• Title/Summary/Keyword: material recovery

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Recovery of Intracel lular Biomaterials from the Suspension of Lysed or Disintegrated Yeast by Membranes

  • Matsumoto, Kanji
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.10a
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    • pp.1-6
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    • 1994
  • Many useful biomaterials like enzymes are contained in yeast cells. However, the release of these intracellular biomateriais from the cells is required to recover them with hot water, solvent or various cell breakage methods of mechanical or non mechanical ones. The cell lysis or breakage of yeast is usually made by solvent like ethyl acetate and mechanical disintrgration with high pressure homogenizer or agitating beads mill. The separation of cell debris (i.e. solid liquid separation) is done by centrifuge or membrane depending on the recovery conditions. The features of both separation methods are shown in Tables 1 and 2. As it is often difficult to obtain a clear supernatant by centrifuge from the suspension containing cell debris, the membrane separation is also often used to gel a clear supernatant. In this report we introduce the several applications of membrane separation to separate the cell debris of yeast disintegrated chemically or mechanically and to recover the intracellular biomaterials.

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Basic Research on 3D Cultural Heritage Packaging Technology Using Thermoplastic Polyurethane Elastomers

  • Oh, Seung-Jun;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.37 no.1
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    • pp.55-62
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    • 2021
  • This study investigated mechanical property changes by measuring compression factors, resilience, and compressive strength according to packaging pattern and filling rate to identify the applicability of cultural heritage packaging using thermoplastic polyurethane elastomers (TPU). Research results indicate that the cross-shaped 3D pattern showed the best resilience when the internal filling rate was 20%, while the octet pattern was the best when the filling rate was either 40 and 60%. The octet pattern had the best mechanical properties and stability with resistance capacities of 20.79 kgf/cm2, 40.40 kgf/cm2, and 82.23 kgf/cm2 at 38%, 39%, and 40% recovery speeds, respectively, depending on the internal filling rate (20, 40, 60%). Based on these results, basic data on the applicability, stability, and reliability of 3D cultural heritage packaging materials using TPU materials were obtained.

An Analysis of Cutting Force in Micromachining (미소절삭에서의 절삭력 해석)

  • Kim, Dong Sik;Kahng, C.H.;Kwak, Yoon Keun
    • Journal of the Korean Society for Precision Engineering
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    • v.12 no.12
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    • pp.72-80
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    • 1995
  • Ultraprecision machining technology has been playing a rapidly increasing and important role in manufacturing. However, the physics of the micromachining process at very small depth of cut, which is typically 1 .mu. m or less is not well understool. Shear along the shear plane and friction at the rake face dominate in conventional machining range. But sliding along the flank face of the tool due to the elastic recovery of the workpiece material and the effects of plowing due to the large effective negative rake angle resultant from the tool edge radius may become important in micromachining range. This paper suggests an orthogonal cutting model considering the cutting edge radius and then quantifies the effect of plowing due to the large effective negative rake angle.

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Recovery of Cobalt from Waste Cathode Active Material Using Organic Acid (폐 리튬이온 배터리 양극으로부터 유기산을 이용한 코발트 회수)

  • Moon, Ji-Hoon;Ahn, J.E.;Kim, Hyun-Jong;Sohn, S.H.;Lee, H.W.;Kim, H.S.
    • Applied Chemistry
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    • v.16 no.1
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    • pp.73-76
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    • 2012
  • Due to the developments of communications equipment and electronic devices, lithium ion secondary battery usage is growing. Along with demand increasing, the amount of scrap has been steadily increasing. In this study, method of cobalt recovery using organic eco-friendly is proposed. Sulfuric acid, Malic acid, Citric acid at reflux device had good cobalt leaching efficiency. And Sulfuric acid, Malic acid at the autoclave increased cobalt leaching efficiency.

