• Title/Summary/Keyword: mass fraction

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Synthesis of titania nanopowder and its photocatalytic properties

  • Jang, Hee-Dong;Lee, Jae-Chun;Kil, Dae-Sup
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.569-572
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    • 2003
  • Titanium dioxide ($TiO_2$) nanoparticles were prepared by the oxidation of titanium tetrachloride ($TiCl_4$) in a diffusion flame reactor. The average diameter of particles was 15 to 30 nm and mass fraction of anatase ranged from $40\;to\;80\%$. Effects of particle size and phase composition of those $TiO_2$ nanoparticles on photocatalytic properties such as decomposition of methylene blue and bacteria gas were investigated. The degree of decomposition of methylene blue by the $TiO_2$ nanoparticles under the illumination of the black light was directly proportional to the anantase mass fraction, but inversely to the particle size. The decomposition of bacteria by the $TiO_2$ nanoparticles under the illumination of the fluorescent light showed the same trend as in the case of the methylene blue.

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Screening of Inhibitory Effect of Edible Mushrooms on Tyrosinase and Isolation of Active Component (한국산 식용버섯류의 Tyrosinase 활성 저해 검색 및 그 유효성분 분리)

  • 박영현;장성근
    • Journal of Food Hygiene and Safety
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    • v.12 no.3
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    • pp.195-199
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    • 1997
  • For the purpose of isolation and screening of tyrosinase inhibitory activity from edible mushrooms, Pleurotus ostreatus, Auricularia auricula-Judae, Umbilicaria esculenta, Agaricus bisporus, Flammuline velutipes, Lentinus edodes, Ganoderma lucidum, and Coriouls versicolor were examined by tracing inhibitory activities against tyrosinase, utilizing L-3,4-dihydroxyphenylalanine (L-DOPA) as a substrate. Among the eight edible mushrooms tested, Umbilicaria esculenta showed potent enzyme inhibitory activities above 7804% against tyrosinase in ethylacetate (EtOAc) extracts. Ganoderma lucidum and Agaricus bisporus showed inhibitory activities of 67.3% and 51.5% in water extracts. EtOAc extracts of Umbilicaria esculenta was fractionated from silicagel column chromatography and one fraction showed the most inhibitory activity of 60.9%. The three bands (Rf=0.38, 0.27, 0.19) were isolated from preparative TLC of the fraction for purification and identified as mixtures of orsellinate, methyl orsellinate, methyl lecanorate, and methyl gyrophorate by high pressure liquid chromatography (HPLC), ultravisible spectrophotometer (UV), mass spectrophotometer (Mass), nuclear magnetic resonance spectrometer (NMR).

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An Experimental Study of the Effect of Flow on Flame Propagation in a Constant-Volume Combustion Chamber (정적연소기내 유동형태가 화염전파에 미치는 영향 연구)

  • Jeong, D.S.;Oh, S.M.;Suh, S.W.;Chang, Y.J.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.2
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    • pp.136-145
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    • 1995
  • The aim of this study is to gain a better understanding of the effect of a flow motion on the flame development by means of an optically-accessible constant-volume combustion chamber and the visualization technique of a combustion flame. At first, the characteristics of a flame propagation are investigated in the combustion field of the two kinds of flow conditions such as a quiescent and a flowing condition, and methane-air mixture is used as fuel. Then the same investigation is performed in two flow configurations : bulk flow motion type and turbulence generating type. In this study, the combustion phenomena are analyzed by measuring the combustion pressure, flame propagation speed, mean velocity, turbulent intensity, and mass fraction burned.

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A Study on the Normal Combustion and Abnormal Combustion in Automotive S.I.Engine (Knocking Phenomena in Quiscent or Swirl Flow Field) (자동차용 가솔린 기관의 정상연소 및 이상연소에 관한 연구)

  • Lee, K.W.;Fujimoto, H.;Park, K.S.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.6
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    • pp.250-261
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    • 1995
  • In this study, a rapid compression and expansion machine(RCEM) equipped with a swirl generator was designed and developed, in order to clarify normal and abnormal combustion(knocking phenomena). This RCEM is intended to simulate combustion process in actual automotive S.I.engines, having a high reproducibility in the compression stroke. Flame propagation and autoignition processes associated with normal and abnormal combustion were captured by the high speed schlieren photography. And swirl intensity. equivalence ratio and ignition position were varied to investigate the effect of turbulence, concentration in the unburnt gas region and flame propagation length. The knock intensity, knock mass fraction and knock mass fraction after autoignition were calculated by use of history of measured cylinder pressure.

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Kinetics analysis of energetic material using isothermal DSC (등온 DSC를 이용한 고에너지 물질의 정밀 반응 모델 기법 개발)

  • Kim, Yoocheon;Park, Jungsu;Kwon, Kuktae;Yoh, Jai-ick
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.219-222
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    • 2015
  • The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The frequency factor and activation energy are extracted as a function of product mass fraction. The extracted kinetic scheme does not assume multiple chemical steps to describe the response of energetic materials; instead, multiple set of Arrhenius factors are used in describing a single global step. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

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Sterol Compositions in Three Solanaceous Seed Oils (3종(種)의 가지과식물종자유중(料植物種子油中)의 Sterol 조성(組成))

  • Jeong, Tae-Myoung;Yang, Min-Suk;Nah, Hyo-Hwan
    • Applied Biological Chemistry
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    • v.21 no.1
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    • pp.51-57
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    • 1978
  • Sterol compositions of three solanaceous plant seed oils i.e., tobacco(Nicotiana tabacum L.), datura (Datura stramonium L.) and Chinese lycium (Lycium chinense Mill.) were analyzed by thin layer chromatography, gas liquid chromatography and gas liquid chromatography-mass spectrometry. Cholesterol, cholest-7-enol, campesterol, 24-methylenecholesterol, stigmasterol, sitosterol, and 28-isofucosterot were identified in 4-des-methylsterol fraction. 31-Norlanost-8-enol, $4{\alpha}$-methylcholest-8-enol, lophenol, 31-norlanosterol, obtusifoliol, 31-norcycloartenol, cyloeucalenol, gramisterol (24-methylenelophenol), and citrostadienol in 4-monomethylsterol fraction, and lanost-8-enol, cycloartanol, lanosterol, ${\beta}$-amyrin, 24-methylenelanost-8-enol, cycloartenol, lupeol and 24-methylenecycloartanol in 4,4-dimethylsterol fraction were identified respectively.

