• 제목/요약/키워드: mechanical activation

검색결과 542건 처리시간 0.026초

Effect of Carbon Black Activation on Physicomechanical Properties of Butadiene-nitrile Rubber

  • Shadrinov, N.V.;Kapitonov, E.A.;Sokolova, M.D.;Okhlopkova, A.A.;Shim, Ee Le;Cho, Jin-Ho
    • Bulletin of the Korean Chemical Society
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    • 제35권10호
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    • pp.2891-2894
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    • 2014
  • The effects of mechanical activation of carbon black on the processing and properties of butadiene nitrile rubber were studied. Mechanical activation of carbon black caused an improvement in the physical and mechanical properties of the butadiene-nitrile rubber, BNR-18AMN. The optimum activation time that would afford rubber with improved properties was established.

Influence of Mechanical Activation on Synthesis of Compounds in B/C-Mg/Al/Ca System

  • Urakaev, F.Kh
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2004년도 SMICS 2004 International Symposium on Maritime and Communication Sciences
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    • pp.60-65
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    • 2004
  • The possibility of mechano-chemical synthesis and influence of mechanical activation on thermal synthesis of borides and boron carbides of mass-low metals is investigated. The opportunity of mechanochemical synthesis in the mill AGO-2 of such compounds as Al $B_2$and Ca $C_2$ $B_2$is established. Influence of mechanical activation in the mill SPEX 8000 on synthesis of such compound as $Mg_{0.5}$A $l_{0.5}$ $B_2$is shown. Features of synthesis in systems containing metal magnesium are considered.d.d.

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Mechanosensitive Modulation of Receptor-Mediated Crossbridge Activation and Cytoskeletal Organization in Airway Smooth Muscle

  • Hai, Chi-Ming
    • Archives of Pharmacal Research
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    • 제23권6호
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    • pp.535-547
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    • 2000
  • Recent findings indicate that mechanical strain (deformation) exerted by the extracellular matrix modulates activation of airway smooth muscle cells. Furthermore, cytoskeletal organization in airway smooth muscle appears to be dynamic, and subject to modulation by receptor activation and mechanical strain. Mechanosensitive modulation of crossbridge activation and cytoskeletal organization may represent intracellular feedback mechanisms that limit the shortening of airway smooth muscle during bronchoconstriction. Recent findings suggest that receptor-mediated signal transduction is the primary target of mechanosensitive modulation. Mechanical strain appears to regulate the number of functional G-proteins and/or phospholipase C enzymes in the cell membrane possibly by membrane trafficking and/or protein translocation. Dense plaques, membrane structures analogous to focal adhesions, appear to be the primary target of cytoskeletal regulation. Mechanical strain and receptor-binding appear to regulate the assembly and phosphorylation of dense plaque proteins in airway smooth muscle cells. Understanding these mechanisms may reveal new pharmacological targets for control1ing airway resistance in airway diseases.

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First-principles study of dissociation processes of O2 molecular on the Al (111) surface

  • Sun, Shiyang;Xu, Pingping;Ren, Yuan;Tan, Xin;Li, Geyang
    • Current Applied Physics
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    • 제18권12호
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    • pp.1528-1533
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    • 2018
  • The trajectories of adsorption and dissociation process of $O_2$ on the Al (111) surface were studied by the spinpolarized ab initio molecular dynamics method, and the adsorption activation energy was clarified by the NEB method with hybrid functionals. Three typical dissociation trajectories were found through simulation of $O_2$ molecule at different initial positions. When vertically approaches to the Al surface, the $O_2$ molecule tends to rotate, and the activation energy is 0.66eV. If $O_2$ molecule does not rotate, the activation energy will increase to 1.43 eV, and it makes the O atom enter the Al sublayer eventually. When the $O_2$ molecules parallel approach to the Al surface, there is no activation energy, due to the huge energy released during the adsorption process.

Imbalance in the spinal serotonergic pathway induces aggravation of mechanical allodynia and microglial activation in carrageenan inflammation

  • Junxiu Jin;Dong Ho Kang;Jin Jeon;Hyung Gon Lee;Woong Mo Kim;Myung Ha Yoon;Jeong Il Choi
    • The Korean Journal of Pain
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    • 제36권1호
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    • pp.51-59
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    • 2023
  • Background: This study investigated the effect of an excess and a deficit of spinal 5-hydroxytryptamine (5-HT) on the mechanical allodynia and neuroglia activation in a rodent pain model of carrageenan inflammation. Methods: Male Sprague-Dawley rats were implanted with an intrathecal (i.t.) catheter to administer the drug. To induce an excess or deficit of 5-HT in the spinal cord, animals were given either three i.t. 5-HT injections at 24-hour intervals or a single i.t. injection of 5,7-dihydroxytryptamine (5,7-DHT) before carrageenan inflammation. Mechanical allodynia was measured using the von Frey test for 0-4 hours (early phase) and 24-28 hours (late phase) after carrageenan injection. The changes in the activation of microglia and astrocyte were examined using immunofluorescence of the dorsal horn of the lumbar spinal cord. Results: Both an excess and a deficit of spinal 5-HT had no or a minimal effect on the intensity of mechanical allodynia during the early phase but prevented the attenuation of mechanical allodynia during the late phase, which was observed in animals not treated with i.t. 5-HT or 5,7-DHT. Animals with an excess or deficit of 5-HT showed stronger activation of microglia, but not astrocyte, during the early and late phases, than did normal animals. Conclusions: Imbalance in the descending 5-HT pathway in the spinal cord could aggravate the mechanical allodynia and enhance the activation of microglia, suggesting that the spinal 5-HT pathway plays an essential role in maintaining the nociceptive processing in balance between facilitation and inhibition in inflammatory pain caused by carrageenan inflammation.