Water and Oil Repellency of Wool Fabric Treated with Nano-type Finishing Agent (Wool 직물의 나노 발수 발유가공)

  • Choi, Bo-Ryun;Han, Sam-Sook;Lee, Mun-Cheul
    • Textile Coloration and Finishing
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    • v.20 no.6
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    • pp.26-34
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    • 2008
  • Wool fabric having high moisture content were treated with fluorocarbon-based water and oil repellent finishing agents by pad-dry-cure system. Three types of finishing agents which were regular-type or nano-type were adapted to compare the surface chemical composition, water and oil repellent property, crease recovery angle, and durability to repeated laundering. From the surface chemical compositions resulted by ESCA and C1s curve-fitting, it was shown that the regular-type finishing agent were easily taken off from the finished wool fabrics after repeated laundering. On the other hand, the fluoroalkyl groups of nano-type finishing agents turned round from fabric surface to fiber internal after repeated laundering. The water repellency of the wool fabrics treated with regular-type agent had a little changes according to the treatment condition changes and sharply decreased with repeated laundering. However, these values when treated with nano-type agents increased with the concentration and cure temperature and were maintained after 20 times laundering. The wool fabrics treated with nano-type agent had a great oil repellency irrespective of treatment conditions. Furthermore, the wrinkle recovery values of the wool fabrics treated with nano-type agents were higher than those of the fabrics treated with regular-type agent and were unchanged after 20 times laundering.

Analysis of Springback of Sheet Metal(I): Analytical Model Based on the Residual Differential Strain (박판재의 스프링백 해석(I)-잔류 변형율에 근거한 해석모델)

  • Lee, Jae-Ho;Kim, Dong-Woo;Sohn, Sung-Man;Lee, Mun-Yong;Moon, Young-Hoon
    • Transactions of Materials Processing
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    • v.16 no.7
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    • pp.509-515
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    • 2007
  • As the springback of sheet metal during unloading may cause deviation from a desired shape, accurate prediction of springback is essential for the design of sheet stamping operations. When considering the case of a sheet metal being bent to radius $\rho$ that is such that the maximum stress induced exceed the elastic limit of the material, plastic strain in the outer surface will occur and the material will take a permanent set: but since, on removing the bending moment, the recovery of the material is not uniform across the thickness, springback will occur and the radius $\rho$ will not be maintained. Furthermore, when a tensile load being applied to each end of specimen, the tensile stress due to bending is increased and the compressive stress is decreased or cancelled and eventually the whole specimen may be in varying degree of tension. On the removal of the applied load the specimen loses its elastic strain by contracting around the contour of the block, the radius $\rho$ will be determined by the residual differential strain. Therefore in this study the springback is analytically estimated by the residual differential strains between upper and lower surfaces of greatest radius after elastic recovery, and a springback model based on the bending moment is also analytically derived for comparison purpose.

Material Life Cycle Assessment of Extrusion Process of A7003 (A7003 알루미늄 합금 압출공정의 MLCA 산정기술)

  • Jo Huyng-ho;Cho Hoon;Kim Byung-min;Kim Young-jig
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2002.11a
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    • pp.43-49
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    • 2002
  • A7003 alloy has characteristics of their excellent weldability, high corrosion resistance and superior plastic working however the broadening of application for the alloy has been hampered by the lower extrudability associated by Mg content. For improvement of extrudability and enhanced recovery efficiency during Al scrap recyeling, it has been generally practiced to reduce Mg content in A7003 alloy. Therefore, it is necessary to investigate the influence of Mg content on mechanical strength and extrudability of A7003 alloy. For efficient material processing which has small amounts, life cycle assessment in material processing(MLCA) is evaluated. The quantitative analysis of energy requirements and $CO_2$ emission for production of A7003 extruded bar are estimated with different Mg content and billet pre-heating process (heating source by light oil or LPG). In particular, the estimation of energy requirements was performed within shipping and gating range (except the mining and extraction stages)to investigate the influence of the variables on energy requirements and $CO_2$ emission in detail. As Mg content increased, the flow stress and the extrusion pressure for A7003 alloy increased. It has been thought that an increment in extrusion pressure with increasing Mg content is caused by the solid solution hardening of Mg atoms in the matrix and increment in volume fraction of intermetallic compound, $Mg_2Si$. The extrudability and the tensile strength are equal to, or above that of conventional A 7003 alloy even the content of Mg varied from $1.1wt.\%\;to\;0.5wt.\%$ alloy. This means that minimizing the content of Mg in A7003 alloy can enhance recovery efficiency during Al scrap recycling. It can be quoted that rather than Mg content energy source for billet heating is a prime factor to determine the atmospheric $CO_2$ emission.

