• Title/Summary/Keyword: mass recovery rate

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A Numerical Study of Heat and Mass Transfer Phenomena for Thermal Protection Material (열보호재료의 열 및 물질전달 현상에 관한 수치해석적 연구)

  • Kim, Jung-Hoon;Kwon, Chang-Oh;Seo, Jeong-Il;Bai, Cheol-Ho;Song, Dong-Joo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.9
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    • pp.1201-1212
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    • 1999
  • A numerical analysis is performed to predict the thermal response and ablation rate for charring or non-charring material which is designed to be used as thermal protection system (TPS). The numerical program composed of in-depth energy balance equation and the aerotherm chemical equilibrium (ACE) program. The ACE program calculates various thermochemical state from ablation products. The developed numerical program is verified by comparing the reported results from literature. The sensitivity tests for input parameters are performed. The thermal behavior of ablating material is mainly affected by density of ablating material, convective heat transfer coefficient and recovery enthalpy of flow field.

Performance of adsorption heat pump with radial shape adsorber heat exchanger for air cooling (공냉식 방사형 열교환기를 갖는 흡착식 히트펌프의 성능)

  • Baek, N.C.;Yang, Y.S.;yoon, E.S.;Lee, J.K.;Joo, M.C.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.1
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    • pp.73-81
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    • 1997
  • In this experimental study, the air cooling radial shape heat exchanger which influences on the COP and the cooling capacity by heat and mass transfer rate in the adsorbent bed was designed and applied to test its performance for adsorption heat pump(AHP). Zeolite-water was used for the adsorbent-adsorbat pair. As a result, the cooling COP and a cycle period of this adsorption heat pump are 0.28 and 2 hours, respectively, on the condition of none heat recovery from the adsorption reactor(absorber). The other results and recommendations are mainly related to improving the heat and mass transfer inside the absorber to reduce a cycle period.

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Distribution Model Based on Computer Simulation for Internal Temperature and Moisture Content in Press Drying of Tree Disks (원판(圓板)의 열판건조(熱板乾燥)에서 컴퓨터 시뮬레이션에 의한 내부온도(內部溫度)와 함수율(含水率) 분포모형(分布模型))

  • Yeo, Hwan-Myeong;Jung, Hee-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.2
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    • pp.61-70
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    • 1994
  • This study was executed to find the applicability of press drying of tree disk by investigating the shrinkage and drying defect and to form appropriate model by comparing the actual moisture content(MC) and internal temperature in respect of drying time with calculated values based computer simulation to which was applied finite difference method. In press drying disk, heating period, constant drying rate period maintained plateau temperature at 100$^{\circ}C$ and falling drying rate period were significantly distinguished. Actual MC and internal temperature were analogous to those calculated at comparing points. Heat transfer model formed by Fourier's law using specific heat of moist wood and conduction coefficient considering fractional volume of each element of wood cell wall, bound water, free water and air showed applicability as basic data to developing heat expansion, shrinkage and drying stress during press drying. Also mass transfer model formed by Fick's diffusion law using water vapor diffusion coefficient showed applicability. Longitudinal shrinkage was developed by pressure of hot press and tangential shrinkage was restrained by hygrothermal recovery. The heart check, surface check and ring failure were occurred differently in species, but V-shaped crack didn't develop.

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Quantification of Bacterial Attachment-related Parameters in Porous Media

  • Park, Seong-Jik;Lee, Chang-Gu;Kim, Song-Bae
    • Environmental Engineering Research
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    • v.13 no.3
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    • pp.141-146
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    • 2008
  • Transport of Escherichia coli ATCC 11105 through porous media was investigated in this study using two sets of column experiments to quantify the attachment-related parameters (sticking efficiency, attachment rate coefficient and filter factor). The first set of experiments was performed in quartz sand under different ionic strength conditions (1, 20, 100, 200 mM) while the second experiments were carried out in quartz sand mixed with metal oxyhydroxide-coated sand (0, 5, 10, 25%). The breakthrough curves of bacteria were obtained by monitoring effluent, and then bacterial mass recovery and attachment-related parameters were quantified from these curves. The first experiments showed that the mass recoveries were in the range of 13.3 to 64.7%, decreasing with increasing ionic strength. In the second experiments, the mass recoveries were in the range of 15.0 to 43.4%, decreasing with increasing coated sand content. The analysis indicated that the sticking efficiency, attachment rate coefficient and filter factor increased with increasing ionic strength and coated sand content. The value of filter factor in the first experiments ranged from 1.45 e-2 to 6.72 e-2 1/cm while in the second experiments it ranged from 2.78 e-2 to 6.32 e-2 1/cm. Our filter factor values are one order of magnitude lower than those from other studies. This discrepancy can be attributed to the size of sand used in the experiment. The analysis demonstrated that the travel distance of bacteria estimated using the filter factor can be varied greatly depending on the solution chemistry and charge heterogeneity of porous media.

