• Transactions of the Korean Society of Automotive Engineers
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• v.25 no.3
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• pp.380-388
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• 2017

Wood pyrolysis oil(WPO) has been regarded as an alternative fuel for diesel engines. However, WPO is not feasible for use directly in diesel engines due to its poor fuel quality such as low energy density, high acidity, high viscosity and low cetane number. The most widely used approach to improve WPO fuel quality is to blend WPO with other hydrocarbon fuels that have a higher cetane number. However, WPO and fossil fuels are not usually blended because of their different polarity. Also, clogging and polymerization problems in the fuel supply system can occur when the engine is operated with WPO. Polymerization can be prevented by diluting WPO with other alcohol fuels. However, WPO-alcohol blended fuel does not produce self-ignition. Therefore, additional cetane enhancement to the blended fuel is required to enhance auto-ignitability. In this study, WPO was blended with n-butanol and two cetane enhancements(PEG 400 and 2-EHN) for application to a diesel generator. Experimental results showed that the WPO-butanol blended fuel achieved a very stable engine operation under maximum WPO content of 20 wt%.

• Environmental Engineering Research
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• v.22 no.1
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• pp.19-30
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• 2017

Direct catalysis of vapors from vacuum pyrolysis of biomass was performed on MCM-41 to investigate the effects of operating parameters including catalyzing temperature, catalyzing bed height and system pressure on the organic yields. Optimization of organic phase yield was further conducted by employing response surface methodology. The statistical analysis showed that operating parameters have significant effects on the organic phase yield. The organic phase yield first increases and then decreases as catalyzing temperature and catalyzing bed height increase, and decreases as system pressure increases. The optimal conditions for the maximum organic phase yield were obtained at catalyzing temperature of $502.7^{\circ}C$, catalyzing bed height of 2.74 cm and system pressure of 6.83 kPa, the organic phase yield amounts to 15.84% which is quite close to the predicted value 16.19%. The H/C, O/C molar ratios (dry basis), density, pH value, kinematic viscosity and high heat value of the organic phase obtained at optimal conditions were 1.287, 0.174, $0.98g/cm^3$, 5.12, $5.87mm^2/s$ and 33.08 MJ/kg, respectively. Organic product compositions were examined using gas chromatography/mass spectrometry and the analysis showed that the content of oxygenated aromatics in organic phase had decreased and hydrocarbons had increased, and the hydrocarbons in organic phase were mainly aliphatic hydrocarbons. Besides, thermo-gravimetric analysis of the MCM-41 zeolite was conducted within air atmosphere and the results showed that when the catalyst continuously works over 100 min, the index of physicochemical properties of bio-oil decreases gradually from 1.15 to 0.45, suggesting that the refined bio-oil significantly deteriorates. Meanwhile, the coke deposition of catalyst increases from 4.97% to 14.81%, which suggests that the catalytic activity significantly decreases till the catalyst completely looses its activity.

• Journal of Korean Ophthalmic Optics Society
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• v.4 no.1
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• pp.45-49
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• 1999

To prepare high-transmittance films, thin films were fabricated on the microscope slide glasses with silicon alkoxides and boric acids as starting materials by using a dip-coating technique. Thicknesses of the thin films were controled as viscosity of the sol used and composition of the $B_2O_3$ was changed at 5, 10, 15 and 20 mol%. Transmittance at visible range and IR transmittance of the films according to the composition were measured, and refractive index of the films were analyzed also. Maximum transmittance at visible range and minimum refractive index were obtained at 15 mol% $B_2O_3$. We will discuss a decrease of the transmittance at 20 mol% on the basis of the refractive index.

