• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.12
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• pp.1776-1783
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• 2001

Heat recovery from boiler exhaust gas with multi-stage water-fluidized-bed heat exchanger is analyzed in this study. The recovered energy here is not only sensible heat but also latent heat contained in the exhaust gas. In this system direct contact heat transfer occurs while exhaust gas passes through water bed and the thermal energy recovered this way is again delivered to the water circulating through heat exchanging pipes within the bed. Thus the thermal energy of exhaust gas can be recovered as a clean hot water. A computer program developed in this study can predict the heat transfer performance of the system. The results of experiments performed in this study agree well with the calculated ones. The heat and mass transfer coefficients can be fecund through these experiments. The performance increases as the number of stage increases. However at large number of stages the increasing rate becomes very low.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.7 no.1
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• pp.49-59
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• 1997

This study was performed to analyze the purity of technical grade ${\alpha}$-naphthylamine, to establish optimal analytical condition of ${\alpha}$-naphthylamine in urine and to determine the urine sample of workers exposed to ${\alpha}$-naphthylamine. The purity of technical grade ${\alpha}$-naphthylamine were $96.5{\pm}2.38%$, $94.1{\pm}0.97%$, $97.0{\pm}0.02%$ by gas chromatography-mass selective detector. To analyze ${\alpha}$-naphthylamine in urine, high performance liquid chromatography-electrochemical detector and gas chromatography-electron capture detector operating conditions have been optimized by preliminary expriment. In high performance liquid chromatography-electrochemical detector, the mobile phase was consisted of acetonitrile(35%) and water(65%), and the flow rate was maintained at 1.0ml per minute. Optimal detective condition was 9.0V(10nA/V) of electrochemical detector. The recovery of sep-pak treatment method was highly estimated as pretreatment of ${\alpha}$-naphthylamine in urine. The free amine was isolated by gas chromatography-electron capture detector after basic hydrosis, sep-pak treatment, toluene elution and HFBA(heptafluoro-butyric anhydride) derivatization of urine. The recovery of ${\alpha}$-naphthylamine in urine was $98.73{\pm}3.29%$ by gas chromatography-electron capture detector. The sensitivity was more higher than that of high performance liquid chromatography-electrochemical detector. Urinary ${\alpha}$-naphthylamine was detected in only one worker among nine workers. The level of ${\alpha}$-naphthylamine in urine was 6.42 ng/ml.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.3
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• pp.293-299
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• 2012

The thermodynamic efficiency characteristics of R245fa and water as working fluids have been analyzed for the electricity generation system applying the Rankine cycle to recover the waste heat of the exhaust gas from a diesel engine for the propulsion of a large ship. The theoretical calculation results showed that the cycle, system, and total efficiencies were improved as the turbine inlet pressure was increased for R245fa at a fixed mass flow rate. In addition, the net work rate generated by the Rankine cycle was elevated with increasing turbine inlet pressure. In the case of water, however, the maximum system efficiencies were demonstrated at relatively small ratios of mass flow rate and turbine inlet pressure, respectively, compared to those of R245fa. The optimized values of the net power of the cycle, system efficiency, and total efficiency for water had relatively large values compared to those of R245fa.

• Korean Journal of Microbiology
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• v.45 no.3
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• pp.268-274
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• 2009

A photosynthetic cyanobacterium Arthrospira platensis, well known for health food supplement, was studied as a target species for atmospheric $CO_2$ removal as well as biomass production. Although the biomass of A. platensis was massively produced in many countries, the recovery cost of its biomass is still high. The purpose of this study was to develop the A. platensis mutant strains which have enhanced growth rate and floatation activity to reduce the recovery cost. A. platensis KCTC AG20590 was treated with 0.24% ethyl methanesulfonate (EMS) for 20 min at room temperature. The mutant strain A. platensis M20CJK3 was finally selected by its morphological and physiological features. The morphology of the mutant A. platensis M20CJK3 was changed from loose-coiled form to tight-coiled form showing short pitch. The growth and $CO_2$ uptake rate of A. platensis M20CJK3 were improved about 15% and 17% compared with A. platensis KCTC AG20590, respectively. The floatation activity of A. platensis M20CJK3 was enhanced in 2-fold compared with that of A. platensis KCTC AG20590. Soluble proteins extracted from two strains were analyzed by two dimensional electrophoresis (2-DE) and MALDI-TOF MS/MS. Among 15 protein spots induced in 2-DE analysis, two spots were the proteins related to photosynthesis and electron transfer system of the other cyanobacteria. As a consequence, it seems that the tight-coiled mutant A. platensis M20CJK3 has an advantage of high growth rate and floatation activity which are beneficial for the mass cultivation and recovery.

• KSBB Journal
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• v.8 no.5
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• pp.446-451
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• 1993

In ethanol fermentation, by-products such as glycerol, acetic acid and lactic acid are produced along with ethanol. The effects of culture conditions on cell growth ethanol production and by-products biosynthesis were investigated in ethanol fermentation using S. cerevisiae. With increasing aeration rate or yeast extract concentration, ethanol and by-products biosynthesis decreased while final cell mass increased. With increasing glucose concentration or decreasing temperature, final cell mass, ethanol and by-products concentrations all increased. The optimal pH for the cell growth, ethanol and by-products productions was found to be pH 4.5. By-products biosynthesis was found, in general, to proceed with the ethanol biosynthesis. The results can be applied for the optimization of ethanol fermentation and for the recovery and purification of ethanol from the culture broth.

