• Title/Summary/Keyword: mechanical and thermal properties

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Open-Cell Rigid Polyurethane Foam Using Reactive Cell Opening Agents (반응성 기포개방제를 이용한 개방기포형 경질우레탄폼)

  • Ahn, WonSool
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.5
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    • pp.2524-2528
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    • 2013
  • Cell opening characteristics dependent on the cell openers for the conventional formulation of a closed-cell polyurethane foam (PUF) was studied using 1-butanol and lithium salt of 12-hydroxystearic acid (Li-12HSA) as the reactive cell opening agents. While cell openining content of only 10.5 % was obtained for the sample with 4 phr of 1-butanol as the single reactive cell opener, that of 98.0% could be obtained for the sample with 2 phr of Li-12HSA as the reactive co-cell opener. As the results, it showed that a fully open-cell rigid PUF could be obtained by introducing a novel reactive cell opener, having a functional group able to form a bulky side-chain on the urethane networks, without severe loss of mechanical properties of the closed-cell PUF like cell size, bulk density, and thermal conductivity.

A Study on the Property Changes of Rigid Polyurethane Foams by Nucleating Effects of PFA and MWCNT (PFA 및 MWCNT의 기핵효과에 의한 경질 폴리우레탄 폼의 물성 변화에 대한 연구)

  • Ahn, WonSool
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.4
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    • pp.2945-2950
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    • 2015
  • While perfluoroalkane (PFA), a liquid state nucleating agent for a rigid polyurethane foam (RPUF) to enhance the thermal insulation property, has the excellent nucleating characteristics, it is very expensive as well as environmentally harmful due to the fluoride compound. Many researches, therefore, have been performed to develop the alternative nucleating agents to replace PFA. In the present work, a multi-wall carbon nanotube (MWCNT) was used as a sloid state nucleating agent, and thereby the effects on the property changes of the RPUF were carried out. Average cell size decreased from 165.6 for base RPUF to $162.9{\mu}m$ and cell uniformity was also enhanced, showing the standard cell-size deviation of 45.6 and 35.2, respectively. While k-factor of base PUF was $0.01763kcal/m.hr.^{\circ}C$, that of the sample with 0.01 phr MWCNT showed 1.02% reduced value of $0.01745kcal/m.hr.^{\circ}C$. Though the compressive yield stress is nearly the same as $0.030{\times}105Pa$ for the both samples, initial modulus of the sample with 0.01 phr MWCNT was higher than that of base sample. it was considered as the results that small amount of MWCNT could play a sufficient role as the effective nucleating agent for RPUF, showing that an echo-friendly RPUF with reduced-cost could be fabricated, which has an enhanced thermal and mechanical properties.

Effect of Processing Additives on Vulcanization and Properties of EPDM Rubber (EPDM 고무의 첨가제에 따른 가류 및 물성에 미치는 영향 연구)

  • Lee, Soo;Bae, Joung Su
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.1
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    • pp.173-185
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    • 2018
  • Effects of three different types of dispersions and flow improving additives composed with fatty acid esters, fatty acid metal salts and amide compound on the vulcanization and the mechanical properties properties of rubber compounds of EPDM and carbon black as fillers. were investigated using Mooney viscometer, moving die rheometer, hardness tester, and universal test machine. The aging characteristics of vulcanized EPDM compounds were also investigated. The Mooney viscosity measured at $125^{\circ}C$ showed a tendency to decrease in the order of amide type> metal salt type > ester type additive. Scorch time showed little or no difference with the addition of ester or metal salt type additives, but the amide type additive shortened a scorch time more than one minute. Rheological measurement data obtained at $160^{\circ}C$ showed that the vulcanization time was faster for metal salt type and amide type additive systems. Delta torque values of EPDM compound increased with metal salt type and amide type additives, but slightly decreased with ester type additive. The tensile strength of the EPDM compound was greatly improved when an ester type additive was added, but the amide type or metal salt type additive had no significant effect. The elongation was significantly improved for metal salt type additive, while the rest were not significantly affected. The tear strength of the EPDM compounds increased with the addition of all kinds of additives, and it increased remarkably in the case of metal salt type additive. Hardness of the EPDM compounds was nearly same value regardless of additive types. The thermal aging of the EPDM blend at $100^{\circ}C$ for 24 h showed little change in the case of metal salt type or amide type additive, but the elongation tends to decrease by 10-20% for all EPDM compounds containing additives.

