• Title/Summary/Keyword: matrix diffusion

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Synthesis of Magnetic Powder in the Sm-Fe-N System by the Reduction-Diffusion Process (환원-확산법에 의한 Sm-Fe-N계 자성분말 제조)

  • Lee, Jung-Goo;Kang, Seok-Won;Park, Sang-Jun;Oh, Yung-Woo;Choi, Chul-Jin
    • Korean Journal of Metals and Materials
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    • v.48 no.9
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    • pp.842-846
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    • 2010
  • In the present study, the reduction-diffusion method was employed to produce Sm-Fe alloy powder. It was confirmed that the amount of unreacted ${\alpha}-Fe$ in $Sm_2Fe_{17}$ matrix gradually decreased as the percentage of $Sm_2O_3$ increased. $Sm_2Fe_{17}$ single-phase powder was produced by the reduction-diffusion method with 40% excess $Sm_2O_3$. The Ca and Oxygen contents of the powder were approximately 300 ppm and 1600 ppm, respectively, after washing and acid treatment. By a subsequent nitrogenation, $Sm_2Fe_{17}N_x$ magnetic powders were produced. The coercivity of the powder increased with decreasing of the particle size by ball milling, and the highest coercivity of 2850 Oe was obtained after milling for 10 hours.

Stability Enhancement by the Interaction of Diffusion Flames (다수 비예혼합 화염의 안정화 특성)

  • Kim, Jin-Sun;Lee, Byeong-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.10
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    • pp.1420-1426
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    • 2003
  • The stability of turbulent nonpremixed interacting flames is investigated in terms of nozzle configuration shapes and kind of fuels. Four nozzle arrangements - cross 5, matrix 8, matrix 9 and circle 8 nozzles - are used in the experiment. There are many parameters affecting flame stability in multi-nozzle flames such as nozzle separation distance, fuel flowrates and nozzle configuration etc. Key factors to enhance blowout limit are the nozzle configuration and the existence of center nozzle. Even nozzle exit velocity equal 204 m/s, flame is not extinguished when there is not a center nozzle and s/d=15.3∼27.6 in matrix-8 and circular-8 configurations. At these conditions, recirculation of burnt gas is related with stability augmentation. Fuel mole fraction measurements using laser induced fluorescence reveal lifted flame base is not located at the stoichiometric contour.

The Study on Solid-State Reaction Between MgO Single Crystal and $Fe_2O_3$ Powder (단결정 MgO와 분말 $Fe_2O_3$간의 고상 반응 연구)

  • 김성재;박재우
    • Journal of the Korean Ceramic Society
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    • v.32 no.2
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    • pp.234-238
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    • 1995
  • MgFe2O4 formation, grain growth in Fe2O3, Fe solid-solution limit in MgO for MgO-Fe2O3 mixture were studied by means of investigating the distribution of phases and compositions in reaction area between MgO and Fe2O3. The reaction area at equlibrium was composed with MgO-FexO matrix and MgFe2O4 precipitation, MgFe2O4 was formed by precipitating from MgO-FexO matrix dependent on oxygen partial pressure. Fe contents was exponentially decreased with diffusion distance in MgO single crystal, and thus Fe solid-solution limitation in MgO was about 4mol%. The grain growth rate in Fe2O3 base was increased with Mg contents diffused from MgO single crystal.

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Evaluation of Several Parameters of in situ Polymerase Chain Reaction (ISPCR) to Reduce the Leakage of Amplificants from Cells

  • Lee, Jae-Yung;Auh, Chung-Kyoon;George W. Jordan
    • Journal of Microbiology
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    • v.40 no.1
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    • pp.70-76
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    • 2002
  • Proviral DNAs from HIV-1-infected CD4+ T cells (Molt/LAV cells) were amplified and detected in infected individual cells using polymerase chain reaction and in rifu hybridization. In this in situ PCR, three parameters were considered to achieve effective amplification and retention of amplificants inside the cells by making high molecular weight PCR products intracellularly, forming agarose matrix against the cells, and maintaining the appropriate PCR temperature profile. Over the cycles of ampliHcationl tailed primers with complementary overhanging sequences at their 5' sides manufactured high molecular weight products by using short primary products as a repeating unit. Agarose matrix could prevent the diffusion of the amplificants from the cells. Use of Thermanox coverslip inside the PCR tube offered target cells a similar temperature profile to that of conventional PCR in solution.

Effect of Ethanolamine Salts and Enhancers on the Percutaneous Absorption of Meloxicam from a Pressure Sensitive Adhesive Matrix

  • Ki, Han-Moe;Cheong, Hyun-Ah;Choi, Hoo-Kyun
    • Journal of Pharmaceutical Investigation
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    • v.37 no.3
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    • pp.173-177
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    • 2007
  • The purpose of this study was to investigate the effect of salt formation on the percutaneous absorption of meloxicam through hairless mouse skin from a pressure sensitive adhesive (PSA) matrix. In addition, the influences of enhancers on the permeation of meloxicam or meloxicam-ethanolamine (MX-EA) salts across the hairless mouse skin were evaluated using a flow-through diffusion cell system. The salt formation of meloxicam resulted in lower permeation rate than the parent drug. $Span^{(R)}$ 80 provided the highest enhancing effect for meloxicam and meloxicam monoethanolamine salt. The maximum amount of the drug that can be loaded without retarding permeation rate was different depending on the compound. No relationship was found between the fluxes of meloxicam or MX-EA salts from saturated solutions and those from PSA matrices containing the same enhancer.