• Journal of Korean Society for Atmospheric Environment
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• v.34 no.1
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• pp.120-143
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• 2018

The analytical methods and their ambient levels of organic nitrogenous compounds such as nitrosamines, nitramines (nitroamines), imines, amides and nitro-polycyclic aromatic hydrocarbons (nitro-PAHs) in the atmosphere are summarized and discussed. Sampling for the analysis of organic nitrogenous compounds was mostly conducted using high volume air sampler. The direct liquid extraction (DLE) using sonification and the pressurized liquid extraction (PLE) using the accelerated solvent extraction (ASE) have been frequently employed for the extraction of organic nitrogenous compounds in the atmospheric samples. After extraction, clean-up via filtration and the solid phase extraction (SPE) and concentrations using nitrogen and rotary evaporator have been generally conducted but in some studies the clean-up and concentration steps have been omitted to prevent the loss of analyte and improve the recovery rate of the analytical procedure. Instrumental analysis was mainly carried out using gas chromatography (GC) or the high performance liquid chromatography (HPLC) coupled with the single quadrupole mass spectrometer or tandem mass spectrometer in the electron ionization (EI), positive chemical ionization (PCI) and negative chemical ionization (NCI) mode and analysis sensitivity of nitrosamines and nitramines were higher in NCI mode. Desirable sampling and analysis methods for analyzing particulate organic nitrogenous compounds are suggested.

• Nuclear Engineering and Technology
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• v.42 no.3
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• pp.297-304
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• 2010

In the design of advanced light water reactors (ALWRs) and in the safety assessment of currently operating nuclear power plants, it is necessary to evaluate the possibility of experiencing a degraded core accident and to develop innovative safety technologies in order to assure long-term debris cooling. The objective of this experimental study is to investigate the enhancement factors of dryout heat flux in debris beds by coolant injection from below. The experimental facility consists mainly of an induction heater, a double-wall quartz-tube test section containing a steel-particle bed and coolant injection and recovery condensing loop. A fairly uniform heating of the particle bed was achieved in the radial direction and the axial variation was within 20%. This paper reports the experimental data for 3.2 mm and 4.8 mm particle beds with a 300 mm bed height. The dryout heat density data were obtained for both the top-flooding and the forced coolant injection from below with an injection mass flux of up to $1.5\;kg/m^2s$. The dryout heat density increased as the rate of coolant injection increased. At a coolant injection mass flux of $1.0\;kg/m^2s$, the dryout heat density was ${\sim}6.5\;MW/m^3$ for the 4.8 mm particle bed and ${\sim}5.6\;MW/m^3$ for the 3.2 mm particle bed. The enhancement factors of the dryout heat density were 1.6-1.8.

• Mass Spectrometry Letters
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• v.12 no.1
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• pp.1-10
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• 2021

A simple, specific, and economical LC-MS/MS method was investigated for the screening of 43 prescribed antihypertensive and related drugs in human urine. The urine samples were simply prepared by diluting and mixing with internal standard before directly introduced to the LC-MS/MS system, which is fast, straightforward, and cost-effective. Fractional factorial, Box-Behnken, and I-optimal design were applied to screen and optimize the mass spectrometric and chromatographic factors. The analysis was carried out on a triple quadrupole mass spectrometer system utilizing multiple reaction monitoring with positive and negative electrospray ionization method. Chromatographic separation was performed on a Thermo Scientific Accucore RP-MS column (50 × 3.0 mm ID., 2.6 ㎛) using two separate gradient elution programs established with the same mobile phases. Chromatographic separation was performed within 12 min. The optimal method was validated based on FDA guideline. The results indicated that the assay was specific, reproducible, and sensitive with the limit of detection from 0.1 to 50.0 ㎍/L. The method was linear for all analytes with coefficient of determination ranging from 0.9870 to 0.9981. The intra-assay precision was from 1.44 to 19.87% and the inter-assay precision was between 2.69 and 18.54% with the recovery rate ranges from 84.54 to 119.78% for all drugs measured. All analytes in urine samples were stable for 24 h at 25℃, and for 2 weeks at -60℃. The developed method improves on currently existing methods by including larger number of cardiovascular medications and better sensitivity of 12 analytes.

• Journal of Energy Engineering
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• v.20 no.3
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• pp.224-230
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• 2011

For developing high performance fuel cell, peripheral devices and key components have to be studied in priority. In this study, centrifugal pump was studied for heat recovery. For PEM fuel cell system, a four-impeller centrifugal pump was designed, tested and compared with result of commercial product (IWAKI). In addition, effects of number of impeller were analyzed by CFD. The experiment and analysis were progressed in the same conditions. The results showed the quantitative difference under 30% between the numerical and the experimental pressure difference and mass flow rate.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.1
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• pp.25-30
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• 2014

The flow characteristics of two types of overhung compressor volutes for automobile turbochargers were analyzed numerically using commercial software. For obtaining high performance from a volute, it is necessary that the volute have a high pressure recovery coefficient and a low loss coefficient. We investigated the flow characteristics of two types of overhung compressor volutes with a fixed diffuser inlet angle of $24^{\circ}$ and a mass flow rate of 0.055 kg/s. The first type is a volute with one-arc cross section (type 1) and the second type is with three-arc cross section (type 2). Our results showed that between the two types of volutes, type 2 had the higher pressure recovery coefficient and the lower loss coefficient along the entire angular position.