Thermal and Mechanical Properties of Rapidly Solidified Zr-Ni-Cu-Al-Ti Alloy (급냉응고법으로 제조한 Zr-Ni-Cu-Al-Ti 합금의 열적, 기계적 성질)

  • Choe, Ik-Seok;Han, Tae-Gyo;Ji, Yong-Gwon;Im, Byeong-Mun;Kim, Yeong-Hwan;Kim, In-Bae
    • Korean Journal of Materials Research
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    • v.11 no.3
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    • pp.171-177
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    • 2001
  • The thermal and mechanical properties of amorphous Z $r_{62-x}$N $i_{10}$C $u_{20}$A $l_{8}$ $Ti_{x}$ (x=3, 6, 9at%) alloys were investigated. The crystallization process was confirmed as amorphous longrightarrow amorphous + Z $r_2$A $l_3$+ Zr + (Ni,Ti) longrightarrow Z $r_2$Cu + Al + (Ni,Ti) for 3at%Ti, amorphous longrightarrow amorphous + Al longrightarrow $Al_2$Ti + NiZr + CuTi for 6at%Ti and amorphous longrightarrow amorphous + Zr + Al longrightarrow Zr + $Al_2$Zr + Al $Ti_3$+ CuTi for 9at%Ti. lickers hardness ( $H_{v}$ ) increased with increasing volume fraction( $V_{f}$ ) of pricipitates for all concerned compositions. Tensile fracture strength ($\sigma_{f}$ ) showed a maximum value 1219MPa at $V_{f}$ = 38% for 3at%Ti, 1203MPa at $V_{f}$ = 2% for 6at%Ti and 1350MPa at $V_{f}$ = 5% for 9at%Ti. The $\sigma_{f}$ was rapidly decreased after showing the maximum value. The $V_{f}$ corresponding to rapidly decreased $\sigma_{f}$ coincided with the $V_{f}$ transited from ductile to brittle fracture surface.ace.

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Chemo-Mechanical Analysis of Bifunctional Linear DGEBA/Linear Amine (DDM, DDS) Resin Casting Systems (DGEBA/방향족 아민(DDM, DDS) 경화제의 벤젠링 사이의 관능기 변화가 물성 변화에 미치는 영향에 대한 연구)

  • 명인호;정인재;이재락
    • Composites Research
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    • v.12 no.4
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    • pp.71-78
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    • 1999
  • To determine the effect of chemical structure of linear amine curing agents on thermal and mechanical properties, standard epoxy resin DGEBA was cured with diaminodiphenyl methane (DDM), diaminodiphenyl sulphone (DDS) in a stoichiometrically equivalent ratio. From this work, the effect of aromatic amine curing agents. In contrast, the results show that the DGEBA/DDS cure system having the sulfone structure between the benzene rings had higher values in the conversion of epoxide, density, shrinkage (%), glass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBA/DDM cure system having methylene structure between the benzene rings, whereas the DGEBA/DDM cure system presented higher values in the maximum exothermic temperature, thermal expansion coefficient, and thermal stability. These results are caused by the relative effects of sulfone group having strong electronegativity and methylene group having (+) repulsive property and stem from the effect of the conversion ratio of epoxide group. The result of fractography shows that the each grain size of the DDM/DGEBA system with feather-like structure is larger than that of the DDS/DGEBA system.

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A Study on the Alumina Ceramic Composite Dispersed With the Zirconia (지르코니아-알루미나 세라믹 복합재료에 관한 연구)

  • Park, Jae-Sung;Lee, Yeong-Sin
    • 전자공학회논문지 IE
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    • v.49 no.2
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    • pp.1-8
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    • 2012
  • The effects of the addition of either monoclinic $ZrO_2(pure)$ or tetragonal $ZrO_2$ containing 5.35wt% $Y_2O_3(Y-TZP)$ on the mechanical properties and thermal shock resistance of $Al_2O_3$ ceramics were investigated. The addition of $ZrO_2$(m) and Y-TZP increased sintered density of $Al_2O_3$. The Vickers hardness also increased as the volume fraction of Y-TZP increased going through a maximum at 20wt%. The hardness of the specimens was found to be dependent on the sintered density. The higher volume fraction of either $ZrO_2(m)$ or Y-TZP resulted in the higher fracture toughness of the composite was. This result may be taken as evidence that toughening of $Al_2O_3$ can be achieved by not only the transformation toughening but microcrack toughening of $ZrO_2$. The thermal shock property for $Al_2O_3-ZrO_2$ composites was improved by increasing the volume fraction of monoclinic $ZrO_2(pure)$. The grain size increased as the volume fraction of $ZrO_2$ did.

