• 제목/요약/키워드: mass uncertainty

검색결과 252건 처리시간 0.028초

Determination of more than 500 Pesticide Residues in Hen Eggs by Liquid Chromatography-Tandem Mass Spectrometry (LC-MS/MS) and Gas Chromatography-Tandem Mass Spectrometry (GC/MS/MS)

  • Golge, Ozgur;Liman, Turan;Kabak, Bulent
    • 한국축산식품학회지
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    • 제41권5호
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    • pp.816-825
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    • 2021
  • This study aims to validate a fast method of simultaneous analysis of 365 LCamenable and 142 GC-amenable pesticides in hen eggs by liquid chromatography-tandem mass spectrometry (LC-MS/MS) and gas chromatography-tandem mass spectrometry (GC-MS/MS), respectively, operating in multiple reaction monitoring (MRM) acquisition modes. The sample preparation was based on quick, easy, cheap, effective, rugged, and safe (QuEChERS) extraction. Key method performance parameters investigated were specificity, linearity, limit of quantification (LOQ), accuracy, precision and measurement uncertainty. The method was validated at two spiking levels (10 and 50 ㎍/kg), and good recoveries (70%-120%) and relative standard deviations (RSDs) (≤20) were achieved for 92.9% of LC-amenable and 86.6% of GC-amenable pesticide residues. The LOQs were ≤10 ㎍/kg for 94.2% of LC-amenable and 92.3% of GC-amenable pesticides. The validated method was further applied to 100 egg samples from caged hens, and none of the pesticides was quantified.

Probabilistic study on buildings with MTMD system in different seismic performance levels

  • Etedali, Sadegh
    • Structural Engineering and Mechanics
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    • 제81권4호
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    • pp.429-441
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    • 2022
  • A probabilistic assessment of the seismic-excited buildings with a multiple-tuned-mass-damper (MTMD) system is carried out in the presence of uncertainties of the structural model, MTMD system, and the stochastic model of the seismic excitations. A free search optimization procedure of the individual mass, stiffness and, damping parameters of the MTMD system based on the snap-drift cuckoo search (SDCS) optimization algorithm is proposed for the optimal design of the MTMD system. Considering a 10-story structure in three cases equipped with single tuned mass damper (STMS), 5-TMD and 10-TMD, sensitivity analyses are carried out using Sobol' indices based on the Monte Carlo simulation (MCS) method. Considering different seismic performance levels, the reliability analyses are done using MCS and kriging-based MCS methods. The results show the maximum structural responses are more affected by changes in the PGA and the stiffness coefficients of the structural floors and TMDs. The results indicate the kriging-based MCS method can estimate the accurate amount of failure probability by spending less time than the MCS. The results also show the MTMD gives a significant reduction in the structural failure probability. The effect of the MTMD on the reduction of the failure probability is remarkable in the performance levels of life safety and collapse prevention. The maximum drift of floors may be reduced for the nominal structural system by increasing the TMDs, however, the complexity of the MTMD model and increasing its corresponding uncertainty sources can be caused a slight increase in the failure probability of the structure.

해저작업 로봇 매니퓰레이터의 강건한 신경망 제어기 (A Robust Neural Control of Robot Manipulator Operated Under the Sea)

  • 박예구;최형식;이민호
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1995년도 추계학술대회 논문집
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    • pp.337-341
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    • 1995
  • This paper presents a robust control scheme using a multilayer network for the robot manipulator operating under the sea which has large uncertainties such as the buoyancy and the added mass/moment of inertia. The multilayer neural network acts as a compensator of the conventional sliding mode controller to maintain the control performance when the initial assumptions of uncertainty bounds are not valid. By the computer simulation results, the proposed control scheme dose not effectively compensate large uncertainties, but also reduces the steady stare error of the conventional sliding mode controller.

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Optimal estimation of rock joint characteristics using simulated annealing technique - A case study

  • Hong, Chang-Woo;Jeon, Seok-Won
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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    • pp.78-82
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    • 2003
  • In this paper, simulated annealing technique was used to estimate the rock joint characteristics, RMR(rock mass rating) values, to overcome the defects of ordinary kriging. Ordinary kriging reduced the variance of data, so lost the characteristics of distribution. Simulated annealing technique could reflect the distribution feature and the spatial correlation of the original data. Through the comparisons between three times simulations, the uncertainty of the simulation could be quantified, and sufficient results were obtained.

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대용량 이동 객체 위치 데이타 관리 시스템의 개발 (Development of a Location Data Management System for Mass Moving Objects)

  • 김동오;주성완;장인성;한기준
    • 한국공간정보시스템학회 논문지
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    • 제7권1호
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    • pp.63-76
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    • 2005
  • 최근 이동 객체의 위치 데이타를 이용하기 위한 무선 측위 기술과 모바일 컴퓨팅 기술이 급속도로 발전하였다. 또한, 이동 객체의 위치 데이타를 활용하는 위치 기반 서비스에 대한 수요가 급증하고 있으며, 이러한 서비스를 지원하기 위해서는 이동 객체의 위치 데이타를 효과적으로 저장할 수 있는 시스템이 필요하다. 이러한 시스템은 이동 객체의 수가 많고 위치 획득 간격이 짧을수록 위치 데이타가 급격히 늘어나기 때문에 대용량의 위치 데이타 처리가 가능해야 하며, 위치 기반 서비스를 위한 다양한 시공간 질의를 지원해야 하고, 또한 이동 객체의 불확실성 문제를 해결할 수 있어야 한다. 따라서, 본 논문에서는 이동 객체의 위치 데이타를 효율적으로 관리하기 위한 해쉬 기법, 클러스터링 기법, 시간 질의 검색 기법을 제시하였다. 그리고, 대용량의 이동 객체 위치 데이타를 효과적으로 저장하고 검색할 수 있으며, 시공간 질의 기능과 불확실한 과거 위치 데이타 처리 기능을 제공하는 디스크 기반의 대용량 이동 객체 위치 데이타 관리 시스템을 개발하였다. 본 시스템을 SQL-Server과 성능 비교한 결과 이동 객체 저장 성능은 약 5% 증가하였으며, 이동 객체 검색성능은 약 300% 증가하였다.

