• Title/Summary/Keyword: maximum absorption wavelength

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Dyeability and Functionality of Bamboo Extracts (Part I) -Characteristics of Bamboo Extracts and Dyeing Properties of Cotton- (대나무 추출물의 염색성과 기능성 (제1보) -대나무 추출물의 특성과 면직물에 대한 염색성-)

  • Jung, Go-Eun;Lee, Jung-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.2
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    • pp.206-217
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    • 2011
  • The dyeing properties of cotton fabrics with bamboo colorants were studied by investigating the analysis of bamboo colorants, the effect of dyeing conditions (dye concentrations, dyeing temperatures and times on dye uptakes), effect of mordants, and color change. The various colorfastness of dyed fabrics were evaluated for practical use; in addition, the antimicrobial ability, ultraviolet-cut ability, and deodorant ability were also estimated. In the UV-Visible spectrum, the wavelength of the maximum absorption for bamboo stems and leaves extracts was found to be 280nm and 295nm, respectively; in addition, bamboo colorants produced a yellow color. From the FT-IR and GC-MS results, it was assumed that the chromophoric substance from bamboo extracts was composed of flavones substances with tricin. An increased dyeing concentration resulted in a larger dye uptake and a Freundlich absorption isotherm was obtained. A larger dye uptake occurred as the dyeing time and temperature increased. The post-mordanting was more effective than pre-mordanting. Mordants, Fe and N.Fe, were effective for an increased dye uptake. The color of fabrics mordanted with Cu and N.Cu changed to GY. Regardless of mordanting, the colorfastness on the washing of dyed fabrics showed a low rating compared to other fastness. Mordanting adversely affected the lightfastness of dyed fabric. The dyed fabric showed very good antimicrobial abilities of 99.9%. In addition, the ultraviolet-cut ability and deodorant ability improved in cotton fabric dyed with bamboo extracts.

A Study on the Development of Electrophotographic Photoreceptor by Dye Sinsitized System (색소증감계를 이용한 전자사진 감광체개발에 관한 연구)

  • Jeong, Eun-Sil;Kim, Yeong-Sun;Jeong, Pyeong-Jin
    • Korean Journal of Materials Research
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    • v.3 no.5
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    • pp.505-513
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    • 1993
  • To make the electrophotographic photoreceptor that srnsirizes for panchromatic matcrial, the dying element of sunfasr yellow which has an absorption ivavclength at near 400nm, and $\alpha,\beta$-copper phthalocyaninc dying elements with 700nm absorption wavelength were adsorbed and then dispersed onto the zine oxide(Zn0). In ordcr to characterize rhe change In sensitivity the various binders and different mole ratio of ZnO to binder were employed in here. It was found rhat the optimum sensitivity was obtained with 5.5 ratio. I;rom the measurements of electrostatic and spectral sensitivity, it was found that the maximum photographic properties were obtained for mixing the sunfast yellow and $\beta$-copper phthalocyaninr. In this case the electrophotographic sensiri\ity was found to he $E{1:2}$= 1440 lux . sec. And also the spectral sensitivity shows that it had a good properties for panchromatic matcrial.

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Stabilization of Output Pulses from a Passively Q-switched Nd:YVO4 Laser Pumped by a Continuous-wave Laser Diode (연속 발진 다이오드 레이저로 여기된 수동형 Q-스위치 Nd:YVO4 레이저의 출력 펄스 안정화)

  • Ahn, Seung-In;Park, Yune-Bae;Yeo, Hwan-Seop;Lee, Joon-Ho;Lee, Kang-In;Yi, Jong-Hoon
    • Korean Journal of Optics and Photonics
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    • v.20 no.5
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    • pp.276-280
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    • 2009
  • A Cr:YAG crystal was used as a saturable absorber for passive Q-switching of a Nd:$YVO_4$ laser which was pumped by a 1-W continuous wave laser diode. The first surface of the Cr:YAG was high-reflection coated for the pump wavelength. The high-reflection coating improved the absorption efficiency of the pump beam in the Nd:$YVO_4$ through double pass absorption. It also prevented pump beam induced partial bleaching of the Cr:YAG. The peak-to-peak pulse fluctuation of passively Q-switched laser output was approximately 4 %. The minimum pulse-width was measured to be 7.11 ns. Also, the average pulse repetition rate was 9 kHz and the maximum output power was 16.27 mW.

