• Title/Summary/Keyword: mechanical activation

Search Result 542, Processing Time 0.039 seconds

Effect of Carbon Black Activation on Physicomechanical Properties of Butadiene-nitrile Rubber

  • Shadrinov, N.V.;Kapitonov, E.A.;Sokolova, M.D.;Okhlopkova, A.A.;Shim, Ee Le;Cho, Jin-Ho
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.10
    • /
    • pp.2891-2894
    • /
    • 2014
  • The effects of mechanical activation of carbon black on the processing and properties of butadiene nitrile rubber were studied. Mechanical activation of carbon black caused an improvement in the physical and mechanical properties of the butadiene-nitrile rubber, BNR-18AMN. The optimum activation time that would afford rubber with improved properties was established.

Influence of Mechanical Activation on Synthesis of Compounds in B/C-Mg/Al/Ca System

  • Urakaev, F.Kh
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • 2004.05a
    • /
    • pp.60-65
    • /
    • 2004
  • The possibility of mechano-chemical synthesis and influence of mechanical activation on thermal synthesis of borides and boron carbides of mass-low metals is investigated. The opportunity of mechanochemical synthesis in the mill AGO-2 of such compounds as Al $B_2$and Ca $C_2$ $B_2$is established. Influence of mechanical activation in the mill SPEX 8000 on synthesis of such compound as $Mg_{0.5}$A $l_{0.5}$ $B_2$is shown. Features of synthesis in systems containing metal magnesium are considered.d.d.

  • PDF

Mechanosensitive Modulation of Receptor-Mediated Crossbridge Activation and Cytoskeletal Organization in Airway Smooth Muscle

  • Hai, Chi-Ming
    • Archives of Pharmacal Research
    • /
    • v.23 no.6
    • /
    • pp.535-547
    • /
    • 2000
  • Recent findings indicate that mechanical strain (deformation) exerted by the extracellular matrix modulates activation of airway smooth muscle cells. Furthermore, cytoskeletal organization in airway smooth muscle appears to be dynamic, and subject to modulation by receptor activation and mechanical strain. Mechanosensitive modulation of crossbridge activation and cytoskeletal organization may represent intracellular feedback mechanisms that limit the shortening of airway smooth muscle during bronchoconstriction. Recent findings suggest that receptor-mediated signal transduction is the primary target of mechanosensitive modulation. Mechanical strain appears to regulate the number of functional G-proteins and/or phospholipase C enzymes in the cell membrane possibly by membrane trafficking and/or protein translocation. Dense plaques, membrane structures analogous to focal adhesions, appear to be the primary target of cytoskeletal regulation. Mechanical strain and receptor-binding appear to regulate the assembly and phosphorylation of dense plaque proteins in airway smooth muscle cells. Understanding these mechanisms may reveal new pharmacological targets for control1ing airway resistance in airway diseases.

  • PDF

First-principles study of dissociation processes of O2 molecular on the Al (111) surface

  • Sun, Shiyang;Xu, Pingping;Ren, Yuan;Tan, Xin;Li, Geyang
    • Current Applied Physics
    • /
    • v.18 no.12
    • /
    • pp.1528-1533
    • /
    • 2018
  • The trajectories of adsorption and dissociation process of $O_2$ on the Al (111) surface were studied by the spinpolarized ab initio molecular dynamics method, and the adsorption activation energy was clarified by the NEB method with hybrid functionals. Three typical dissociation trajectories were found through simulation of $O_2$ molecule at different initial positions. When vertically approaches to the Al surface, the $O_2$ molecule tends to rotate, and the activation energy is 0.66eV. If $O_2$ molecule does not rotate, the activation energy will increase to 1.43 eV, and it makes the O atom enter the Al sublayer eventually. When the $O_2$ molecules parallel approach to the Al surface, there is no activation energy, due to the huge energy released during the adsorption process.

Imbalance in the spinal serotonergic pathway induces aggravation of mechanical allodynia and microglial activation in carrageenan inflammation

  • Junxiu Jin;Dong Ho Kang;Jin Jeon;Hyung Gon Lee;Woong Mo Kim;Myung Ha Yoon;Jeong Il Choi
    • The Korean Journal of Pain
    • /
    • v.36 no.1
    • /
    • pp.51-59
    • /
    • 2023
  • Background: This study investigated the effect of an excess and a deficit of spinal 5-hydroxytryptamine (5-HT) on the mechanical allodynia and neuroglia activation in a rodent pain model of carrageenan inflammation. Methods: Male Sprague-Dawley rats were implanted with an intrathecal (i.t.) catheter to administer the drug. To induce an excess or deficit of 5-HT in the spinal cord, animals were given either three i.t. 5-HT injections at 24-hour intervals or a single i.t. injection of 5,7-dihydroxytryptamine (5,7-DHT) before carrageenan inflammation. Mechanical allodynia was measured using the von Frey test for 0-4 hours (early phase) and 24-28 hours (late phase) after carrageenan injection. The changes in the activation of microglia and astrocyte were examined using immunofluorescence of the dorsal horn of the lumbar spinal cord. Results: Both an excess and a deficit of spinal 5-HT had no or a minimal effect on the intensity of mechanical allodynia during the early phase but prevented the attenuation of mechanical allodynia during the late phase, which was observed in animals not treated with i.t. 5-HT or 5,7-DHT. Animals with an excess or deficit of 5-HT showed stronger activation of microglia, but not astrocyte, during the early and late phases, than did normal animals. Conclusions: Imbalance in the descending 5-HT pathway in the spinal cord could aggravate the mechanical allodynia and enhance the activation of microglia, suggesting that the spinal 5-HT pathway plays an essential role in maintaining the nociceptive processing in balance between facilitation and inhibition in inflammatory pain caused by carrageenan inflammation.

