• 제목/요약/키워드: measurement of permeability

검색결과 257건 처리시간 0.024초

A Study on the Properties of Silk and Nylon 6 Fabrics by Tannic Acid Treatment

  • Yoa, Soojin;Kim, Jongjun
    • 패션비즈니스
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    • 제20권3호
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    • pp.119-132
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    • 2016
  • Weighting of silk fabrics have long been practiced in silk fabric trading based on the primary consideration of price-weight, and secondary one of quality improvement in handle, luster, and drape properties. Recent trend of practicing weighting of silk fabrics is, however, focused on the improvement of the handle, luster, drape, and other properties. During the finishing processes of synthetic fiber, nylon, comprising amide structure, include the use of tannic acid, especially in the dyeing. A multitude of studies are being implemented in terms of improving fastness to washing, fastness to light of dyed nylon product, or the light fastness of nylon 6 itself. In this study, the effects of various tannic acid treatments on the physical properties related to the handle of nylon 6 and silk fabrics are examined and reviewed. The effects of treatment condition of the tannic acid, e.g., the concentration of the aqueous tannic acid solution, treatment time, and temperature were investigated. As the concentration of the aqueous solution of tannic acid increased, the bending rigidity values of the silk and nylon 6 fabrics increased. The treated fabrics felt stiff to the touch. Within the mild conditions of bending employed in the bending measurement of KES, nylon 6 treated fabric specimen exhibited a trend of improvement of bending resiliency within the range of small bending deformation. The weight of treated fabrics have all increased. The air-permeability values decreased as the treatment concentration increased. However, the decrease tendency of air permeability values may be alleviated by adjusting the fabric count during the tentering or expanding processes, either by tension adjustment or heat treatment. Optimum conditions of the treatment for nylon 6 are 1.25% tannic acid concentration, bath temperature of $85^{\circ}C$, pH 3.1, and those for silk fabric treatment are 1.25% tannic acid concentration, bath temperature of $85^{\circ}C$, pH 3.1. The treatment conditions will lead to the improvement in the properties of fabrics for summer.

통현이팔단 에탄올 추출물의 Methicillin Resistant Staphylococcus aureus에 대한 항균활성 (Antibacterial activity of Tonghyeonipal-dan against Methicillin-resistant Staphylococcus aureus)

  • 김인원;강옥화;공룡;권동렬
    • 대한본초학회지
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    • 제30권5호
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    • pp.15-21
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    • 2015
  • Objectives : Methicillin-resistantStaphylococcus aureus(MRSA) is a human pathogen. New antibacterial agents are needed to treat MRSA-related infections. This study investigated the antibacterial activity of EtOH 70% extracts ofTonghyeonipal-dan(THD) which prescription is composed of oriental medicine against MRSA.Methods : The antibacterial activity of THD was evaluated against MRSA strains by using the Disc diffusion method, broth microdilution method, Checkerboard dilution test, and Time-kill test; its mechanism of action was investigated by bacteriolysis, detergent or ATPase inhibitors were used.Results : The minimum inhibitory concentration (MIC) of THD is 1,000~2,000 μg/mL against MRSA. In the checkerboard dilution test, fractional inhibitory concentration index (FICI) of THD in combination with antibiotics indicated synergy or partial synergism againstS. aureus. Furthermore, a time-kill assay showed that the growth of the tasted bacteria was considerably inhibited after 24 h of treatment with the combination of THD with selected antibiotics. For measurement of cell membrane permeability, THD 500 μg/mL along with concentration of Triton X-100 (TX) and Tris-(hydroxymethyl) aminomethane (TRIS) were used. In the other hand, N,N-dicyclohexylcarbodimide (DCCD) and Sodium azide (NaN3) were used as an inhibitor of ATPase. TX, TRIS, DCCD and NaN3 cooperation againstS. aureusshowed synergistic action.Conclusions : Accordingly, antimicrobial activity of THD was affected by cell membrane and inhibitor of ATPase were assessed. These results suggest that THD has antibacterial activity, and that THD extract offers great potential as a natural antibiotic against MRSA.