Study on the Ethanol Recovery Process using Dircet Contact Heat Exchange (고온의 기포접촉에 의한 에탄올 회수공정에 관한 연구)

  • Lee, Won-Young;Yeo, Sang-Do;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
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    • v.27 no.2
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    • pp.176-180
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    • 1995
  • Direct contact heat exchange (DCHE) method has been employed to investigate the separation of ethanol from dilute aqueous solutions. Bubbles at high temperature were dispersed into a continuous liquid phase, generating temperature gradient in air-liquid interface, which causes heat and mass transfer accordingly. The experiments were performed in the ranges of jet regime air flow. The air-water stripping coefficient increased $5{\sim}10,\;and\;1{\sim}1.5$ times as temperature and air flow rate increased, respectively. The recovery ratio based on the initial ethanol concentration reached into 80% at the air flow rate of 84.88 m/min. The initial ethanol concentration showed little effect on the stripping coefficient and the recovery ratio.

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Removal Characteristics of Volatile Organic Compounds in Biofilters and Stoichiometric Analysis of Biological Reaction by Carbon Mass Balance (바이오필터의 휘발성유기화합물 제거특성 및 탄소물질수지를 이용한 생물반응의 양론적 해석)

  • Kim, Dae-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.8
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    • pp.747-753
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    • 2010
  • This study was performed to investigate the removal characteristics of volatile organic compounds (VOCs) in the gasphase biofilters, and to propose a stoichiometric analysis approach to characterize biological reaction through carbon mass balance. The VOCs studied were toluene, styrene, methyl ethyl ketone (MEK), and methyl isobutyl ketone (MIBK) as a single substrate for each biofilter. The critical loading rate was determined to be $46.9\;g/m^3{\cdot}hr$, $25.8\;g/m^3{\cdot}hr$, $96.3\;g/m^3{\cdot}hr$, and $66.5\;g/m^3{\cdot}hr$ for toluene, styrene, MEK, and MIBK, respectively. The obtained results indicated that the critical loading rate was well correlated the octanol-water partition coefficient. In the analysis of carbon mass balance, carbon recovery to $CO_2$ became relatively lower as substrate loadings increased, but higher for carbon recovery to biomass. Stoichiometric analysis revealed that biomass yield increased as substrate loadings increased, and its coefficient (g biomass/g substrate) varied from 0.31 to 0.57 for toluene, 0.29 to 0.57 for styrene, 0.08 to 0.56 for MEK, and 0.14 to 0.53 for MIBK.

Simultaneous Determination of Five Porphyrins in Human Urine and Plasma Using High Performance Liquid Chromatography-Tandem Mass Spectrometry

  • Hur, Yeoun;Tae, Sookil;Koh, Yun-Joo;Hong, Sung-Hyun;Yoon, Young Ho;Jang, Haejong;Kim, Sooji;Kim, Kyeong Ho;Kang, Seung Woo;Lee, Youngshin;Han, Sang Beom
    • Mass Spectrometry Letters
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    • v.5 no.2
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    • pp.42-48
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    • 2014
  • A specific and sensitive liquid chromatography-electrospray ionization tandem mass spectrometry method (LC-ESI-MS/MS) was developed and validated for the simultaneous quantification of porphyrins (coproporphyrin, pentacarboxylporphyrin, hexacarboxylporphyrin, heptacarboxylporphyrin, and uroporphyrin) in human plasma and urine. Acidified plasma samples and urine samples were prepared by using liquid-liquid extraction using ethyl acetate and protein precipitation with acetonitrile, respectively. The separation was achieved onto a Synergi Fusion RP column ($150mm{\times}2.0mm$, $4{\mu}m$) with a gradient elution of mobile phase A (0.1% formic acid in 2 mmol/L ammonium acetate, v/v) and mobile phase B (20% methanol in acetonitrile, v/v) at a flow rate of $450{\mu}L$/min. Porphyrins and the internal standard (IS), coproporphyrin I-$^{15}N_4$, were detected by a tandem mass spectrometer equipped with an electrospray ion source operating in positive ion mode. Multiple reaction monitoring (MRM) transitions of the protonated precursor ions and the related product ions were optimized to increase selectivity and sensitivity. The proposed method was validated by assessing selectivity, linearity, limit of quantification (LOQ), precision, accuracy, recovery, and stability. The calibration curves were obtained in the range of 0.1-100 nmol/L and the LOQs were estimated as 0.1 nmol/L for all porphyrins. Results obtained from the validation study of porphyrins showed good accuracy, precision, recovery, and stability. Finally, the proposed method was successfully applied to clinical studies on the autism spectrum disorder (ASD) diagnosis of 203 Korean children.

