• 제목/요약/키워드: matrix modification

검색결과 270건 처리시간 0.029초

Development of fine grained concretes for textile reinforced cementitious composites

  • Daskiran, Esma Gizem;Daskiran, Mehmet M.;Gencoglu, Mustafa
    • Computers and Concrete
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    • 제18권2호
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    • pp.279-295
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    • 2016
  • A new innovative composite material is textile reinforced cementitious composite (TRCC). To achieve high flexural performance researchers suggest polymer modification of TRCC matrices. In this study, nine ready mix repair mortars commonly used in construction industry and the production of TRCC elements were examined. Mechanical properties such as compressive and flexural strength, drying shrinkage were studied. Being a significant durability concern, alkali silica reaction tests were performed according to related standards. Results showed that, some ready repair mortar mixes are potentially reactive due to the alkali silica reaction. Two of the ready mortar mixes labelled as non-shrinkage in their technical data sheets showed the highest shrinkage. In this experiment, researchers designed new matrices. These matrices were fine grained concretes modified with polymer additives; latexes and redispersible powders. Two latexes and six redispersible powder polymers were used in the study. Mechanical properties of fine grained concretes such as compressive and flexural strengths were determined. Results showed that some of the fine grained concretes cast with redispersible powders had higher flexural strength than ready mix repair mortars at 28 days. Matrix composition has to be designed for a suitable consistency for planned production processes of TRCC and mechanical properties for load-carrying capacity.

전선피복용 컴파운드의 제조에서 가소제의 종류와 첨가량에 따른 물성 변화 연구 (Study on Property Modification with Kind and Additive Amount of Plasticizer in the Manufacture of Compounds for Cable Sheath)

  • 리시앙수;이상봉;조을룡
    • 반도체디스플레이기술학회지
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    • 제18권2호
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    • pp.11-16
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    • 2019
  • The four different polymer compounds were manufactured with the two kinds of plasticizers [(di-2-ethylhexyl sebacate(DOS), and di-2-butyl sebacate(DBS)] and two different additive amounts(18, 26 phr) of the same plasticizer for making cable sheath for ship. Ethylene-vinylacetate, ethylene-propylene-diene-copolymer as matrix polymers and ethylene-vinylacetate grafted maleic anhydride as coupling agent were selected for compounding with fire retardant, closslinking agent, filler, and other additives besides plasticizer. The compound including DOS showed the higher ${\Delta}T$ than that including DBS at the same additive amount in the rheology test. And with increasing plasticizer, the compounds resulted in lower tensile strength and higher elongation by lubricating effect of plasticizer. DOS yielded better aging resistance and cold resistance than DBS due to the good heat resistance and low solidifying point of DOS compared to DBS.

Study on Property Modification with Polymer Compositions in the Manufacture of Compounds for Cable Sheath

  • Li, Xiang Xu;Lee, Sang Bong;Cho, Ur Ryong
    • Elastomers and Composites
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    • 제54권3호
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    • pp.220-224
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    • 2019
  • Herein, three polymer compounds were manufactured using three polymer combination methods, ethylene-vinyl acetate/ethylene-propylene-diene-copolymer (EPDM), ethylene-vinyl acetate (EVA)/polyethylene-A (PE-A; density: 0.870), and ethylene-vinyl acetate (EVA)/polyethylene-B (PE-B; density: 0.885), for making cable sheath for use in the shipping industry. In this study, EVA, EPDM, PE-A, and PE-B were used as matrix polymers, and EVA-grafted maleic anhydride was used as a coupling agent for compounding with various compounds such as a fire retardant, cross-linking agent, filler, and other additives, besides the plasticizer. ${\Delta}T$, Mooney viscosity, and tensile strength increased in order of EPDM < PE-A < PE-B, the probable reason is due to the different crosslinking effect. The three compounds showed similar results for fire resistance and aging resistance after compounding process, but they showed excellent cold resistance owing to the non-polarity of the polymers and sufficient plasticizer content.

쇄빙연구선 ARAON호의 북극해 실측 데이터에 기초한 국부 빙하중 추정식의 수정 (Modification of Local Ice Load Prediction Formula Based on IBRV ARAON's Arctic Field Data)

  • 조성록;최경식
    • 한국해양공학회지
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    • 제33권2호
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    • pp.161-167
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    • 2019
  • This paper focuses on a newly designed ice load formula based on the ARAON's 2016 Arctic field data in order to improve a structural design against ice loads. The strain gage signals from ARAON's hull plating were converted to the local ice pressure upon the hull plating using the influence coefficient matrix and finite element analysis. First, a traditional pressure-area relationship is derived by applying probabilistic approaches to handle the strains measured onboard the ARAON. Then, the local ice load prediction formula is re-analyzed after reviewing the ARAON's additional field data to consider information about the ship speed and thickness of the sea ice. It is shown that the newly developed pressure-area relationship well reflects the influence of other design parameters such as the ship speed and ice thickness in the prediction of local ice loads on Arctic vessels.