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AUGMENTING WFIRST MICROLENSING WITH A GROUND-BASED TELESCOPE NETWORK

  • ZHU, WEI;GOULD, ANDREW
    • Journal of The Korean Astronomical Society
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    • v.49 no.3
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    • pp.93-107
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    • 2016
  • Augmenting the Wide Field Infrared Survey Telescope (WFIRST) microlensing campaigns with intensive observations from a ground-based network of wide-field survey telescopes would have several major advantages. First, it would enable full two-dimensional (2-D) vector microlens parallax measurements for a substantial fraction of low-mass lenses as well as planetary and binary events that show caustic crossing features. For a significant fraction of the free-floating planet (FFP) events and all caustic-crossing planetary/binary events, these 2-D parallax measurements directly lead to complete solutions (mass, distance, transverse velocity) of the lens object (or lens system). For even more events, the complementary ground-based observations will yield 1-D parallax measurements. Together with the 1-D parallaxes from WFIRST alone, they can probe the entire mass range M ≳ M. For luminous lenses, such 1-D parallax measurements can be promoted to complete solutions (mass, distance, transverse velocity) by high-resolution imaging. This would provide crucial information not only about the hosts of planets and other lenses, but also enable a much more precise Galactic model. Other benefits of such a survey include improved understanding of binaries (particularly with low mass primaries), and sensitivity to distant ice-giant and gas-giant companions of WFIRST lenses that cannot be detected by WFIRST itself due to its restricted observing windows. Existing ground-based microlensing surveys can be employed if WFIRST is pointed at lower-extinction fields than is currently envisaged. This would come at some cost to the event rate. Therefore the benefits of improved characterization of lenses must be weighed against these costs.

A Study on the Source Apportionment of the Atmospheric Fine Particles in Jeju area (제주지역 미세먼지의 오염원 규명에 관한 연구)

  • Hu, Chul-Goo;Yang, Su-Mi;Lee, Ki-Ho
    • Journal of Environmental Science International
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    • v.12 no.2
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    • pp.217-225
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    • 2003
  • Samples of size-fractionated PM10 (airborne particulate matter with aerodynamic diameter less than $10\mu\textrm{m}$) were collected at an urban site in Jeju city from May to September 2002. The mass concentration and chemical composition of the samples were measured. The data sets were then applied to the CMB receptor model to estimate the source contribution of PM10 in Jeju area. The average PM10 mass concentration was 28.80$\mu\textrm{g}/m^3$ ($24.6~33.49\mu\textrm{g}/m^3$), and the FP (fine particle with aerodynamic diameter less than $2.l\mu\textrm{m}$ fraction in PM10 was approximately 8% higher than the CP (coarse particle with aerodynamic diameter greater than $2.l\mu\textrm{m}$ and less than $10\mu\textrm{m}$ fraction in PM10. The CP composition was obviously different from the FP composition, that is, the most abundant water soluble species was nitrate ion in the FP, but sulfate ion in the CP. Also sulfur was the most dominant element in the FP, however, sodium was that in the CP. From CMB receptor model results, it was found that road dust was the largest contributor to the CP mass concentration (45% of the CP) and ammonium nitrate, domestic boiler, and marine aerosol were major sources to the CP mass. However, the secondary aerosol was the most significant contributor to the FP mass concentration (45% of the FP). In this study, it was suggested that the contributions of soil dust and gasoline vehicle became very low due to collinearity with road dust and diesel vehicle, respectively.

Studies on the Volatile Flavor Components of Fresh Ginseng (수삼중 휘발성 향기성분에 관한 연구)

  • 김만욱;박종대
    • Journal of Ginseng Research
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    • v.8 no.1
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    • pp.22-31
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    • 1984
  • Volatile flavor components of fresh ginseng (Panax ginseng C.A. Meyer.) were studied. Steam distillate of fresh ginseng was extracted with ethyl ether and the extract was separated into four fraction: neutral, phenolic, acidic and basis fractions. The ethyl ether concentrates and neutral fraction were analyzed by a combination of SE-54 fused silica capillary gas chromatography and mass spectrometry. Major flavor components of fresh ginseng were predominantly mono(n +2) and sesquiterpenes(n +3) in over two hundred constituents. Of these, 28 were newly identified in volatile flavor components of fresh ginseng by GC-MS.

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Studies on the Components of the Seeds of Phaseolus radiatus (녹두의 성분연구)

  • Shin, Soon-Hee;Kang, Sam-Sik;Kwon, Kyung-Sook
    • YAKHAK HOEJI
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    • v.34 no.4
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    • pp.282-286
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    • 1990
  • An hydrocarbon alcohol and steroids were isolated from the hexane fraction of the extract from the seeds of Phaseolus radiatus L. And also a flavonoid was identified from the ethyl acetate and butanol fraction. The structure of the obtained compound were elucidated by spectroscopic methods (UV, IR, mass and NMR) and their physicochemical properties. As the results, triacontanol, stigmasterol, ${\beta}-sitosterol$ and vitexin were identified.

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