• Title/Summary/Keyword: matrix modification

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Microstructure modification and electrochemical properties of steel corrosion in the blended cement systems containing internal chlorides (고농도 염화물을 함유하는 혼합시멘트 계에서 철근부식에 따른 미세구조의 변화와 전기화학적 특성)

  • 나종윤;이승헌;김창은
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.131-134
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    • 1999
  • Microstructure modification and electrochemical properties are investigate to estimate the effects of internal chlorides on the steel corrosion in the blended cement systems. According to the test results, slag cement system showed high chloride binding capacity and low corrosion rate. The impedance data showed three distince arcs from lowest(mHz) frequency to highest (MHz) frequency due to product layer, interfacial reaction and bulk matrix. Through the microstructural investigation, fine steel-matrix interface of slag cement system was observed but rough steel-matrix interface of OPC system was observed. Friedel's salt was thought that the substantial material contributed to the chloride binding of slag cement system.

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Permutation Algorithm for fast Hadamard Transform (고속하다마드 변환을 위한 치환기법)

  • Nam, Ji-Tak;Park, Jin-Bae;Choi, Yun-Ho;Joo, Young-Hoon
    • Proceedings of the KIEE Conference
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    • 1997.07b
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    • pp.616-619
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    • 1997
  • The spectrum-recovery scheme in Hadamard transform spectroscopy is commonly implemented with a fast Hadamard transform (FHT). When the Hadamard or simplex matrix corresponding to the mask does not have the same ordering as the Hadamard matrix corresponding to the FHT, a modification is required. When the two Hadamard matrices are in the same equivalence class, this modification can be implemented as a permutation scheme. This paper investigates permutation schemes for this application. This paper is to relieve the confusion about the applicability of existing techniques, reveals a new, more efficient method: and leads to an extension that allows a permutation scheme to be applied to any Hadamard or simplex matrix in the appropriate equivalence class.

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Investigation of Co-poly-para-aramid Fiber Dispersion in Chloroprene Rubber Matrix and Improvement of Dispersibility Through Fiber Surface Modification

  • Garam Park;Hyeri Kim;Gayeon Jeong;Dohyeong Kim;Seungchan Noh;Dajeong Gwon;Myung Chan Choi;Jaseung Koo
    • Elastomers and Composites
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    • v.57 no.4
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    • pp.175-180
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    • 2022
  • To produce a co-poly-para-aramid fiber (AF, Technora®)-reinforced neoprene rubber composite, dispersion of AF in a neoprene matrix is investigated. The AF is then surface-modified by mercerization and acetone, plasma, and silane treatments to improve dispersibility. Finally, an internal mixer process is used to disperse the surface-modified fibers in the neoprene rubber matrix.

Mechanical Properties of Styrene-Butadiene Rubber Reinforced with Silica by in situ Tetraethoxysilane Hydrolysis over Acid Catalyst

  • Li, Qingyuan;Li, Xiangxu;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.53 no.2
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    • pp.57-66
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    • 2018
  • Styrene-butadiene rubber (SBR), reinforced with different contents of silica (with or without modification using silane coupling agents), was prepared by a modified sol-gel method involving hydrolyzation of tetraethoxysilane over an acid catalyst. The structures of the as-prepared samples were characterized using various techniques, such as scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, and thermogravimetric analysis. The mechanical properties of the as-prepared samples were discussed in detail. The results revealed an increasing of the storage modulus (G') with increase in the silica content without modification. In contrast, G' decreased after modification using silane coupling agents, indicating a reduction in the silica-silica interaction and improved dispersion of silica in the SBR matrix. Both tensile stress and hardness increased with increase in the silica content (with modification) in the SBR matrix, albeit with low values compared to the samples with un-modified silica, except for the case of silica modified using (3-glycidyloxypropyl) trimethoxysilane (GPTS). The latter observation can be attributed to the special structure of GPTS and the effort of oxygen atom lone-pair.

Effect of Surface Treated Magneto-responsible Particle on the Property of Magneto-rheological Elastomer Based on Silicone Rubber

  • Choi, Soyeon;Chung, Kyungho;Kwon, Seunghyuk;Choi, Hyoungjin
    • Elastomers and Composites
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    • v.51 no.2
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    • pp.113-121
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    • 2016
  • Magneto-rheological elastomer (MRE) is a material which shows reversible and various modulus under magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb broader frequency range of vibration. These characteristic phenomena result from the orientation of magnetic particle (i.e., chain-like formation) in rubber matrix. In this study, silicone rubber was used as a matrix of MREs. Carbonyl iron particle (CIP) was used to give magnetic field reactive modulus of MRE. The surface of the CIP was modified with chemical reactants such as silane coupling agent and poly(glycidyl methacrylate), to improve interfacial adhesion between matrix and CIP. The mechanical properties of MREs were measured without the application of magnetic field. The results showed that the tensile strength was decreased while the hardness was increased with the addition of CIP. Also, surface modification of CIP resulted in the improvement of physical properties of MRE, but the degree of orientation of CIP became decreased. The analysis of MR effect was carried out using electromagnetic equipment with various magnetic flux. As the addition of CIP and magnetic flux increased, increment of MR effect was observed. Even though the surface modification of CIP gave positive effect on the mechanical properties of MRE, MR effect was decreased with the surface modification of CIP due to decrease of CIP orientation. Throughout this study, it was found that the loading amounts of CIP affected the mechanical properties of MRE, and surface property of CIP was an important factor on MR effect of MRE.