• Journal of Microbiology and Biotechnology
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• v.19 no.7
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• pp.713-717
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• 2009

The dependence of the catalytic properties of horseradish peroxidase on the structural changes of ionic liquids was investigated with two water-miscible ionic liquids, N-butyl-3methypyridinium tetraftuoroborate ([$BMP_y$][$BF_4$]) and 1-butyl-3-methylimidazolium methylsulfate ([BMIM][$MeSO_4$]), each of which shares an anion ($BF_4^-$) or a cation ($BMIM^+$) with 1-butyl-3-methylimidazolium tetraftuoroborate ([BMIM][$BF_4$]), respectively. The oxidation of guaiacol (2-methoxyphenol) with $H_2O_2$was used as a model reaction. In order to minimize the effect of solution viscosity on the kinetic constants of the enzymatic catalysis, the enzymatic reactions for the kinetic study were performed in water-ionic liquid mixtures containing 25% (v/v) ionic liquid at maximum. Similarly to the previously reported results for [BMIM][$BF_4$], as the concentration of [$BMP_y$][$BF_4$] increased, the $K_m$value increased with a decrease in the $k_{cat}$value: the $K_m$value increased markedly from 2.8 mM in 100% water to 12.6 mM in 25% (v/v) ionic liquid, indicating that ionic liquid significantly weakens the binding affinity of guaiacol to the enzyme. On the contrary, [BMIM][$MeSO_4$] decreased the Km value to 1.4 mM in 25% (v/v) ionic liquid. [BMIM][$MeSO_4$] also decreased $k_{cat}$more than 3-folds [from 13.8 $s^{-1}$in 100% water to 4.1 $s^{-1}$in 25% (v/v) ionic liquid]. These results indicate that the ionic liquids interact with the enzyme at the molecular level as well as at a macroscopic thermodynamic scale. Specifically, the anionic component of the ionic liquids influenced the catalysis of horseradish peroxidase in different ways.

• Journal of the Korean Magnetics Society
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• v.4 no.3
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• pp.219-225
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• 1994

The alignment of Sr-ferrite magnetic powders, which is usually related to the fluidity and the applied magnetic field, is investicated in the anisotropic Sr-ferrite / resin-bonded permanent magnets. The magnetic powder alignment is observed to increase with the applied magnetic field and the fluidity which is a function of molding temperature and powder packing ratio. The best magnetic powder alignment is achieved at the following conditions; Sr-ferrite packing ratio of 56vol%, apparent viscosity of about 3000 poise in $1000sec^{-1}$ shear rate, and applied magnetic field of about 5kOe. The degree of preferred orientation of the magnetic powders in the field direction, as determined by the dc hysterisis graphs, is 84~85% (0.84~0.85). This result is in agreement with the value of 0.85 obtained by the X-ray experiments in the $2{\theta}$ range of ${23~40}^0$. The best magnetic properties obtained are:2.2kG of remanent flux density, 2.2MGOe of maximum energy product.

• Journal of Ocean Engineering and Technology
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• v.22 no.4
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• pp.8-13
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• 2008

In this study, an investigation of shear wave ultrasonic technique was carried out to detect stacking orientation error for CF/Epoxy quasi-isotropy composite laminates. The ultrasonic shear wave is particularly sensitive to ply orientation and layup sequence in tire CF/Epoxy composite laminates. In the manufacturing of composite laminates, it is important that layup errors be detected in samples. In this work, an effect was mack to develop shear wave techniques that can be applied to composite laminates. During testing, the mast significant problem is that the couplant conditions do not remain the same because of its changing viscosity. The design and use of a shear ware transducer would greatly alleviate the couplant problem. A pyramid of aluminum, with isosceles triangle (two 45o angles) sides, was made to generate shear waves, using two longitudinal transducers based on an ultrasonic-polarized mechanism. A signal splitter was connected to the pulser jack on a pulser/receiver and to the longitudinal transducers. The longitudinal transducers were mounted with mineral oil, and the shear transducer was mounted with burnt honey on the bottom as a receiver. The shear wave was generated at a maximum and a minimum based on the ultrasonic-polarized mechanism. Results show it is feasible to measure layup error using shear wave transducers on a stacking of prepregs in composites.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.7
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• pp.599-607
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• 2015

