/100), 31% (31/100), and 5% (5/100), respectively. In genotype 3a infected patients, rs12979860 (CC and CT alleles) and in genotype 1a infected patients (CC allele) were significantly associated with a sustained virological response (SVR). The SVR rates for CC, CT and TT (IL28B rs12979860) were 18%, 34% and 4%, respectively. Multiple logistic regression analysis identified two independent factors that were significantly associated with SVR: IL-28B genotype (rs 12979860 CC vs TT and CT; odds ratio [ORs], 7.86 and 4.084, respectively), and HCV subtype 1a (OR, 7.46). In the present study, an association between SVR rates and IL28B polymorphisms was observed. Conclusions: The HRM assay described herein is rapid, inexpensive, sensitive and accurate for detecting rs12979860 alleles in CHC patients. This method can be readily adopted by any molecular diagnostic laboratory with HRM capability and will be clinically beneficial in predicting treatment response in HCV genotype 1 and 3 infected patients. In addition, it was demonstrated that CC and CT alleles in HCV-3a and the CC allele in HCV-1a were significantly associated with response to pegIFN-${\alpha}$/RBV treatment. The present results may help identify subjects for whom the therapy might be successful.