열분해성 그룹이 도입된 폴리이미드로부터 유도된 탄소분자체막의 수소 분리 특성 (Hydrogen Separation of Carbon Molecular Sieve Membranes Derived from Polyimides Having Decomposable Side Groups)

  • Young Moo Lee;Youn Kook Kim;Ji Min Lee;Ho Bum Park
    • 멤브레인
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    • 제14권2호
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    • pp.99-107
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    • 2004
  • Carbon molecular sieve (CMS) membranes were prepared by pyrolysis of polyimides having carboxylic acid groups and applied to the hydrogen separation. The polymeric membranes having carboxylic acid groups showed different steric properties as compared with polymeric membranes having other side groups ($-CH_3$ and $-CF_3$) because of the hydrogen bond between the carboxylic acid groups. However, the microporous CMS membranes were significantly affected by the decomposable side groups evidenced from the wide angle X-rat diffraction, nitrogen adsorption isotherms, and single gas permeation measurement. Furthermore, the gas separation properties of the CMS membranes were essentially affected by the pyrolysis temperature. As a result, the CMS membranes Prepared by Pyrolysis of polyimide containing carboxylic acid froups at $700^{\circ}C$ showed the $H_2$ permeability of 3,809 Baller [$1{\times}10^{-10}$ H $\textrm{cm}^$(STP)cm/$\textrm{cm}^2$.s.cmHg], $H_2$/$N_2$, selectivity of 46 and $H_2$/$CH_4$ selectivity of 130 while the CMS membranes derived from polyimide showed the H$_2$ permeability of 3,272 Barrer, $H_2$/$N_2$ selectivity of 136 and $H_2$/$CH_4$ selectivity of 177.

In-situ modification of PVC UF membrane by SiO2 sol in the coagulation bath during NIPS process

  • Cheng, Liang;Xu, Zhen-Liang;Yang, Hu;Wei, Yong-Min
    • Membrane and Water Treatment
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    • 제9권5호
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    • pp.317-325
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    • 2018
  • Polyvinyl chloride (PVC) ultrafiltration (UF) membrane was modified by silica sol in the coagulation bath during non-solvent induced phase separation (NIPS) process. The effects of silica sol concentrations on the morphology, surface property, mechanical strength and separation property of PVC UF membranes were systematically investigated. PVC membranes were characterized by Fourier transform infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM), contact angle goniometry and tensile strength measurement. The results showed that silica had been successfully assembled on the surface of PVC UF membrane. With the increase of silica sol concentration in the coagulation bath, the morphologies of PVC UF membranes changed from cavity structure to finger-like pore structure and asymmetric cross-section structure. The hydrophilicity and permeability of PVC UF membranes were further evaluated. When silica sol concentration was 20 wt.%, the modified PVC membrane exhibited the highest hydrophilicity with a static contact angle of $36.5^{\circ}$ and permeability of $91.8(L{\cdot}m^{-2}{\cdot}h^{-1})$. The structure of self-assemble silica had significant impact on the surface property, morphology, mechanical strength and resultant separation performance of the PVC membranes.

PCC(Powder Compacted Capsule) 크기 및 혼입율에 따른 자기치유 모르타르의 공학적 특성에 관한 실험적 연구 (An Experimental Study on Engineering Properties of Self-healing Mortar according to PCC(Powder Compacted Capsule) Size and Mixing Ratio)

  • 이재인;김채영;최세진
    • 한국건설순환자원학회논문집
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    • 제10권4호
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    • pp.514-522
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    • 2022
  • 본 연구에서는 시멘트 복합체에 시멘트계 재료로 구성된 자기치유 캡슐을 적용하여 콘크리트 구조물의 자기치유 성능을 향상시키기 위한 연구의 일환으로 PCC(Powder Compacted Capsule) 크기 및 혼입율에 따른 모르타르의 공학적 특성을 비교ㆍ분석하였다. 이를 위해 PCC 크기 및 혼입율에 따른 모르타르의 유동성, 압축강도, 하중재부하 시험, 탄산화, 초음파속도, 투수 특성 등을 측정하였다. 측정 결과, PCC의 혼입율이 증가할수록 유동성과 압축강도가 증가하였으며, 치유특성 검토를 위해 진행한 하중재부하 시험의 경우 03PC 배합에서 PCC 혼입율이 증가할수록 치유율이 증가하였다. 정수위투수 시험의 경우 PCC를 사용할 경우 유출수량 감소율이 Plain 배합에 비해 최대 35 % 높은것으로 나타났으며, 크기 0.3~0.6 mm의 PCC를 15 % 혼입할 시 모르타르의 균열 치유율 향상에 효과적인 것으로 나타났다.

