• Macromolecular Research
• /
• 제16권7호
• /
• pp.644-650
• /
• 2008

This study examined the effect of nanoclays on the shape memory behavior of polyurethane (PU) in fibrous form. A cation was introduced into the PU molecules to disperse the organo-nanoclay (MMT) into poly($\varepsilon$-caprolactone) (PCL)-based PU (PCL-PU). The MMT/PCL-PU nanocomposites were then spun into fibers through melt-processing. The shape memory performance of the spun fibers was examined using a variety of thermo-mechanical tests including a new method to determine the transition temperature of shape memory polymers. The MMTs showed an improved the fixity strain rate of the MMT /PCL- PU fibers but a slight decrease in their recovery strain rate. This was explained by the limited movement of PU molecules due to the presence of nanoclays. The shape memory performance of the MMT/PCL-PU fibers was not enhanced significantly by the nanoclays. However, their recovery power was improved significantly up to a strain of approximately 50%.

• Macromolecular Research
• /
• 제8권4호
• /
• pp.186-191
• /
• 2000

Clay-dispersed nanocomposites have been prepared by simple melt-mixing of three components, i.e. poly (styrene co-acrylonitrile) copolymer (SAN), poly ($\xi$-caprolactone ) (PCL), and an organophilic clay(Cloisite(R) 30A). In the present study, poly($\xi$-caprolactone) was added in the mixtures in order to facilitate the intercalation of SAN into the gallery of silicate layers, and the molecular weight effects of PCL on the dispersion of silicate layers were compared by changing the amount of added PCL. The degree of dispersion of 10-$\AA$-thick silicate layers of clay in the nanocomposites was investigated by using an X-ray diffractometer and a transmission electron microscope. It was found that PCL added in the mixture facilitate the intercalation of SAN copolymers into the galleries of silicate layers modified with an organic intercalant, resulting in the better dispersion of clay. It was, also, observed that the processing temperature influences the degree of clay dispersion.

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
• /
• pp.364-365
• /
• 2006

Nanostructured or partially amorphous Al-and Zr-based alloys are attractive candidates for advanced high-strength lightweight materials. Such alloys can be prepared by quenching from the melt or by powder metallurgy using mechanical attrition techniques. This work focuses on mechanically attrited powders and their consolidation into bulk specimens. Selected examples of mechanical deformation behavior are presented, revealing that the properties can be tuned within a wide range of strength and ductility as a function of size and volume fraction of the different phases.

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
• /
• pp.395-396
• /
• 2006

To manufacture a flange for a compressor with a relief groove by using powder metallurgy in order to prevent deformation to the compressor in operation, powder material for the flange is charged into a mold; an ablative member having a melting point lower than that of the powder material is positioned at a place where a relief groove is to be formed; the flange is formed by compressing the powder material and the ablative member; and the formed flange is sintered at a temperature between the melting point of the powder material and the ablative member so as to melt and remove the ablative member. It made according to the new method has more excellent strength and airtight property than the conventional one. It is analyzed that the ablative member is melted and penetrated into the flange structure during the sintering process, which results in improvement of the airtight property and increase of the strength.

• 소성∙가공
• /
• 제10권1호
• /
• pp.30-34
• /
• 2001

The magnetic and metallurgical characteristics of Mischmetal(MM) -Ferroboron (FeB) Permanent magnets have been investigated by X-ray diffractometer, scanning and transmission electron microscope and vibrating sample magnetometer under hot-pressing and die-upsetting process. The best magnetic properties obtained in these studies were $H_c$=5.8 kOe, $B_r$=5.0 kG with $(BH)_{max}=7.6 MGOe for melt-spun ribbons, $H_c$=3.0 kOe, $B_r$=4.6 kG with $(BH)_{max}$=2.9 MGOe for hot-pressed magnets and $H_c$=1.8 kOe, $B_r$=5.5 kG with $(BH)_{max}$=4.1 MGOe for die-upset magnets. The higher magnetic properties in die-upset magnets were resulted from alignment of the c-axis along the die-upsetting direction.

• 한국산업융합학회 논문집
• /
• 제24권2_1호
• /
• pp.79-89
• /
• 2021

Poly(lactic acid) (PLA) is considered as one of the most promising bio-based polymers due to its high strength, high modulus, good processability, transparency after processing, and commercial availability. This study aimed to investigate the mechanical, thermal, and migration properties of poly(lactic acid)/zeolite (10 phr) composites prepared with various biocompatible plasticizers, such as triethyl citrate(TEC), tributyl citrate(TBC), and poly(ethylene glycol)(PEG400), through differential scanning calorimetry(DSC), thermo-gravimetric analysis(TGA) and standard tensile testing. The incorporation of PEG400 significantly increased the elongation at break, and DSC results showed that the addition of plasticizers drastically decreased the T_g of PLA/zeolite composites and improved the melt flow and processability. Besides, it was found from TGA results that PLA/zeolites composites plasticized by TEC and TBC were more easily to be thermally degraded than the composites plasticized by PEG400.