Preparation of Activated Carbon by Recycling of Waste Grape-seed (포도씨를 再活用한 活性炭의 製造)

  • Kim, Hak-Hee;Yoon, Kyung-Sik;Kim, Myung-Nyu
    • Resources Recycling
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    • v.14 no.1
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    • pp.47-54
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    • 2005
  • Korean grape-seed that is one of the agricultural waste was used as a raw material to prepare activated carbon through roasting, carbonization and chemical activation processes. NaOH, KOH, ZnCl$^2$ were also used as activation reagents. The mixing of the ratios of the grape-seed and each activation reagent were varied to 100-300 weight percent. The surface areas of the activated carbon manufacture from the grape-seed were 44.09~121.33 m$^2$/g. The adsorbate transmittance of methylene blue was determined UV absorption at 660 nm as maximum adsorption wavelength using by UV spectrophotometer. As a result, adsorption of methylene blue on the activated carbon prepared with NaOH activation was more successful than others. Equilibrium absorption time was approximately 60 min.

Output power characteristics of a CW Nd:YVO4/KTP laser pumped by a tunable Ti:Sapphire laser (파장가변 티타늄 사파이어 레이저로 펌핑하는 연속발진 Nd:YVO4/KTP 레이저의 출력 특성)

  • 추한태;안범수;김규욱;이치원
    • Korean Journal of Optics and Photonics
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    • v.13 no.2
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    • pp.140-145
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    • 2002
  • We measured the absorption rate of a Nd:YVO$_4$crystal with a thickness of 1 mm and the output power characteristics of a cw Nd:YVO$_4$/KTP laser with respect to the change of wavelength and the polarizations of a tunable Ti:sapphire pump laser with a linewidth of 0.2 nm. In the case of S-polarization (E┴$\pi$) and P-polarization (E∥$\pi$) of a pump laser, the maximum absorption rate of the crystal was 82% at 809.4 nm and 98% at 808.8 nm, and slope efficiencies for the output power of the Nd:YVO$_4$laser (1064 nm) were 43% and 52%, respectively. The maximum Nd:YYO$_4$laser output power of 516 mW was obtained from the P-polarization pump laser of 1000 mW. As a result of an intracavity frequency-doubling, slope efficiency for the output power of the Nd:YVO$_4$/KTP green laker (532nm) was 23% and the maximum output power of 205 mW with the beam quality (M$^2$) of 1.42 was obtained from the P-polarization pump laser of 1000 mW.

Natural Indigo Dyeing by Using Glucose Reduction (포도당 환원을 이용한 천연 인디고 염색)

  • Shin, Youn-Sook;Cho, A-Rang;Yoo, Dong-Il
    • Textile Coloration and Finishing
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    • v.21 no.3
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    • pp.10-18
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    • 2009
  • Dyeing process of the natural indigo powder onto ramie and silk fabrics was investigated by using glucose and calcium hydroxide as a reducing system. Effect of reduction and dyeing conditions such as temperature and time of reduction/dyeing, and concentrations of glucose and calcium hydroxide on the dyeing process were explored. Indigo powder was obtained by drying the conventional niram paste in an oven at $50^{\circ}C$. Color strength of the dyed fabrics was evaluated by K/S value measured at the wavelength of maximum absorption(${\lamda}$max). Munsell color coordinates(H V/C) were used to compare fabric colors of ramie and silk. Ramie fabric showed purple-blue color for all the temperature and time. On the contrary, silk fabric showed wide range of color including brown, brown-green, green at the different temperature. With the increase of K/S value, the coordinate of value(lightness) decreased for both of ramie and silk fabrics. The coordinate of hue(shade) changed drastically with the increase of K/S value for silk fabric, compared with that of ramie fabric which showed nearly constant value at the whole range of K/S value. Optimum concentrations of calcium hydroxide were for 6 g/L for ramie and 4 g/L for silk at $60^{\circ}C$ and 50 min. K/S value increased with the indigo concentration. Maximum K/S value was shown at $10{\sim}12$ g/L of glucose concentration. For both of ramie and silk fabrics, the colorfastness of washing and light was lower than that of rubbing. All the colorfastness values were improved with the increase of color strength.

Natural Indigo Dyeing of Cotton Fabric - One-step reduction/dyeing process - (면직물에의 천연 인디고 염색 - 일단계 환원/염색 공정 -)