In this study, we theoretically investigate the thermal performances of heat pipes that have different nano-fluid properties. Two different types of nano-particles have been used: $Al_2O_3$ and CuO. The thermal performances of the heat pipes are observed for varying nano-particle aggregations and volume fractions. Both the viscosity and the conductivity increase as the volume fraction and the aggregation increase, respectively. Increasing the volume fraction helps increase the capillary limit in the well-dispersed condition. Whereas, the capillary limit is decreased under the aggregate condition, when the volume fraction increases. The dependence of the heat pipe thermal resistance on the volume fraction, aggregation, and conductivity of the nano-particles is analyzed. The maximum thermal transfer of the heat pipe is highly dependent on the volume fraction because of the high permeability of the heat pipe. For the proposed heat pipe, the optimum volume fraction of the nano-particle can be seen through 3D graphics.

• Korean Journal of Food Science and Technology
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• v.28 no.4
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• pp.644-649
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• 1996

The purpose of this study was to investigate the relationship between physicochemical properties and optimum amount of added water for cooking in the preparation of Korean cooked rice (bab). Seven different kinds of rice samples were tested for their chemical and physical properties in relation to the eating quality after cooking with various amounts of water added. The amylose content and water content of rice did not show significant correlation with the amount of added water for optimum cooking. The width of rice kernel, expansion ratio, amylogram maximum viscosity showed significant correlation with the optimum ratio of added water for cooking.

• KSBB Journal
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• v.8 no.2
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• pp.164-171
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• 1993

The production of extracellular polysaccharide by Methylomonas mucosa (NRRL B-5696) was investigated. The microorganism uses methanol as the carbon source for their growth and produces exopolysaccharides. The productivity of exopolysaccharides was investigated under various culture modes: batch, fed-batch and continuous culture. In flask culture the growth of cell mass and the production of polysaccharide were inhibited at above 1% (v/v) methanol. At 1%(v/v) methanol maximum specific growth rate was obtained. As C/N ratio (g methanol/g ammonium sulfate) increased, polysaccharide production increased and cells mass decreased. Magnesium ion was also found to be essential for the polysaccharide production. In batch culture the production of polysaccharides was more affected by the specific growth rate than the cell concentration. In fed-batch culture the concentration of polysaccharide was 4 times higher than that of batch culture, but the yield was lower. The productivity of fed-batch with continuous feeding was higher than that of batch or fed-batch with intermittent feeding. This is due to no methanol limitation or inhibition that used to occur in fed-batch culture with intermittent feeding. In continuous culture pure oxygen was supplied to avoid the oxygen limitation. As the dilution rate in- creased up to 0.21 h-1, the yield and productivity increased. The solution viscosity of the produced polysaccharide obtained from above increased exponentially with the concentration of polysaccharide.

• Journal of the Korean Society of Food Science and Nutrition
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• v.21 no.5
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• pp.519-524
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• 1992

purified rapeseed(Brassica napus var. Youngsan) protein was hydrolyzed by pronase. The hyrolysate protein was investigated for the some physicochemical and functional properties. UV and intrinsic fluorescence spectra of the hydrolysate showed the maximum absorption at 274nm and 360nm respectively. Intensity of yellow color decreased in the process of hydrolysis and the surface hydrophobicity decreased up to fourfold. The main bands of hydrolysate by sodium dodecyl sulfate-polyacrylamide gel electrophoresis(SDS-PAGE) were observed at 14,000 to 12,000 dalton molecular weight. Solubilities of hydrolyzed protein increased by 10~15% compared to those of unhydrolyzed protein at acidic pH. In the hydrolysate, while absorption of both water and oil, foam expansion and emulsion stability were increased, absolute viscosity, heat coagulation, calcium coagulation, foam stability and emulsion activity were decreased.