• Journal of Welding and Joining
• /
• 제28권6호
• /
• pp.21-27
• /
• 2010

Due to excellent weld quality, orbital welding with TIG is widely applied to pipe welding. But concave back bead is formed easily in overhead and inclined-up position of butt orbital welding. It is difficult to find a paper to overcome this problem. In this study, in order to make convex back bead in overhead and inclined-up position of pipe 5G welding, control method of molten pool was actively investigated. Melt run welds were conducted on thickness 4.0mm SS400 with overhead and inclined-up position and was observed the variation of bead shape after welding with the bead former developed. The height of back bead showed the trend of increase as the distance from molten pool to the bead former was decreased. Also, there is no trend in the bead width of front and back as welding position was changed or the distance from molten pool to the bead former was decreased.

• 한국주조공학회지
• /
• 제18권4호
• /
• pp.349-356
• /
• 1998

In this study, the influence of impurity element Ca, P on solidification behavior and morphology of eutectic silicon was examined by observation of microstructure and by DSC analysis. In the case of 1.3 ppm P, eutectic Si was fine and fibrous when the added amount of Ca was 500 ppm, However, the modification of eutectic Si was depressed by formation of polygonal Ca-Si compounds when the addition amount of Ca was greater than 1000 ppm. The addition of Ca 500 ppm depressed the primary and eutectic temperature. The primary and eutectic temperature were depressed with Ca 500 ppm but rather ascended when the addition amount of Ca was more than 1000 ppm. When the content of P was 17.5 ppm, eutectic Si had modified morphology with Ca addition. DAS was increased, the primary temperature was ascended and eutectic temperature was depressed with Ca added. Eutectic Si appeared as coarse flake phase and DAS was decreased with the increase of P content. The existence of P in the melt depressed the primary temperature and ascended eutectic temperature.

• 한국주조공학회지
• /
• 제24권5호
• /
• pp.281-289
• /
• 2004

The present study focused on the estimation of the interfacial heat transfer coefficient as a function of the surface temperature of the aluminum casting at the mold/casting interface to investigate the effects of superheat and coating layer. The casting experiments of aluminum into a cylindrical copper mold were systematically conducted to obtain the thermal history during solidification. The thermal history recorded by four thermocouples embedded both in the mold and the casting was used to solve the inverse heat conduction problem using Beck's method. The effects of superheat and coating on the interfacial heat transfer coefficient in the liquid state, during the solidification, and in the solid state were comparatively discussed. In the liquid state, the interfacial heat transfer coefficient is thought to be affected by the roughness of the mold, the wettability of the casting on the mold surface, and the thermophysical properties of the coating layer. When the solidification begins, the air gap forms between the casting and the mold, and the interfacial heat transfer coefficient becomes a function of the air gap as well as surface roughness and the superheat. In the solid phase, it depends only upon the thermal conductivity and the thickness of the air gap. The coating layer reduces seriously the interfacial heat transfer coefficient in the liquid state and during the solidification.

• 한국재료학회지
• /
• 제15권1호
• /
• pp.31-36
• /
• 2005

It is well known that PCB (Printed Circuit Board) is a complex mixture of various metals mixed with various types of plastics and ceramics. In this study, high temperature pyre-metallurgical process was investigated to extract valuable metallic components from the PCB scrap. For this purpose, PCB scrap was shredded and oxidized to remove plastic materials, and then, quantitative analyses were made. After the oxidation of the PCB scrap, $30.6wt\%SiO_2,\;19.3wt\%Al_2O_3\;and\;14wt{\%}CaO$ were analyzed as major oxides, and thereafter, a typical composition of $32wt\%SiO_2-20wt\%Al_2O_3-38wt{\%}CaO-10wt\%MgO$ was chosen as a basic slag system for the separation of metallic components. Moreover a size effect of crushed PCB scrap was also investigated. During experiments a high frequency induction furnace was used to melt and separate metallic components. As a result, it was found that the size of oxidized PCB scrap was needed to be less 0.9 m to make a homogeneous liquid slag and to recycle metallic components over $95\%$.