Studies of Annealing Effect on the Properties of the Rigid Polyurethane (열처리에 따른 경질 폴리우레탄의 물성 변화 연구)

  • Kang S. J.;Jung H. C.;Kim W. N.;Lee Y. B.;Choe K. H.;Hong S. H.;Kim S. B.
    • Journal of the Korean Institute of Gas
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    • v.2 no.4
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    • pp.18-24
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    • 1998
  • Polyurethane (PU) synthesized from 4,4'-diphenylmethane diisocyanate having high functionality (f=2.9) and polyester polyol have been investigated by differential scanning calorimeter (DSC), dynamic mechanical thermal analyzer (DMTA), and Fourier transform infrared spectroscope (FT-IR). From the DSC measurement of polyurethane, a single transition temperature ($T_g$) was observed. This result indicates that polyurethanes synthesized in this work have homogeneous network structure due to high functionality of diisocyanate. It was also found that the $T_g$ of polyurethane was increased as hard segment content was increased. The results from DMTA measurement are consistent with DSC results. In order to investigate the effect of thermal annealing on the $T_g$ of polyurethane, the samples were annealed at various annealing conditions. $T_gs$ of polyurethanes were found to increased with annealing temperature. From swelling experiment and FT-IR studies, it was found that the $T_g$ was increased as crosslinking density of polyurethane was increased.

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Characteristics of Nylon 6/Poly(acrylonitrile-co-styrene-co-acrylic rubber) Blends Containing Compatibilizer (상용화제가 포함된 나일론 6/Poly(acrylonitrile-co-styrene-co-acrylic rubber) 블렌드의 특성)

  • Kim, Lang-Wook;Yoo, Sun-Hwa;Kim, Chang-Keun
    • Polymer(Korea)
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    • v.31 no.1
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    • pp.8-13
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    • 2007
  • To overcome drawbacks of the nylon 6/poly (acrylonitrile-co-butadiene-co-styrene) (ABS) blend, nylon 6 blend with poly (acrylonitrile - co-styrene - co-acrylic rubber) (ASA) which containing poly (butyl acrylate) as a rubber phase in substitute of poly (butadiene) in ABS, was examined. Poly (styrene-co-maleic anhydride) (SMA) containing 25 wt% of maleic anhydride (MA) or poly (styrene- co-acrylo-nitrile-co-maleic anhydride) (SANMA) containing less than 3 wt% MA was used as a compatibilizer to fabricate blends having high impact strength. Changes in the mechanical properties of nylon 6/ASA blend with compatibilizer content were similar with those of nylon 6/ABS blend. Blends haying high impact strength was produced when blends contained more than about 20 wt% rubber. Blends containing SAM or SANMA as a compatibilizer were stayed in a injection molding machine at the molding temperature and afterwards specimens for the examination of the impact strength was prepared. Impact strength of blends containing SMA was decreased with retention time, while that of blends containing SANMA was not changed with retention time.

Studies on the Physical Properties of Major Tree Barks Grown in Korea -Genus Pinus, Populus and Quercus- (한국산(韓國産) 주요(主要) 수종(樹種) 수피(樹皮)의 이학적(理學的) 성질(性質)에 관(關)한 연구(硏究) -소나무속(屬), 사시나무속(屬), 참나무속(屬)을 중심(中心)으로-)