Research Progress in SiC-Based Ceramic Matrix Composites

  • Dong, Shaoming;Wang, Zhen;Zhou, Haijun;Kan, Yan-Mei;Zhang, Xiangyu;Ding, Yusheng;Gao, Le;Wu, Bin;Hu, Jianbao
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.295-300
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    • 2012
  • SiC-based ceramic matrix composites show many advantages over their monolithic ceramic counterparts, which makes them potential candidates for applications in various fields. Depending strongly on the chemical composition and microstructure of the fiber reinforcement, matrix as well as the fiber/matrix interphase in the material, the properties of ceramic matrix composites(CMCs) are highly tailorable. In this paper, the latest progresses in the interphase design, matrix modification and fiber reinforcement decoration of CMCs are reviewed, their effects on the properties of the CMCs are introduced.

Effect of Allyl Modified/Silane Modified Multiwalled Carbon Nano Tubes on the Electrical Properties of Unsaturated Polyester Resin Composites

  • Swain, Sarojini;Sharma, Ram Avatar;Patil, Sandip;Bhattacharya, Subhendu;Gadiyaram, Srinivasa Pavan;Chaudhari, Lokesh
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.6
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    • pp.267-272
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    • 2012
  • Considering the properties of the carbon nano tubes (CNT), their inclusion into the polymer matrix vastly increases the properties of the resultant composite. However, this is not the case due to the poor interfacial adhesion of the CNT and the polymer matrix. The present approach focuses on increasing the interaction between the polymer matrix and the CNT through the chemical modification of the CNT resulting in allyl ester functionalized carbon nanotubes (ACNT) and silane functionalized carbon nano tubes (SCNT) which are capable of reacting with the polymer matrix during the curing reaction. The addition of ACNT/SCNT into unsaturated polyester resin (UPR) resulted in the improvement of the electrical properties of resulted nanocomposites in comparison to the CNT. The surface resistivity, volume resistivity, dielectric strength, dry arc resistivity, and the comparative tracking index of the nanocomposites were significantly improved in comparison to CNT. The chemical modification of CNT was confirmed via spectroscopy.

Temperature Dependence of Thermo-Mechanical Properties of Banana Fiber-Reinforced Polyester Composites

  • Shaktawat, Vinodini;Pothan, Laly A.;Saxena, N.S.;Sharma, Kananbala;Sharma, T.P.
    • Advanced Composite Materials
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    • v.17 no.1
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    • pp.89-99
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    • 2008
  • Using a Dynamic Mechanical Analyzer (DMA), mechanical properties like modulus and phase transition temperature of polyester composites of banana fibers (treated and untreated) are measured simultaneously. The shifting of phase transition temperature is observed in some treatments. The performance of the composite depends to a large extent on the adhesion between polymer matrix and the reinforcement. This is often achieved by surface modification of the matrix or the filler. Banana fiber was modified chemically to achieve improved interfacial interaction between the fiber and the polyester matrix. Various silanes and alkalies were used to modify the fiber surface. Chemical modification was found to have a profound effect on the fiber/matrix interaction, which is evident from the values of phase transition temperatures. Of the various chemical treatments, simple alkali treatment with 1% NaOH was found to be the most effective.

Periodontal biotype modification using a volume-stable collagen matrix and autogenous subepithelial connective tissue graft for the treatment of gingival recession: a case series

  • Kim, Hyun Ju;Chang, Hyeyoon;Kim, Sungtae;Seol, Yang-Jo;Kim, Hyeong-Il
    • Journal of Periodontal and Implant Science
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    • v.48 no.6
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    • pp.395-404
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    • 2018
  • Purpose: The purpose of this study was to propose a technique for periodontal biotype modification through thickening of the entire facial aspect using a volume-stable collagen matrix and autogenous subepithelial connective tissue graft (CTG) for the treatment of gingival recession. Methods: Four systemically healthy patients showing Miller class I or class II gingival recession in the mandibular incisor area were included in this study. Full-mouth scaling and root planing procedures were performed at least 4 weeks prior to periodontal plastic surgery. A split-thickness flap with a horizontal intrasulcular incision and 2 vertical incisions was used in cases 1-3, and the modified tunnel technique was used in case 4 for coronal advancement of the mucogingival complex. After the exposed root surfaces were debrided thoroughly, double-layered volume-stable collagen matrix was placed on the apical part of the recession and a subepithelial CTG harvested from the palatal area was placed on the coronal part. The amount of root coverage at 3 months postoperatively was evaluated in cases 1-3, and facio-lingual volumetric changes were analyzed in cases 1 and 2. Results: Healing was uneventful in all 4 cases and complete root coverage was shown in cases 1-3. In case 4, reduction of gingival recession was observed at 3 months after surgery. In cases 1 and 2, a comparison of stereolithographic files from the preoperative and postoperative time points demonstrated that the entire facio-lingual volume had increased. Conclusions: The surgical technique suggested herein, using a volume-stable collagen matrix and autogenous subepithelial CTG, may be an effective method for periodontal biotype modification through thickening of the entire facial aspect for the treatment of gingival recession.

Analysis of Design Parameter of Structural Modification using Change of Dynamic Characteristics (동특성 변화로부터 구조물의 변경된 설계파라미터 해석)

  • Oh Jae-Eung;Lee Jung-Woo;Lee Jung-Youn
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.4 s.247
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    • pp.387-392
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    • 2006
  • This paper predicts the modified mass and stiffness of structure using the sensitivity coefficients with the iterative method. The sensitivity coefficients are obtained by the change of the eigenvectors according to structural modification. The method is applied to an examples of a 3 degree of freedom system by modifying mass and stiffness. The predicted mass and stiffness are in good agreement with these from the structural reanalysis using the modified mass and stiffness.