A17075합금의 고온 크리프 활성화에너지의 상태의존성 (State Dependence of Activation Energies for High Temperature Creep of A17075 Alloy)

  • 조용이;김희송
    • 대한기계학회논문집
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    • 제17권1호
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    • pp.131-140
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    • 1993
  • 본 연구에서는 A17075의 활성화에너지의 각 변수 의존성을 온도 보상시간과 Zener-Hollomon 개변수를 써러 조사하고 가장 신빙성이 있는 Miller에 의한 현상론적 크리프식을 조사 연구하였다.

DAEM 분석 방법을 통한 국내 수입탄의 탈휘발화 반응특성 비교연구 (Application of a DAEM Method for a Comparison of Devolatilization Kinetics of Imported Coals)

  • 김량균;송주헌;이병화;장영준;전충환
    • Korean Chemical Engineering Research
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    • 제48권1호
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    • pp.110-115
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    • 2010
  • 본 연구 목적은 두가지 종류의 국내 수입탄에 대한 열분해 반응율을 구하고 이를 비교하는 것이다. 이를 위해 TGA를 통하여 열분해 실험을 수행하였으며, 반응상수 분석은 New DAEM 방법을 이용하였다. 서로 다른 가열속도에서 각각 얻어진 TGA 질량변화 곡선으로부터, 활성화 에너지의 분포함수를 구한 후 최고빈도를 나타내는 활성화 에너지를 평균 활성화 에너지로 결정하였다. 그 결과 석탄의 종류에 따라 상기 반응에 대한 반응속도상수가 확실한 차이를 보였다. 이 같은 New DAEM 분석기법을 통해 얻은 반응상수를 적용시킨 CPD 모델을 가지고 예측한 결과가 TGA 실험치와 비교할 때보다 더 잘 일치함도 확인할 수 있었다.

핵융합로용 저방사화 철강재료(RAFs)의 크리프 특성평가 (Evaluation on Creep properties of Reduced Activation Ferritic Steel(RAFs) for Nuclear Fusion Reactor)

  • 공유식;윤한기;김동현;박이현;남승훈
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2003년도 추계학술대회 논문집
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    • pp.146-151
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    • 2003
  • Reduced Activation Ferritic/Martenstic (RAFs) are leading candidates for structural materials of D-T fusion reactor. One of The RAFs, JLF-1 (9Cr-2W-V, Ta) has been developed and proved to have good resistance against high-fluency neutrino irradiation and good phase stability. Recently, in order to clarify the strengthening mechanical at high temperature, a new scheme to improve high temperature mechanical properties is desired. Therefore, the creep properties and creep life prediction by Larson-Miller Parameter method for JLF-1 to be used for fusion reactor materials or other high temperature components were presented at the elevated temperatures of $500^{\circ}C$, $550^{\circ}C$, $600^{\circ}C$, $650^{\circ}C$ and $704^{\circ}C$. It was confirmed experimentally and quantitatively that a creep life predictive e벼ation at such various high temperatures was well derived by LMP.

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활성탄소섬유의 기공구조가 기계적 특성에 미치는 영향 (Effect of Pore Structure of Activated Carbon Fiber on Mechanical Properties)

  • 최윤정;이영석;임지선
    • 공업화학
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    • 제29권3호
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    • pp.318-324
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    • 2018
  • 본 연구에서는 물리적 활성화법인 수증기 활성화법을 이용하여 PAN (Polyacrylonitrile)계 활성탄소섬유를 제조하였다. 활성화는 온도와 시간을 변수로 하였으며, 활성화 온도(700, 750, $800^{\circ}C$)에 도달하였을 때 200 mL/min의 수증기 유량의 조건으로 PAN 탄소섬유의 활성화를 진행하였다. 제조된 활성탄소섬유의 기공구조를 분석하기 위하여 질소가스의 흡 탈 등온선을 통한 비표면적($S_{BET}$) 측정과 표면분석을 위한 AFM 분석을 실시하였다. 또한 인장시험을 실시하여 활성화 결과 형성된 기공구조가 섬유의 기계적 특성에 미치는 영향을 고찰하였다. 그 결과, 활성화 후 섬유의 비표면적($S_{BET}$)은 $448{\sim}902m^2/g$의 값을 나타냈으며, 인장강도는 58.16~84.92%, 탄성계수는 69.81~83.89%의 감소를 보였다.