Preparation of Furosemide Retard Tablets Using Hydroxyethylcellulose as Matrix Forming Material (히드록시에칠셀룰로오스를 겔상 메트릭스로 사용한 서방성 푸로세미드정제의 제조)

  • Kim, Choong-Ho;Shim, Chang-Koo;Lee, Min-Hwa;Kim, Shin-Keun
    • Journal of Pharmaceutical Investigation
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    • v.17 no.2
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    • pp.47-53
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    • 1987
  • Furosemide retard tablets were prepared using hydroxyethylcellulose(HEC) as a matrix material. Dissolution of furosemide from this tablet was retarded significantly comparing with conventional tablets and greatly dependent on HEC concentration and pH of the dissolution medium. The mechanism of retarded release was supposed to be due to HEC gel formation and drug diffusion through the gel matrix.

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Numerical Simulation of 2-D Estuaries and Coast by Multi-Domain and the Interpolating Matrix Method (Multi-Domain과 행렬 보간법을 이용한 강 하구와 연안의 2차원 수치해석)

  • Chae H. S.
    • Journal of computational fluids engineering
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    • v.2 no.1
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    • pp.21-28
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    • 1997
  • This paper presents a two-dimensional horizontal implicit model to general circulation in estuaries and coastal seas. The model is developed in non-orthogonal curvilinear coordinates system, using the Interpolating Matrix Method (IMM), in combination with a technique of multi-domain. In the propose model, the Saint-Venant equations are solved by a splitting-up technique, in the successive steps; convection, diffusion and wave propagation. The ability of the proposed model to deal with full scale nature is illustrated by the interpretation of a dye-tracing experiment in the Gironde estuary.

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The Metallization of Diamond Grits

  • Sung, James-C.;Hu, Shao-Chung;Chang, Yen-Shuo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1134-1135
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    • 2006
  • A revolutionary "Active Braze Coated Diamond" (ABCD) has been developed for bonding diamond grits firmly in the metal matrix. The molten braze is wetted and reacted with diamond to form strong chemical bond at the interface so that the diamond does not become knocked out of tools. The ABC is a nickel alloy that can form metallurgical diffusion bondswith the metal matrix. In essence, ABCD turns diamond into a metal grain so that the diamond tools can be made by conventional powder metallurgical process without being concerned about the poor bonding between matrix metal powder and the diamond as before.

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Controlled Release of Drugs from Silicone Rubber Matrices-Effects of Physical Properties of Drugs and Release Controlling Agents on Drug Release Mechanisms- (실리콘 마트릭스로부터의 약물조절 방출-약물 및 방출조절제의 물성이 방출기전에 미치는 영향-)

  • Jeon, So-Young;Lee, Seung-Jin
    • Journal of Pharmaceutical Investigation
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    • v.21 no.4
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    • pp.237-245
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    • 1991
  • Matrix type silicone rubber devices were designed for long-term implantable drug delivery system. Release controlling agents (RCA), i.e., polypropylene glycol, polyethylene glycol, were employed to control drug release from the devices. The release rate of drug from RCA dispersed silicone matrices was mainly dependent on hydrophilicity-hydrophobicity of drug and RCA. In the case of hydrophilic drug, the release from the RCA dispersed matrix was regulated by swelling kinetics. Especially when the relatively hydrophobic polypropylene glycol was used, swelling control mechanism induced zero-order release kinetics. Whereas, the release of hydrophobic drug was resulted from partition mechanism. The effect of RCA was to increase drug diffusivity.

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Fourier Transform Infrared Matrix Isolation Study of Acetonitrile in Solid Argon

  • Hack Sung Kim;Kwan Kim
    • Bulletin of the Korean Chemical Society
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    • v.13 no.5
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    • pp.520-526
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    • 1992
  • The intramolecular fundamental vibrations of $CH_3CN$ trapped in solid argon matrix have been reinvestigated by means of FT-IR spectroscopy in the spectral range of 4000-500 $cm^{-1}$. By employing a quantum detector, infrared spectra could be obtained at matrix to solute ratio of 10000, allowing the clarification of the peaks due to monomeric species more clearly. Temperature controlled diffusion was initiated to identify the dimeric and polymeric species in terms of difference spectra. The assignments of monomeric and dimeric species are found, in general, to agree with the earlier work performed at higher concentration (Ar/$CH_3CN$ = 1500) using a dispersive spectrometer. Nonetheless the difficulty of minute differences between the earlier infrared and Raman spectroscopic results could be resolved. Moreover, the previously unnotified peaks due to polymeric species have been identified.