• 제목/요약/키워드: maximum absorption wavelength

검색결과 145건 처리시간 0.019초

주파수 200 kHz-3 MHz영역에 대한 알부민용액의 초음파 흡수측정 (Ultrasonic Absorption Measurements of Bovine Serum Albumin Solutions in the Frequency Range 200 kHz to 3 MHz)

  • 배종림
    • The Journal of the Acoustical Society of Korea
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    • 제25권1E호
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    • pp.14-19
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    • 2006
  • Ultrasonic absorption and velocity spectra in bovine serum albumin (BSA) aqueous solutions have been measured at $20^{\circ}C$ over the frequency range 0.2-3 MHz in the pH range 1.5-13.2. The high-Q ultrasonic resonator and pulse-echo overlap methods were used. At acid pH's, excess absorption over that of pH 7 was explained by double relaxation. The pH dependences of the relaxation frequency and maximum absorption per wavelength, showed that the relaxation at about 200 kHz was related to the expansion of molecules and that about 3 MHz resulted from the proton transfer reaction of carboxyl group. At alkaline pH's, the excess absorption was explained by double relaxation. The relaxation at about 300 kHz was associated with a helix-coil transition, and that about 3 MHz was attributed to the proton transfer reaction of phenolic group. The rate constants and volume changes associated with these processes were estimated.

전송선 이론에 의한 적외선 흡수 구조체의 흡수율 모의시험 (Modeling and simulation on an IR absorbing structure with the cascaded transmission line model)

  • 박승만
    • 전기학회논문지
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    • 제62권12호
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    • pp.1725-1729
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    • 2013
  • In this paper, the modeling and simulation of infrared absorption in an infrared absorbing structure with the cascaded transmission line model were carried out. Each layer in the infrared absorbing structure can be modeled as a characteristic impedance of the cascaded transmission line model. The simulation results show that the cavity thickness to get a maximum absorption should be less than a quarter wavelength, which is somewhat different from prevalent thickness. It can be assured that the sheet resistance of an absorbing layer to get a maximum absorption is $377{\Omega}/{\square}$, that the thickness of the absorbing layer dose not affect the spectral characteristics of absorption. It is also shown that the thickness of the active layer is not critical to the IR absorption. It can also be assured that the validation of this modeling is proved in comparison with the previous results from similar absorbing structures.

Study on Wave Energy Generation of Multi-Floating Bodies for Energy Absorption by CFD

  • Li, Kui-Ming;Choi, Yoon-Hwan;Lee, Yeon-Won
    • 동력기계공학회지
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    • 제17권5호
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    • pp.38-43
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    • 2013
  • In order to design a wave energy generating system, a 6-DOF analysis technique is applied to CFD analysis on of a floating body and the behavior is interpreted according to the nature of the incoming waves. A spring constant is adopted to control the motion of multi floating bodies and to calculate the total average power absorption. Three cases of different wavelengths namely 20D, 30D and 40D have been modeled to analyze the total average power absorption. The average power absorption not only varies with the position of the floating body but also varies with wavelength. From the results obtained, it is concluded that the maximum total average power absorption is 9W approximately in wavelength 30D and the minimum total average power absorption is 4.3W approximately in wavelength 40D.

천연염료의 복합염색에 관한 연구 (A Study on the Complex Dyeing of Natural Dye)