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Study of Humidity Sensing Properties Related to Metal Content of Aerosol Deposited Ceramic/Metal Composite Films (에어로졸 증착한 세라믹/금속 복합막의 금속 함량에 따른 습도 감지 특성 연구)

  • Kim, Ik-Soo;Koo, Sang-Mo;Park, Chulhwan;Shin, Weon Ho;Lee, Dong-Won;Oh, Jong-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.5
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    • pp.314-320
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    • 2021
  • Controlling ambient humid condition through high performance humidity sensors has become important for various fields, including industrial process, food storage, and the preservation of historic remains. Although aerosol deposited humidity sensors using ceramic BaTiO3 (BT) material have been widely studied because of their longtime stability, there remain critical disadvantages, such as low sensitivity, low linearity, and slow response/recovery time in case of the sensors fabricated at room temperature. To achieve superior humidity sensing properties even at room temperature condition, BT-Cu composite films utilizing aerosol deposition (AD) process have been proposed based on the percolation theory. The BT-Cu composite films showed gradually improved sensing properties until the Cu concentration reached 15 wt% in the composite film. However, the excessive Cu (above 30 wt%) containing BT-Cu composite films showed a rapid decrease of the sensing properties. The results of observed surface morphology of the AD fabricated composite films, to figure out the metal filler effect, showed correlation between surface topography as well as size and the amount of open pores according to the metal filler content. Overall, it is very important not only dielectric constant of the humidity sensing films but also microstructures, because they affect either the variation range of capacitance by ambient humidity or adsorption/desorption of ambient humidity onto/from the humidity sensing films.

Preparation of diffusion dialysis membrane for acid recovery via a phase-inversion method

  • Khan, Muhammad Imran;Wu, Liang;Hossain, Md. Masem;Pan, Jiefeng;Ran, Jin;Mondal, Abhishek N.;Xu, Tongwen
    • Membrane and Water Treatment
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    • v.6 no.5
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    • pp.365-378
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    • 2015
  • Herein, the preparation of anion exchange membrane (AEM) from brominated poly(2,6-dimethyl 1,6-phenylene oxide) BPPO and dimethylaniline (DMA) by phase-inversion process is reported. Anion exchange membranes (AEMs) are prepared by varying the DMA contents. Prepared AEMs show high thermal stability, water uptake (WR) around 202% to 226%, dimensional change ratios of 1.5% to 2.6% and ion exchange capacities (IECs) of 0.34 mmol/g to 0.82 mmol/g with contact angle of $59.18^{\circ}$ to $65.15^{\circ}$. These membranes are porous in nature as confirmed by SEM observation. The porous property of membranes are important as it could reduce the resistance of transportation of ions across the membranes. They have been used in diffusion dialysis (DD) process for recovery of hydrochloric acid (HCl) from the mixture of HCl and ferrous chloride ($FeCl_2$). Presence of $-N+(CH_3)_2C_6H_5Br^-$ as a functional group in membrane matrix facilitates its applications in DD process. The dialysis coefficients of hydrochloric acid ($U_H$) of the membranes are in range of 0.0016 m/h to 0.14 m/h and the separation factors (S) are in range of 2.09 to 7.32 in the $HCl/FeCl_2$ system at room temperature. The porous membrane structure and presence of amine functional group are responsible for the mechanism of diffusion dialysis (DD).

A Rapid Method for Analysing Polycyclic Aromatic Hydrocarbons (PAH's) in Urban Dust Using Supercritical Fluid Extraction (SFE) and Gas Chromatography/Mass Spectrometry (GC/MS)허귀석, 김달호 (초임계유체추출과 GC/MS를 이용한 도심 대기분진 중 PAH들의 신속한 분석법에 관한 연구)

  • Heo, Gwi Seok;Kim, Dal Ho
    • Journal of the Korean Chemical Society
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    • v.38 no.10
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    • pp.726-733
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    • 1994
  • Supercritical fluid extraction (SFE) followed by gas chromatographic separation and mass spectrometric (MS) detection were used in rapid analysis of polycyclic aromatic hydrocarbons (PAH's) in air particulate material extracted for 30 min with 10 ml of supercritical $N_2O$ without another sample preparation step. Two samples, urban dust in Seoul area and a certified air particulate reference material 1649 supplied by the NBS (National Bureau of Standards), were processed for the purpose of evaluating extraction and analysis methods. As a result, the quantitative recovery of PAH's in the SFE method was relatively lower than conventional organic solvent extraction methods, but reproducibility was resonable, and analysis time was reduced remarkably. The method has proved to be suitable for monitoring of PAH's in air particulate material.

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