  • Lee, Hwa Hyoung
    • Journal of Korean Society of Forest Science
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    • v.33 no.1
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    • pp.33-58
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    • 1977
  • A bark comprises about 10 to 20 percents of a typical log by volume, and is generally considered as an unwanted residue rather than a potentially valuable resourses. As the world has been confronted with decreasing forest resources, natural resources pressure dictate that a bark should be a raw material instead of a waste. The utilization of the largely wasted bark of genus Pinus, Quercus, and Populus grown in Korea can be enhanced by learning its physical and mechanical properties. However, the study of tree bark grown in Korea have never been undertaken. In the present paper, an investigative study is carried out on the bark of three genus, eleven species representing not only the major bark trees but major species currently grown in Korea. For each species 20 trees were selected, at Suweon and Kwang-neung areas, on the same basis of the diameter class at the proper harvesting age. One $200cm^2$ segment of bark was obtained from each tree at brest height. Physical properties of bark studied are: bark density, moisture content of green bark (inner-, outer-, and total-bark), fiber saturation point, hysteresis loop, shrinkage, water absorption, specific heat, heat of wetting, thermal conductivity, thermal diffusivity, heat of combustion, and differential thermal analysis. The mechanical properties are studied on bending and compression strength (radial, longitudinal, and tangential). The results may be summarized as follows: 1. The oven-dry specific gravities differ between wood and bark, further more even for a given bark sample, the difference is obersved between inner and outer bark. 2. The oven-dry specific gravity of bark is higher than that of wood. This fact is attributed to the anatomical structure whose characters are manifested by higher content of sieve fiber and sclereids. 3. Except Pinus koraiensis, the oven-dry specific gravity of inner bark is higher than that of outer bark, which results from higher shrinkage of inner bark. 4. The moisture content of bark increases with direct proportion to the composition ratio of sieve components and decreases with higher percent of sclerenchyma and periderm tissues. 5. The possibility of determining fiber saturation point is suggested by the measuring the heat of wetting. With the proposed method, the fiber saturation point of Pinus densiflora lies between 26 and 28%, that of Quercus accutissima ranges from 24 to 28%. These results need be further examined by other methods. 6. Contrary to the behavior of wood, the bark shrinkage is the highest in radial direction and the lowest in longitudinal direction. Quercus serrata and Q. variabilis do not fall in this category. 7. Bark shows the same specific heat as wood, but the heat of wetting of bark is higher than that of wood. In heat conductivity, bark is lower than wood. From the measures of oven-dry specific gravity (${\rho}d$) and moisture fraction specific gravity (${\rho}m$) is devised the following regression equation upon which heat conductivity can be calculated. The calculated heat conductivity of bark is between $0.8{\times}10^{-4}$ and $1.6{\times}10^{-4}cal/cm-sec-deg$. $$K=4.631+11.408{\rho}d+7.628{\rho}m$$ 8. The bark heat diffusivity varies from $8.03{\times}10^{-4}$ to $4.46{\times}10^{-4}cm^2/sec$. From differential thermal analysis, wood shows a higher thermogram than bark under ignition point, but the tendency is reversed above ignition point. 9. The modulus of rupture for static bending strength of bark is proportional to the density of bark which in turn gives the following regression equation. M=243.78X-12.02 The compressive strength of bark is the highest in radial direction, contrary to the behavior of wood, and the compressive strength of longitudinal direction follows the tangential one in decreasing order.

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Comparison of transition temperature range and phase transformation behavior of nickel-titanium wires (니켈-타이타늄 호선의 상전이 온도 범위와 상전이 행동 비교)

  • Lee, Yu-Hyun;Lim, Bum-Soon;Lee, Yong-Keun;Kim, Cheol-We;Baek, Seung-Hak
    • The korean journal of orthodontics
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    • v.40 no.1
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    • pp.40-49
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    • 2010
  • Objective: The aim of this research was to evaluate the mechanical properties (MP) and degree of the phase transformation (PT) of martensitic (M-NiTi), austenitic (A-NiTi) and thermodynamic nickel-titanium wire (T-NiTi). Methods: The samples consisted of $0.016\;{\times}\;0.022$ inch M-NiTi (Nitinol Classic, NC), A-NiTi (Optimalloy, OPTI) and T-NiTi (Neo-Sentalloy, NEO). Differential scanning calorimetry (DSC), three-point bending test, X-ray diffraction (XRD), and microstructure examination were used. Statistical evaluation was undertaken using ANOVA test. Results: In DSC analysis, OPTI and NEO showed two peaks in the heating curves and one peak in the cooling curves. However, NC revealed one single broad and weak peak in the heating and cooling curves. Austenite finishing ($A_f$) temperatures were $19.7^{\circ}C$ for OPTI, $24.6^{\circ}C$ for NEO and $52.4^{\circ}C$ for NC. In the three-point bending test, residual deflection was observed for NC, OPTI and NEO. The load ranges of NC and OPTI were broader and higher than NEO. XRD and microstructure analyses showed that OPTI and NEO had a mixture of martensite and austenite at temperatures below Martensite finishing ($M_f$). NEO and OPTI showed improved MP and PT behavior than NC. Conclusions: The mechanical and thermal behaviors of NiTi wire cannot be completely explained by the expected degree of PT because of complicated martensite variants and independent PT induced by heat and stress.