Label-free and sensitive detection of purine catabolites in complex solutions by surface-enhanced raman spectroscopy

  • Davaa-Ochir, Batmend;Ansah, Iris Baffour;Park, Sung Gyu;Kim, Dong-Ho
    • 한국표면공학회지
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    • 제55권6호
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    • pp.342-352
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    • 2022
  • Purine catabolite screening enables reliable diagnosis of certain diseases. In this regard, the development of a facile detection strategy with high sensitivity and selectivity is demanded for point-of-care applications. In this work, the simultaneous detection of uric acid (UA), xanthine (XA), and hypoxanthine (HX) was carried out as model purine catabolites by surface-enhanced Raman Spectroscopy (SERS). The detection assay was conducted by employing high-aspect ratio Au nanopillar substrates coupled with in-situ Au electrodeposition on the substrates. The additional modification of the Au nanopillar substrates via electrodeposition was found to be an effective method to encapsulate molecules in solution into nanogaps of growing Au films that increase metal-molecule contact and improve substrate's sensitivity and selectivity. In complex solutions, the approach facilitated ternary identification of UA, XA, and HX down to concentration limits of 4.33 𝜇M, 0.71 𝜇M, and 0.22 𝜇M, respectively, which are comparable to their existing levels in normal human physiology. These results demonstrate that the proposed platform is reliable for practical point-of-care analysis of biofluids where solution matrix effects greatly reduce selectivity and sensitivity for rapid on-site disease diagnosis.

Site spectroscopy probing of Eu3+ incorporated into novel LiYxSryZrO3+α host matrix

  • Ahemen, I.;Dejene, F.B.
    • Current Applied Physics
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    • 제18권11호
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    • pp.1359-1367
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    • 2018
  • In this work, we investigated the spectroscopic properties of $LiY_xSr_yZrO_{3+{\alpha}:Eu^{3+}$, a red emitting nanophosphor based on $SrZrO_3$ perovskite. The synthesis process was an auto-combustion process. X-ray diffractograms show the orthorhombic structure of $SrZrO_3$. Photoluminescence (PL) excitation spectra display a split charge transfer band revealing the presence of two possible sites for the $Eu^{3+}$ ions. The emission spectra at 231 nm excitation illustrate the dominance of the $^5D_0-^7F_1$ transition, which is an indication that the smaller sized $Eu^{3+}$ ions are mostly situated at the more ordered (symmetric) $Sr^{2+}$ sites. The emission spectra at 292 nm & 397 nm excitations show the dominance of $^5D_0-^7F_2$ transition which suggests some of the $Eu^{3+}$ ions are also situated at the distorted $Zr^{4+}$ sites. Both the intensity parameters, asymmetry ratio and the decay lifetimes of the nanophosphors show dependence on $Y^{3+}$ concentration, signifying a modification in the host structure. Maximum quantum efficiency value of ${\approx}46%$ was obtained for the nanophosphors which indicate the need for improvement for practical applications. CIE coordinates show the suitability of this phosphor for both red emission in LED and as a complementary colour for white LED applications.

Effect of Surface Modifying Agents Towards Enhancing Performance of Waste Gypsum Based PBAT Composite

  • Kong, Tae Woong;Kim, In Tae;Sinha, Tridib Kumar;Moon, Junho;Kim, Dong Ho;Kim, Inseon;Na, Kwangyong;Kim, Min-Woo;Kim, Hye-Lin;Hyeong, Taegyeong;Oh, Jeong Seok
    • Elastomers and Composites
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    • 제55권4호
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    • pp.347-353
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    • 2020
  • Stearic acid (SA), polyethylene glycol (PEG), and malic acid (MA) have been used to modify the surface of waste gypsum to develop corresponding poly (butylene adipate-co-terephthalate) (PBAT) composites. According to the mechanical properties, MA-treated gypsum (MA-gypsum) showed the best performance, whereas SA-gypsum showed the worst performance. In contrast to SA and PEG (having -COOH and -OH as polar functional groups, respectively), the presence of both -OH and -COOH in MA is responsible for the superior surface treatment of gypsum and its better dispersion in the polymer matrix (as revealed by FE-SEM analyses). The presence of long aliphatic chain in SA is supposed to inhibit the dispersion of SA-gypsum. Further, the performance of MA-gypsum/PBAT was enhanced by adding polylactic acid (PLA). The maximum optimized contents of MA-gypsum and PLA are 20 and 7.5 wt% for developing a high-performance PBAT composite.