State Dependence of Activation Energies for High Temperature Creep of A17075 Alloy (A17075합금의 고온 크리프 활성화에너지의 상태의존성)

  • 조용이;김희송
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.17 no.1
    • /
    • pp.131-140
    • /
    • 1993
  • The activation energy for high temperature creep is associated with stresses, temperatures, straians And the creep strain appears to be a function of a temperature, compensated time, namely $te^{-}$.DELTA.H/RT/, and the stress. In fact this functional relation appears to be isomorphic to material structure by x-ray analyses. Applying this functional relation, the dependance of activation energy for A17075 creep was investigated. The activation energy for creep is insensitive to stress, temperature, structure, and strain. And phenomenological model agrees with experimental creep data.

Application of a DAEM Method for a Comparison of Devolatilization Kinetics of Imported Coals (DAEM 분석 방법을 통한 국내 수입탄의 탈휘발화 반응특성 비교연구)

  • Kim, Ryang Gyoon;Song, Ju Hun;Lee, Byoung Hwa;Chang, Young June;Jeon, Chung Hwan
    • Korean Chemical Engineering Research
    • /
    • v.48 no.1
    • /
    • pp.110-115
    • /
    • 2010
  • The experiment was designed to compare pyrolysis kinetics of two different classes of imported coal. The pyrolysis behaviors of the coals were first observed with thermogravimetric analyzer(TGA). The kinetic analysis was further done based on a new distributed activation energy model(New DAEM). During the analysis, weight loss curves measured at three different heating rates were used to obtain the activation energy distribution function curve f(E) of a given coal sample where a mean activation energy is determined by its peak. The results show a significant difference in the mean activation energy between two coals for the pyrolytic reaction. The prediction of a chemical percolation devolatilization(CPD) model where the kinetics obtained from the New DAEM method were incorporated is in much closer agreement with an experimental data of TGA particularly for the bituminous coal.

Evaluation on Creep properties of Reduced Activation Ferritic Steel(RAFs) for Nuclear Fusion Reactor (핵융합로용 저방사화 철강재료(RAFs)의 크리프 특성평가)

  • Kong, Yu-Sik;Yoon, Han-Ki;Kim, Dong-Hyen;Park, Yi-Hyen;Nahm, Seung-Hoon
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
    • /
    • 2003.10a
    • /
    • pp.146-151
    • /
    • 2003
  • Reduced Activation Ferritic/Martenstic (RAFs) are leading candidates for structural materials of D-T fusion reactor. One of The RAFs, JLF-1 (9Cr-2W-V, Ta) has been developed and proved to have good resistance against high-fluency neutrino irradiation and good phase stability. Recently, in order to clarify the strengthening mechanical at high temperature, a new scheme to improve high temperature mechanical properties is desired. Therefore, the creep properties and creep life prediction by Larson-Miller Parameter method for JLF-1 to be used for fusion reactor materials or other high temperature components were presented at the elevated temperatures of $500^{\circ}C$, $550^{\circ}C$, $600^{\circ}C$, $650^{\circ}C$ and $704^{\circ}C$. It was confirmed experimentally and quantitatively that a creep life predictive e벼ation at such various high temperatures was well derived by LMP.

  • PDF

Effect of Pore Structure of Activated Carbon Fiber on Mechanical Properties (활성탄소섬유의 기공구조가 기계적 특성에 미치는 영향)

  • Choi, Yun Jeong;Lee, Young-Seak;Im, Ji Sun
    • Applied Chemistry for Engineering
    • /
    • v.29 no.3
    • /
    • pp.318-324
    • /
    • 2018
  • In this study, PAN (polyacrylonitrile) based activated carbon fibers were prepared by water vapor activation method which is a physical activation method. Activation was performed with temperature and time as parameters. When the activation temperature reached 700, 750 and $800^{\circ}C$, the activation was carried out under the condition of a water vapor flow rate of 200 ml/min. In order to analyze the pore structure of activated carbon fibers, the specific surface area ($S_{BET}$) was measured by the adsorption/desorption isotherm of nitrogen gas and AFM analysis was performed for the surface analysis. Tensile tests were also conducted to investigate the effect of the pore structure on mechanical properties of fibers. As a result, the $S_{BET}$ of fibers after the activation showed a value of $448{\sim}902m^2/g$, the tensile strength decreased 58.16~84.92% and the tensile modulus decreased to 69.81~83.89%.