  • Shin, Youn-Sook;Cho, A-Rang;Yoo, Dong-Il
    • Textile Coloration and Finishing
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    • v.22 no.2
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    • pp.101-109
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    • 2010
  • The objective of this study is to investigate the characteristics of natural indigo dyeing of cotton fabric. Reduction and dyeing were carried out by one-step process using an infrared dyeing machine at the liquor ratio of 1:100, and subsequently oxidation and washing in water were followed. Dye uptake was increased with the increase of indigo concentration. Over the full range of dyeing tests, the dyeing condition was optimized to $40^{\circ}C$ for 40min. For most of dye concentrations, the cotton fabrics showed mainly PB color. Maximum K/S value was shown at 4g/L of sodium hydrosulfite concentration and the color strength increased with the increase of dye concentration. Value(lightness) decreased with the increase of dye uptake irrespective of mercerization or reduction method, while the mercerized cotton showed two times higher dye uptake than the untreated cotton. Whereas hue of the untreated cotton showed large decrease of P character(5.6~3.5 PB) with the increase of dye uptake, that of the mercerized cotton increased P character(4.7~5.5 PB). Irrespective of mercerization, value and chroma decreased with the increased of dye uptake. In addition, the untreated showed lower chroma than the mercerized cotton. In the case of traditional reduction, hue of the untreated cotton was changed very little with the increase of dye uptake. For hydrosulfite reduction, P character decreased with the increase of dye uptake. The difference of hue value was small with the change of reduction method(hydrosulfite reduction or traditional fermentation). Color character was not influenced by the changed maximum absorption wavelength. Washing fastness showed 4~4/5 shade change rating without any staining. And dry rubbing fastness was good at low color strength. The bacterial reduction ratios of dyed cotton fabric were also increased.

A Study on Charge Transfer Complexes of 1,2,3,4-Tetrahydrocarbazole and Some Derivatives with Chloranil (1,2,3,4-테트라하이드로카바졸 및 그 유도체들과 클로라닐의 전하이동 착물에 관한 연구)

  • Seong-Bae Moon;Jung-Dae Moon
    • Journal of the Korean Chemical Society
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    • v.37 no.11
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    • pp.929-936
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    • 1993
  • Charge transfer complexes of some electron donors with one electron acceptor have been studied to investigate the maximum absorption wavelength and absorbance by UV-Vis spectrometer in three kinds of solvents, such as ethylene chloride, methylene chloride, and chloroform, at the temperature ranges of 16∼25$^{\circ}$C. 1,2,3,4-Tetrahydrocarbazole (THC), 2-methyl, 3-methyl, and 3-ethyl THC were selected as electron donors while chloranil was used as an electron acceptor in this study. It is found that these complexes forms 1 : 1 complexes, and their maximum absorbance and formation constants decreases with respect to the function of the polarity of solvent and temperature. The polarity of solvents and the temperature have been influenced on the formation constants, which were described using the thermodynamic properties. Moreover, the electronic and steric effects of electron donors have also been effects.

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Characteristics of an Optical Waveguide with Two Identical Elliptical Structures (두 개의 동일한 타원형 구조를 지닌 광 도파관의 특성)

  • Jang, SeongHo;Chung, SangHo;Yi, SeungHwan
    • Journal of the Korean Institute of Gas
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    • v.18 no.2
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    • pp.48-54
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    • 2014
  • A unique optical waveguide structure is proposed to enhance the optical characteristics of alcohol screening sensors. This structure is then simulated. The structure consists of two elliptical waveguides that have a common focus to one side and has an IR source and detector at each of the other focal points of the ellipses. When the angle between the two elliptical waveguides is increased from 30 degrees to 90 degrees, the maximum level of irradiance is greatly decreased, falling from $2.23{\times}10^6 W/m^2$ to $5.74{\times}10^5W/m^2$. However, the diameter of the incident rays is at a minimum of 1.86mm and the total incident flux is less than 10% lower when compared to the structure at $90^{\circ}$. It can be seen from the simulation results that this structure might enhance the sensitivity of an optical gas sensor which has a large absorption wavelength.

Effect of Indium Zinc Oxide Transparent Electrode on Power Conversion Efficiency of Flexible Dye-Sensitized Solar Cells (플렉시블 염료 감응형 솔라셀의 효율에 미치는 Indium Zinc Oxide 투명전극의 영향)

  • Lee, Do Young;Chung, Chee Won
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.105-110
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    • 2009
  • IZO thin films have been deposited on poly(ethylene terephthalate) flexible substrate under varying radio frequency (rf) power, process pressure and thickness of IZO films using rf magnetron sputtering under $Ar/O_2$ gas mix. As the process pressure increased, the deposition rate was slightly increased and the transmittance showed little change, but the resistivity was increased. With increasing rf power, the great increase in deposition rate was observed but the transmittance showed a slight change only, and the resistivity was decreased. In addition, an attempt was made to find the optimal thickness of IZO films under varying the thickness of IZO films at the process conditions of 1 mTorr pressure and 90 W rf power, which showed lowest resistivity. IZO thin films with the thickness of $1,500{\AA}$ showed lowest resistivity and also showed highest transmittance around the wavelength zone of the maximum absorption. The power conversion efficiency of solar cells fabricated using various transparent electrodes with different thicknesses were measured and the solar cell with IZO electrode of $1,500{\AA}$ showed the maximum conversion-efficiency of 2.88 %.