답전윤환 인삼재배 예정지 토양의 물 이동특성 평가 (Assessment on Water Movement in Paddy-Upland Rotation Soil Scheduled for Ginseng Cultivation)

  • 허승오;이윤정;연병열;전상호;하상건;김정규
    • 한국약용작물학회지
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    • 제17권3호
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    • pp.204-209
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    • 2009
  • This study was conducted to assess water movement in paddy-upland rotation soil scheduled for ginseng cultivation through the measurement of infiltration and permeability of soil water. Soil sample was divided with four soil layers. The first soil layer (to 30cm from top soil) was loamy sand, the second and the third soil layers (30$\sim$70 ㎝) were sand, and the fourth (< 120 ㎝) was sandy loam. The soil below 130 ㎝ of fourth soil layer was submerged under water. The shear strength, which represents the resisting power of soil against external force, was 3.1 kPa in the first soil layer. This corresponded to 1/8 of those of another soil layer and this value could result in soil erosion by small amount of rainfall. The rates of infiltration and permeability depending on soil layers were 39.86 cm $hr^{-1}$ in top soil, 2.34 cm $hr^{-1}$ in 30$\sim$70 ㎝ soil layer, 5.23 cm $hr^{-1}$ and 0.18 cm $hr^{-1}$ in 70$\sim$120 ㎝ soil layer, with drain tile, and without drain tile, respectively. We consider that ground water pooled in paddy soil and artificial formation of soil layer could interrupt water canal within soil and affect negatively on water movement. Therefore, we suggest that to drain at 5 m intervals be preferable when it makes soil dressing or soil accumulation to cultivate ginseng in paddy-upland rotation soil to reduce failure risk of ginseng cultivation.

Experimental and numerical investigation of closure time during artificial ground freezing with vertical flow

  • Jin, Hyunwoo;Go, Gyu-Hyun;Ryu, Byung Hyun;Lee, Jangguen
    • Geomechanics and Engineering
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    • 제27권5호
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    • pp.433-445
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    • 2021
  • Artificial ground freezing (AGF) is a commonly used geotechnical support technique that can be applied in any soil type and has low environmental impact. Experimental and numerical investigations have been conducted to optimize AGF for application in diverse scenarios. Precise simulation of groundwater flow is crucial to improving the reliability these investigations' results. Previous experimental research has mostly considered horizontal seepage flow, which does not allow accurate calculation of the groundwater flow velocity due to spatial variation of the piezometric head. This study adopted vertical seepage flow-which can maintain a constant cross-sectional area-to eliminate the limitations of using horizontal seepage flow. The closure time is a measure of the time taken for an impermeable layer to begin to form, this being the time for a frozen soil-ice wall to start forming adjacent to the freeze pipes; this is of great importance to applied AGF. This study reports verification of the reliability of our experimental apparatus and measurement system using only water, because temperature data could be measured while freezing was observed visually. Subsequent experimental AFG tests with saturated sandy soil were also performed. From the experimental results, a method of estimating closure time is proposed using the inflection point in the thermal conductivity difference between pore water and pore ice. It is expected that this estimation method will be highly applicable in the field. A further parametric study assessed factors influencing the closure time using a two-dimensional coupled thermo-hydraulic numerical analysis model that can simulate the AGF of saturated sandy soil considering groundwater flow. It shows that the closure time is affected by factors such as hydraulic gradient, unfrozen permeability, particle thermal conductivity, and freezing temperature. Among these factors, changes in the unfrozen permeability and particle thermal conductivity have less effect on the formation of frozen soil-ice walls when the freezing temperature is sufficiently low.

