• 한국주조공학회지
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• 제29권5호
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• pp.192-197
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• 2009

The manufacturing and application characteristics of binderless briquette for in-mold melt treatment of ductile cast iron were investigated. The porosity of briquette was decreased with increased magnesium content. The dissolution rate was increased with the latter in the range of 5~10%. The fluxing effect was the best when 5%$CaF_2$ was added. The optimum composition of the binderless briquette was obtained.

• Macromolecular Research
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• 제17권8호
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• pp.616-622
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• 2009

In-depth understanding of the influence of hot pressing and melt processing on the properties of thermoplastic polyurethane (TPU) is critical for effective mechanical recycling of TPU scraps. Therefore, this study focused on the effects of hot pressing and melt mixing on molecular weight (MW), polydispersity index (PDI), melt index (MI), characteristic IR peaks, hardness, thermal degradation and mechanical properties of TPU. The original TPU pellet (o-TPU) showed two broad peaks at lower and higher MW regions. However, four TPU film samples, TPU-0 prepared only by hot pressing of o-TPU pellet and TPU-1, TPU-2 and TPU-3 obtained by hot pressing of melt mixed TPUs (where the numbers indicate the run number of melt mixing), exhibited only a single peak at higher MW region. The TPU-0 film sample had the highest $M_n$ and the lowest PDI and hardness. The TPU-1 film sample had the highest $M_w$ and tensile modulus. As the run number of melt mixing increased, the peak-intensity of hydrogen bonded C=O stretching increased, however, the free C=O peak intensity, tensile strength/elongation at break and average MW decreased. All the samples showed two stage degradations. The degradation temperatures of TPU-0 sample (359 $^{\circ}C$ and 394 $^{\circ}C$)were higher than those of o-TPU (342 $^{\circ}C$ and 391 $^{\circ}C$). While all the melt mixed samples degraded at almost the same temperature (365 $^{\circ}C$ and 381 $^{\circ}C$). The first round of hot pressing and melt mixing was found to be the critical condition which led to the significant changes of $M_n$/$M_w$/PDI, MI, mechanical property and thermal degradation of TPU.

• 한국초전도ㆍ저온공학회논문지
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• 제5권3호
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• pp.1-5
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• 2003

The effect of CeO$_2$ coating on the surface nucleation of the top-seeded melt-growth processed YBCO superconductors was studied. It was effective that the coating of Y123 compact surfaces by CeO$_2$ powder suppressed the undesirable subsidiary YBa$_2$Cu$_3$O$_{7-y}$ (Y123) nucleation during melt processing. BaCeO$_3$ was formed in the CeO$_2$-coated layers, which might cause a CuO-excessive liquid at the partial melt stage of $Y_2$BaCuO$_{5}$(Y211) plus liquid, and thus the Y123 nucleation at the YBCO compact surfaces could be suppressed during the melt growth of Y123 grain. In addition, the CeO$_2$ refined the Y211 particles near the compact / coating interface. While the levitation forces of the top surfaces with and without CeO$_2$ coating were similar to each other, the levitation force of the interior of the CeO$_2$ coated sample was higher than that of the interior of the sample without CeO$_2$ coating, which was attributed to the suppression of subsidiary Y123 nucleation at the compact walls.s.s.

• 한국주조공학회지
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• 제26권5호
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• pp.222-226
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• 2006

Steel making slag has gained a considerable attraction as one candidate of eco-materials in research fields for recycling resources. Thus, many researches have been performed but were limited to development of substitute for cement being used in the construction field. A little research work also has been done on development of higher value-added materials, including heat resistant and sound absorbing materials. For this reason, the present study were focused on macrostructure characterization of fabricated slag fibers which are applicable to heat resistant materials. The slag fibers were fabricated through a modified melt extraction method. The processing variables employed were the wheel speed and molten slag temperature. The synthesized fibers were characterized by optical microscope and scanning electron microscopy. It was found that the wheel speed of 1400 rpm generated better quality of mineral fibers in terms of the relative amount of shot, diameter and length. This was attributed to the relative extent of contact width between the flowing melt and the rotating wheel. The thickness of the slag fibers also were decreased with increasing the slag melt temperature due mainly to significant decrease in the viscosity of the slag melt. In addition, the lower melt temperature caused an increase in number of shots plus the mineral fibers.