Study on the Characteristic of Elastomer Composite Containing Tungsten Powder

  • Chung, Kyungho
    • Elastomers and Composites
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    • 제56권1호
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    • pp.6-11
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    • 2021
  • In order to develop an ultra-high-density elastomeric material for substitution of steel dynamic dampers, a new curing system and technique for high-loading of the filler were examined in this study. Mechanochemical modification of chloroprene rubber (MAH-g-CR) using an internal mixer was carried out with maleic anhydride (MAH) as a reactive monomer. The optimum amount of MAH was 10 phr and the efficient grafting of MAH on CR could be achieved at a mixing temperature of 100℃. After preparing MAH-g-CR, 50 mol% epoxidized natural rubber (ENR 50) was blended with MAH-g-CR to develop a "self-curable rubber blend system" via reaction between the functional groups of the elastomeric matrices without the curing agent and additives. The content of ENR 50 was fixed at 30 wt.% throughout evaluation of the curing behavior of the MAH-g-CR/ENR blend. Tungsten powder was added to the MAH-g-CR/ENR matrix up to 60 vol.% to obtain ultra-high-density, and the maximum density obtained was 7.57 g/㎤. Stable ts2 (scorch time) and t90 (90% cure time) could be obtained even when tungsten powder was incorporated up to 60 vol.%. In addition, the tensile strength and damping properties of MAH-g-CR/ENR containing 60 vol.% of tungsten were better than those of CR containing 60 vol.% of tungsten.

당뇨병 모바일 앱 관련 연구동향: 텍스트 네트워크 분석 및 토픽 모델링 (Research Trend on Diabetes Mobile Applications: Text Network Analysis and Topic Modeling)

  • 박승미;곽은주;김영지
    • Journal of Korean Biological Nursing Science
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    • 제23권3호
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    • pp.170-179
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    • 2021
  • Purpose: The aim of this study was to identify core keywords and topic groups in the 'Diabetes mellitus and mobile applications' field of research for better understanding research trends in the past 20 years. Methods: This study was a text-mining and topic modeling study including four steps such as 'collecting abstracts', 'extracting and cleaning semantic morphemes', 'building a co-occurrence matrix', and 'analyzing network features and clustering topic groups'. Results: A total of 789 papers published between 2002 and 2021 were found in databases (Springer). Among them, 435 words were extracted from 118 articles selected according to the conditions: 'analyzed by text network analysis and topic modeling'. The core keywords were 'self-management', 'intervention', 'health', 'support', 'technique' and 'system'. Through the topic modeling analysis, four themes were derived: 'intervention', 'blood glucose level control', 'self-management' and 'mobile health'. The main topic of this study was 'self-management'. Conclusion: While more recent work has investigated mobile applications, the highest feature was related to self-management in the diabetes care and prevention. Nursing interventions utilizing mobile application are expected to not only effective and powerful glycemic control and self-management tools, but can be also used for patient-driven lifestyle modification.

Future flood frequency analysis from the heterogeneous impacts of Tropical Cyclone and non-Tropical Cyclone rainfalls in the Nam River Basin, South Korea

  • Alcantara, Angelika;Ahn, Kuk-Hyun
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2021년도 학술발표회
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    • pp.139-139
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    • 2021
  • Flooding events often result from extreme precipitations driven by various climate mechanisms, which are often disregarded in flood risk assessments. To bridge this gap, we propose a climate-mechanism-based flood frequency analysis that accommodates the direct linkage between the dominant climate processes and risk management decisions. Several statistical methods have been utilized in this approach including the Markov Chain analysis, K-nearest neighbor (KNN) resampling approach, and Z-score-based jittering method. After that, the impacts of climate change are associated with the modification of the transition matrix (TM) and the application of the quantile mapping approach. For this study, we have selected the Nam River Basin, South Korea, to consider the heterogeneous impacts of the two climate mechanisms, including the Tropical Cyclone (TC) and non-TCs. Based on our results, while both climate mechanisms have significant impacts on future flood extremes, TCs have been observed to bring more significant and immediate impacts on the flood extremes. The results in this study have proven that the proposed approach can lead to a new insights into future flooding management.

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