  • 신영준
    • 한국의상디자인학회지
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    • 제14권4호
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    • pp.151-162
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    • 2012
  • Regarding experimental study on the dyeing properties of natural dye, I have dyed silk fabric with Styphnolobium japonicum, sappan wood, and indigo. The results of the experiment have been analysed by wavelength of maximum absorption, K/S and CIE Lab chromaticity co-ordinated. The results are as follows: In case of complex dyeing using Styphnolobium japonicum and sappan wood, dyeing with sappan wood, which is red related color, after dyeing with Styphnolobium japonicum, which is yellow related color, is more efficient. When dyeing was maden by complex of Styphnolobium japonicum and sappan wood, Dyeing method by the order of "Styphnolobium japonicum${\rightarrow}$sappan wood${\rightarrow}$mordanting" made the best result of complex dyeing. In case of complex dyeing using Styphnolobium japonicum and Indigo, dyeing with Styphnolobium japonicum after the indigo made the best result. When dyeing with indigo first, and then Styphnolobium japonicum, yellow color was not well dyed, and low level of saturation caused lusterless color. Ordering of Styphnolobium japonicum${\rightarrow}$sappan wood${\rightarrow}$indigo made the best result of complex dyeing in case of complex dying with Styphnolobium japonicum and indigo. Dyeing order, sappan wood first and then indigo last method shown 560~640 nm wavelength of maximum absorption which most color was blue related. In contrast, Indigo first and then sappan wood method shown 460~560nm wavelength of maximum absorption which color was red related. Complex dyeing with sappan wood and indigo was showing lusterless color. In case of dyeing with red and blue, dyeing with sappan wood and indigo was not appropriate.

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Two-Photon Absorption Cross Sections of Dithienothiophene-Based Molecules

  • Chung, Myung-Ae;Lee, Kwang-Sup;Jung, Sang-Don
    • ETRI Journal
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    • 제24권3호
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    • pp.221-225
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    • 2002
  • We performed nonlinear transmission measurements and quantum-chemical calculations on dithienothiophene(DTT)-based molecules to gain insight into the effect of acceptor and donor groups on two-photon absorption(TPA) properties. The TPA intensity showed dispersion characteristics of the single-photon absorption spectrum. When the molecules included an asymmetric donor-acceptor pair, the single- and two-photon absorption maximum wavelengths were red-shifted more than when the molecules had a symmetric donor-donor structure. We interpreted this result as indicating that the $S_2$ state plays the dominating role in the absorption process of molecules with a symmetric structure. The experimental TPA ${\delta}$ values at the absorption peak wavelength showed a dependence on the structural variations. We found the self-consistent force-field theory and Hartree-Fock Hamiltonian with single configuration interaction formalism to be valid for evaluating TPA ${\delta}$. Although the quantum-chemical calculations slightly underestimated the experimental ${\delta}$ values obtained from nonlinear trans -mission measurements, they reasonably predicted the dependence of the ${\delta}$ value on the structural variations. We confirmed the role of molecular symmetry by observing that donor-donor substituted structure gave the highest experimental and theoretical TPA ${\delta}$ values and that the donor-acceptor substituted structure showed a greater red-shift in the TPA absorption maximum wavelength. Overall, the theoretical ${\delta}$ values of DTT-based molecules were in the order of $10^{-46}\;cm^4{\cdot}s{\cdot}photon^{-1}$ and are higher than that of AF-50 by nearly two orders of magnitude.

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사이크로덱스트린과 부탄산의 복합체 형성반응에 의한 초음파 완화 (Ultrasonic Relaxation for Complexation Reaction Between β-Cyclodextrin and Butanoic Acid in Aqueous Solution)

  • 배종림
    • 한국음향학회지
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    • 제31권2호
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    • pp.100-106
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    • 2012
  • The aim of this work was to reveal the effect of butanoic acid in its dissociated form and undissociated form as a guest molecule on the kinetic parameters in an inclusion reaction with ${\beta}$-cyclodextrin (${\beta}$-CD). Ultrasonic absorption measurements in the frequency range from 0.2 to 45 MHz were carried out for ${\beta}$-CD solutions with butanoic acid at $25^{\circ}C$ by ultrasonic relaxation method. The rate and the equilibrium constants were obtained from the guest concentration dependence of the relaxation frequency, and the standard volume change of the complexation reaction were obtained from the maximum absorption per wavelength. A single relaxational absorption was observed, and the cause of the relaxation was attributed to a perturbation of the chemical equilibrium associated with a complexation reaction between ${\beta}$-CD and butanoic acid. These results were compared with those in solutions containing both ${\beta}$-CD and different guest molecules. It was found that the hydrophobicity of guest molecules played an important role in the formation of the inclusion complex and also that the charge on the carboxylic group had a considerable effect on the kinetic characteristics of the complexation reaction.