Web-based Obesity Prevention and Management System Using a Body Variation (신체 변화량을 이용한 웹 기반 비만 예방·관리 시스템)

  • He, Yi-Lun;Kang, Hee-beom;Jung, Hoe-kyung
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.6
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    • pp.1189-1194
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    • 2016
  • While increasing the convenience of life is a high population BMI (Body Mass Index) is increasing rapidly. Accordingly, the development of the monitoring system to manage and prevent obesity is the time that is required. But most of the monitoring system, the less information it receives management and show to have only simple information calculated this was a low efficiency problem. Also Users with normal and disease Management accuracy is low. In this paper shows the user in a graph of Body Mass Index, BMR (Basal metabolic rate) divided by grade increased accuracy for users to manage their own. Also represented by recovery with exercise machines you used, select a balanced movement mechanism, expressed as a Kcal consumption. If the graph recent data show only increased the visibility. We developed an efficient web-based monitoring system for design a exercise plan.

A rapid separation of Cs, Sr and Ba using gas pressurized extraction chromatography with inductively coupled plasma-mass spectrometry

  • Sojin Jeong;Jihye Kim;Hanul Cho;Hwakyeung Jeong;Byungman Kang;Sang Ho Lim
    • Analytical Science and Technology
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    • v.37 no.2
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    • pp.123-129
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    • 2024
  • We present a rapid method for the determination of Cs, Sr, and Ba, heat generators found in highly active liquid wastes, by gas-pressurized extraction chromatography (GPEC) using a column containing a cation-exchange resin. GPEC is a microscale column chromatographic technique that uses a constant flow rate of solvent (0.07 mL/min) with pressurized nitrogen gas supplied through a valve. In particular, because this method uses a small sample volume (a few hundred microliters), it produces less chemical waste and allows for faster separation compared to traditional column chromatography. In this study, we evaluated the separation of Cs, Sr, and Ba using GPEC. The eluate from the column (GPEC or conventional column chromatography) was quantitatively analyzed using inductively coupled plasma-mass spectrometry to measure the column recovery and precision. The column reproducibility of the proposed GPEC system (RSDs of recoveries) ranged from 2.7 to 4.1 %, and the column recoveries for the three elements ranged from 72 to 98% when aqueous HCl was used as the eluent. The GPEC results are slightly different in efficiency and separation resolution compared to those of conventional column chromatography because of the differences in the eluent flow rate as well as the internal diameter and length of the column. However, the two methods had similar recoveries for Cs and Sr, and the precision of GPEC was improved by two-fold. Remarkably, the solvent volume required for GPEC analysis was five times lower than that of the conventional method, and the total analysis time was 11 times shorter.

Determination of Ceftiofur in Bovine Serum by liquid Chromatography-Electrospray Mass Spectrometry (액체크로마토그래프/질량분석기를 이용한 소의 혈청 중 Ceftiofur의 분석)

  • Lim, Jong-hwan;Jang, Beon-su;Park, Byung-kwon;Yun, Hyo-in
    • Korean Journal of Veterinary Research
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    • v.43 no.3
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    • pp.429-433
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    • 2003
  • This study was aimed to develop a more rapid, simple and sensitive method to determine ceftiofur in bovine serum using LC/MS with electrospray interface. Separation was achieved on the Nova-Pak $C_{18}$ reverse phase column. The mobile phase consisted of 0.1% acetic add in water (A) and acetonitrile (B) and gradiently flowed at the rate of 0.4 mL/min. As a result of analysis of blank muscle samples, matrix interference was not shown. Limit of detection and limit of quantitaion was 5 ng/g and 20 ng/g, respectively. The values of precision and recovery satisfied the guideline of NVRQS. The precision and recovery developed in this method are suitable and sensitive to determine the concentration of ceftiofur in the bovine serum. These results could be applied for the confirmation and quantification in the biofluid.