소입경 골재를 이용한 중온 저소음 아스팔트 포장의 적용 연구 (A Study on Application of Warm-Mix Quiet Pavement Using Fine-Size Aggregate)

  • 조신행;백유진;김낙석
    • 한국재난정보학회 논문집
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    • 제9권1호
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    • pp.56-64
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    • 2013
  • 본 연구에서는 소입경 골재와 중온 기술을 사용한 저소음 포장의 현장 적용성 검토를 수행하였다. 배합설계 및 실내실험 수행결과, 소입경 골재를 사용하면 골재간의 맞물림 면적이 증가하여 비산저항성이 향상되는 것으로 나타났다. 고점도 아스팔트 바인더를 사용하는 저소음 아스팔트 포장은 선회다짐기를 통한 다짐온도 결정이 적합하였으며, 중온 첨가제 사용시 약 $15^{\circ}C$의 다짐온도 저감효과를 얻을 수 있었다. 시험 시공 후 현장투수시험과 소음측정을 하였으며 현장투수시험을 통해 저소음 포장이 충분한 공극을 확보하였음을 확인하였다. 소음측정결과 10mm 소입경 저소음 포장의 소음감소효과가 가장 뛰어난 것으로 나타났으며 공극률이 다소 작게 확보된 10mm 중온 소입경 저소음 포장도 13mm 저소음 포장에 비해 높은 소음감소효과가 나타나 소입경 골재의 사용이 저소음 포장의 소음감소에 효과적이었으며, 특히 저속에서의 소음감소효과가 뛰어났다.

NATM 터널의 배수시스템 수리기능저하가 터널 라이닝에 미치는 영향 (An Experimental Study on the Effect of Malfunctioning of Drainage System on NATM Tunnel Linings)

  • 신종호;권오엽;신용석;양유홍
    • 한국지반공학회논문집
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    • 제23권6호
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    • pp.77-84
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    • 2007
  • 유입량과 라이닝에 작용하는 간극수압은 터널 설계시 고려해야 할 중요한 요소 중 하나이다. 간극수압의 발생은 누수를 가속화시키며 라이닝 열화를 초래한다. 본 논문에서는 모형실험을 통하여 배수시스템 기능저하로 인한 간극수압의 발생과 그 영향을 조사하였다. 배수시스템 기능저하거동은 배수재의 투수계수제어법과 유량 조절법으로 모사화 하여 터널 라이닝의 잔류수압발생 메카니즘을 확인하였다. 또한, 유량제어법이 배수시스템 기능저하현상을 모사하기에 보다 더 효과적인 방법임을 알 수 있었다. 모형실험을 수치해석으로 재현한 결과, 배수시스템 기능저하로 인한 영향을 Coupled 수치 모델링을 통해 이론적으로 예측 가능함을 확인할 수 있었다.

플라즈마 처리된 폴리이미드 막의 기체투과특성 (Effect of Plasma Treatment on Permeability and Selectivity Characteristics of Mixture Gas through Polyimide Membrane)

  • 배성렬;노상호;류대선;박희진
    • 멤브레인
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    • 제11권1호
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    • pp.38-49
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    • 2001
  • 우수한 열적, 화학적, 기계적 성질을 가진 폴리이미드 막의 표면을 Ar, $NH_3$ 플라즈마로 처리한 후 혼합기체$(CO_2/N_2=20/80 vol%)$의 투과 실험을 통하여 플라즈마 처리 조건이 기체 투과도와 분리성능에 어떠한 영향을 미치는지를 조사하였다. 투과실험은 $30^{\circ}$C, 5atm에서 variable volume method에 의해 행하여졌다. 표면개질된 폴리이미드 막의 투과거동에 대해 처리시간, 출력세기, 가스주입 유량 및 반응기 내의 압력과 같은 플라즈마 처리 조건의 영향을 조사하였다. 플라즈마 처리된 막의 표면은 FTIR-ATR, ESCA, AFM으로 분석하여 처리전후의 변화를 관찰하였다. 또한 플라즈마 처리시간에 따른 etching 효과와 흡수성은 weight loss와 contact angle를 측정하여 조사하였다. 그리고 투과 실험에 있어서 반응 온도의 변화에 따른 영향도 함께 연구되었으며, saturator를 이용한 dry 상태와 wet 상태에서 혼합가스에 대한 폴리이미드 막의 기체투과특성에 대한 실험 역시 수행되었다.

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