• Journal of Advanced Marine Engineering and Technology
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• 제31권3호
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• pp.282-292
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• 2007

The present paper describes the results of high speed photography, acoustic emission (AE) detection and plasma light emission (LE) measurement during $CO_2$ laser welding of 304 stainless steel in different processing conditions. Video images with high spatial and temporal resolution allowed to observe the melt dynamics and keyhole evolution. The existence of keyhole was confirmed by the slag motion on the weld pool. The characteristic frequencies of flow instability and keyhole fluctuations at different welding speed were measured and compared with the results of Fourier analyses of temporal AE and LE spectra. The experimental results were compared with the newly developed numerical model of keyhole dynamics. The model is based on the assumption that the propagation of front part of keyhole into material is due to the melt ejection driven by laser induced surface evaporation. The calculations predict that a high speed melt flow is induced at the front part of keyhole when the sample travel speed exceeds several 10 mm/s. The numerical analysis also shows the hump formation on the front keyhole wall surface. Experimentally observed melt behavior and transformation of the AE and LE spectra with variation of welding speed are qualitatively in good agreement with the model predictions.

• 소성∙가공
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• 제13권1호
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• pp.39-44
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• 2004

Transcribability of pit or land groove structures in replicating an optical disk substrate greatly affects the performance of a high-density optical disk. However, a solidified layer, generated during the polymer filling, deteriorates transcribability because the solidified layer prevents the polymer melt from filling the sub-micro patterns. Therefore, the development of the solidified layer during filling stage of injection molding must be delayed. For this delay, passive heating by insulation layer has been used. In the present study, to examine the development of the solidified layer delayed by passive heating, the flow of polymer melt with passive heating was analyzed. Passive heating markedly delayed the development of the solidified layer, reduced the viscosity of the polymer melt, and increased the fluidity of the polymer melt in the vicinity of the stamper surface with the sub-micro patterns. As a result, we predict that passive heating can improve transcribability of an optical disk substrate. To verify our prediction, we fabricated an optical disk substrate by using passive heating of a mold and measured the transcribability of an optical disk substrate.

• 한국주조공학회지
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• 제15권5호
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• pp.459-468
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• 1995

For high performance aerospace structures, the properties of highest priority are low density, high strength, and high stiffness(modulus of elasticity). Addition of beryllium decrease the density of the aluminum alloy and increase the strength and the stiffness of the alloy. However it is very difficult to produce the Al-Be alloy having useful engineering properties by conventional ingot casting, because of the extremely limited solid solubility of beryllium in aluminum. So, rapid solidification processing is necessary to obtain extended solid solubility. In this study, rapidly solidified Al-6 at% Be alloy were prepared by twin roll melt spinning process and single roll melt spinning process. Twin roll melt spun ribbons were extruded at $450^{\circ}C$ with reduction in area of 25 : 1 after vacuum hot pressing at $550^{\circ}C and 375^{\circ}C$. The microstructure of melt spun ribbon exhibited a refined cellular microstructure with dispersed Be particles. As advance velocity of liquid/solid interface increase, the morphology of Be particle vary from rod-like type to spherical type and the crystal structure of Be particle from HCP to BCC. These microstructural characteristics of rapidly solidified Al-6at.%Be alloy were described on the basis of metastable phase diagram proposed by Perepezko and Boettinger. The extruded ribbon consisted of recrystallized grains dispersed with Be particles and exhibited improved tensile property compared with that of extruded ingot.

• 한국유변학회:학술대회논문집
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• 한국유변학회 2001년도 Australian-Korean Rheology Conference 2001
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• pp.160.5-161
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• 2001

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2004년도 High Temperature Superconductivity Vol.XIV
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• pp.17-17
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• 2004

• 한국세라믹학회지
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• 제42권6호
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• pp.437-442
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• 2005

We fabricated BSCCO-2212 (2212) bulk superconductor by melt casting process, and evaluated the dependence of the critical properties on the temperature and cooling .ate of mold and the pouring methods of melt. It was observed that the critical current (Ic) of 2212 was significantly dependent on the pre-heating temperature of the mold. At the pre-heating temperature of $500^{\circ}C$ followed by air cooling condition, Ic of 48 A at 77 K was obtained which was higher than others processed at different temperatures. In addition, the Ic improved to 132 A when tilt casting method was applied. The improved Ic is probably due to the fact that the tilt casting reduced a turbulent flow of the melt during casting causing less porosity and more homogeneous microsructure. Critical temperature was measured to be 87-89 K after the first heat treatment and it improved to 90-91 K when subsequently heat treated at $650^{\circ}C$ in a nitrogen atmosphere. This improvement was considered to be due to an optimization of the oxygen content in the range of 8.16-8.2.