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Isotope Measurement of Uranium at Ultratrace Levels Using Multicollector Inductively Coupled Plasma Mass Spectrometry

  • Oh, Seong-Y.;Lee, Seon-A.;Park, Jong-Ho;Lee, Myung-Ho;Song, Kyu-Seok
    • Mass Spectrometry Letters
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    • 제3권2호
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    • pp.54-57
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    • 2012
  • Mass spectrometric analysis was carried out using multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) for the precise and accurate determination of the isotope ratios of ultratrace levels of uranium dissolved in 3% $HNO_3$. We used the certified reference material (CRM) 112-A at a trace level of 100 pg/mL for the uranium isotopic measurement. Multiple collectors were utilized for the simultaneous measurement of uranium isotopes to reduce the signal uncertainty due to variations in the ion beam intensity over time. Mass bias correction was applied to the measured U isotopes to improve the precision and accuracy. Furthermore, elemental standard solution with certified values of platinum, iridium, gold, and thallium dissolved in 3% $HNO_3$ were analyzed to investigate the formation rates of the polyatomic ions of $Ir^{40}$ $Ar^+$, $Pt^{40}$ $Ar^+$, $Tl^{40}$ $Ar^+$, $Au^{40}$ $Ar^+$ for the concentration range of 50-400 pg/mL. Those polyatomic ions have mass-to-charge ratios in the 230-245 m/z region that it would contribute to the increase of background intensity of uranium, thorium, plutonium, and americium isotopes. The effect of the polyatomic ion interference on uranium isotope measurement has been estimated.

A Study of the Transient Flow Characteristics of a Vacuum Ejector-Diffuser System.

  • ;김희동
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2769-2774
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    • 2007
  • In vacuum ejector-diffuser systems where a finite volume secondary chamber is used, the secondary jet exhibits transient characteristics during start-up. A steady state is achieved after some time in which mass entrainment prevails indefinitely inside the ejector, though there is no flow from the secondary chamber. An attempt is made in this work to study the infinite entrainment of secondary jet into the primary jet from a finite secondary chamber, with the help of a computational fluid dynamics method. The present study is also intended to identify the operating range of vacuum ejector-diffuser systems where the steady flow assumption can be applied without uncertainty. The results obtained show that the only condition in which an infinite mass entrainment is possible is the generation of a re-circulation zone near the primary nozzle exit. The flow in the secondary chamber attains a state of dynamic equilibrium at this point. Steady flow assumption is valid only after this point.

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Probabilistic stability analysis of underground structure using stochastic finite element method

  • Na, Sang-Min;Moon, Hyun-Koo
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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    • pp.192-197
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    • 2003
  • It can be said that rock mass properties are characterized not by a mean value but by values with variation due to its characteristic uncertainty. This characteristic is one of the most important parts for the design of underground structures, but yet to be fully examined. Stochastic finite element method (SFEM) has been developed in order to take the randomness of structural systems into account. Using SFEM, the response variability of structural system can be obtained and it leads probabilistic stability of structure to be analyzed. In this study, displacements response variability of circular opening with hydrostatic stress field are analyzed in terms of rock mass properties having a certain mean and a standard deviation using the SFEM. The analyzed response variability shows that the necessity of probabilistic stability analysis of underground structures using reliable mean value and standard deviation of deformation modulus.

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다확률변수를 고려한 불확정 지하구조계의 확률론적 유한요소해석 (Stochastic Finite Element Analysis of Underground Structure Considering the Multi-Random Variables in the Physical Properties of Rock mass)

  • 최규섭;정영수;황신일
    • 한국전산구조공학회:학술대회논문집
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    • 한국전산구조공학회 1996년도 봄 학술발표회 논문집
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    • pp.173-181
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    • 1996
  • In this study, a stochastic finite element model is proposed with a view to consider the uncertainty of physical properties of rock mass in the analysis of structural behavior on underground caverns. Here, the Latin Hypercube Sampling technique, in which can makeup weak points of the Monte Carlo Simulation, is applied for the analysis of underground cavern. The validity of the newly developed computer program has been confirmed in terms of verification examples. And, the applicability of the program to the field has been tested in terms of the analysis of the underground oil storage cavern in korea.

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품질안전개선을 위한 공정능력지수의 연구 (The study on the Process Capability Index for Continuously Improvement Quality Safety)

  • 양광모;오선일;강경식
    • 대한안전경영과학회지
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    • 제8권3호
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    • pp.11-25
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    • 2006
  • It is necessary to deal with the process capability index carefully because it has been developed with certain assumptions. Companies make a decision on processes through the results obtained by using and treating data extracted from the processes. However if they have incorrect or wrong results, they cannot lead to proper outputs but also bring to loss of the competition in quality. Therefore, this study will show a method to analysis Cp (process capability ; CP) and an idea of mass-production on Pp (process performance ; PP) based on the Sigma Estimate which is one of the uncertainty in the process capability index and makes a lot of error. To apply this method, it is essential to understand and to analyze the processes exactly. Especially, it is required to establish the more accurate process capability index that can quickly and properly respond to changes on processes to recognize the small changes on the process which lies in specification in mass production system that the continual monitoring of quality managers is required.