캐스팅법으로 제작한 Poly(3-hexylthiophene)의 흡수스펙트럼에 따른 형광 특성 (Characteristics of Electronic Absorption Spectrum and Photoluminescence in Cast-Poly(3-hexylthiophene) Films)

  • 김주승;구할본;조재철
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 추계학술대회 논문집
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    • pp.57-60
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    • 1998
  • Poly(3-hexylthiophene)(P3HT) was synthesized by use of FeCl$_3$ as a oxidizing agent at $25^{\circ}C$. The infrared spectrum of our polymer gave good evidence for the conjugation of 3-hexylthiophene monomer unit. P3HT contains the HT(head-to-tail) linkage larger than 64% based on NMR analysis. Electronic absorption and photoluminescence studies show that cast films of P3HT have three exciting state. Absorption spectrum was separated with three maximum peaks by Giese-French method and shifted to the shorter wavelength with increasing temperature. Separated absorption spectrum of P3HT is well adapted to PL peak appeared at longer wavelength. Low temperature PL spectrum is well separated at 669nm, 733nm and 812nm.

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PZT박막 적외선 감지소자의 적외선 흡수층으로 증착된 니켈 박막의 광학 및 전기적 특성 분석 (Absorptance and Electrical Properties Evaluation of Nickel Layer Deposited onto Thin Film Pyroelectric PZT IR Detector)

  • 고종수
    • 대한기계학회논문집A
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    • 제28권11호
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    • pp.1727-1732
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    • 2004
  • A nickel layer was deposited onto the PZT thin films, serving both as a selective radiation absorption layer and as a top electrode. The absorption properties of such nickel coated multi-layered infrared detectors were studied in the visible and infrared wavelength ranges. The optimal thickness of the nickel layer on our substrate was 10nm. The maximum absorption coefficient of the deposited 10nm thick nickel layer was 0.7 at a 632nm wavelength. However, a striking asymmetric polarization hysteresis loop was observed in these PZT thin films with nickel as the top electrode. This asymmetric polarization was attributed to the difference between the dynamic pyroelectric responses in these Ni/PZT/Pt films poled either positively or negatively before the measurement. A positively poled film showed a 40% higher voltage response than a negatively poled detector.

Peak-to-zero modulation of optical absorption via electrically controllable quantum interference

  • Lee, Byoung-Ho;Kim, Kyoung-Youm
    • Journal of the Optical Society of Korea
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    • 제6권2호
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    • pp.33-36
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    • 2002
  • We propose a modulation scheme of optical absorption in a coupled asymmetric quantum well (QW) structure via electrically controllable quantum interference. It is based on the parallel-perpendicular energy coupling effect. We show that by applying an external electric Held in the parallel direction (to the QW layers), we can obtain a maximum (peak-type) absorption at a specific wavelength where absorption cancellation would occur due to electrically induced transparency without such an external Held .

견의 탄닌처리에 관한 연구(III) - 축합형 탄닌과 가수분해형 탄닌의 비교 - (A Study on the Tannin Treatment of Silk Fabrics(III) - Comparion Condensed Tannin with Hydrlyzable Tannin -)

  • 설정화;최석철;조경래
    • 한국염색가공학회지
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    • 제7권3호
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    • pp.60-67
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    • 1995
  • This study was made to investigate the effect of silk fabrics treated with mimosa and tannic acid-weighting effect, surface color according to temprature, treatment time, concentration, pH. The results were as follows ; 1. The wavelength of maximum absorption of mimosa and tannic acid solution appeared at 278.5nm and 275.0nm, respectively. By the irradiation, spectra at wavelength of maximum absorption of mimosa solution disappeared, but those of tannic acid solution decreased after 48hr irradiation. 2. The tannin weighting increased with the increase of concentration, treatment temperature at 8$0^{\circ}C$, acidic condition. In case of tannic acid, it was higher than mimosa. 3. Surface color of silk fabric with mimosa changed from 2.8YR to 5.8YR acc-ording to the increase o( tannin concentration but in case of tannic acid itchanged from 4.2Y to 3.9Y. It was more changed acidic or alkaline conditionthan origine solution.

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