• Title/Summary/Keyword: mass formula

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Oxovanadium(IV) Complexes Containing VO(ONS) Basic Core: Synthesis, Structure, and Spectroscopic Properties

  • Jang, Yoon-Jung;Lee, Uk;Koo, Bon-Kweon
    • Bulletin of the Korean Chemical Society
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    • v.26 no.1
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    • pp.72-76
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    • 2005
  • Some mononuclear oxovanadium(IV) complexes having the general formula [VOL(bidentate)] (1-4) of which L is tridentate ONS-donor salicylaldehyde S-methyldithiocarbazate (sal-mdtc$^{2-}$) or salicylaldehyde 4- phenylthiosemicarbazate (sal-phtsc$^{2-}$) and bidentate stands for 2,2'-bipyridyl (bpy) or 1,10-phenanthroline (phen) have been synthesized. The complexes were characterized by elemental analyses, FAB mass, UV, IR spectroscopy, and cyclic voltammetry. Two of the complexes [VO(sal-mdtc)(bpy)] (1) and [VO(sal-mdtc) (phen)] (2) were crystallographically characterized. The structures revealed that vanadium atom is octahedrally coordinated by the O, N, and S donor atoms of the tridentate ligand, the two N atoms of bidentate ligand, and the oxo atom. The oxygen donor, occupying an apical position has a trans-labilizing effect, resulting in elongation of the V-N bond. The cyclic voltammograms of the complexes exhibited one cathodic response in the range −d1.45 $\sim$ −f1.52 V due to the reduction of V(IV) to V(III).

Dynamic Characteristics of a System Composed of a Supporting Structure and Subsystems (지지구조물과 부시스템으로 이루어진 계의 동적 특성)

  • Lee, Gun-Myung
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.26 no.4
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    • pp.406-411
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    • 2016
  • The natural frequencies and mode shapes of a system composed of subsystems on a supporting structure have been derived approximately. The system is modeled as a discrete system, and it is assumed that the masses of subsystems are much smaller than the mass of a supporting structure. It has been found that the fundamental frequency corresponds to the supporting structure, and each higher frequency corresponds to each subsystem. A relation between the vibration amplitudes of the supporting structure and subsystems is also derived for the case when the supporting structure is excited by a harmonic force.

Feeding and Nutritional Status of Elderly Patients receiving Enteral Tube Feeding (경관급식 노인 환자의 영양공급실태와 영양상태 평가)

  • Yoon, Hwa-Young;Kim, Hye-Kyeong
    • The Korean Journal of Food And Nutrition
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    • v.31 no.1
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    • pp.52-61
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    • 2018
  • The purpose of this study is to examine the feeding and nutritional status of enteral tube-fed elderly patients. Subjects included 77 elderly hospitalized patients who had received enteral nutrition more than one week before admission. Medical records on admission and actual feeding volume were used to assess anthropometric, biochemical, and nutritional status. Most patients manifested disorders of the nervous system (93.5%) and the average duration of tube feeding was 13.9 months. The average feeding volume of formula was 1,107 mL per day and the mean ratios of calorie and protein (supplied vs. required) were 81.7% and 80.9%, respectively. At admission, 57.4% of the patients were malnourished according to the institutional criteria. Patients receiving less than 80% of the required calories were in worse nutritional status compared with those receiving more than 80% of the required calories. Body mass index, percent ideal body weight, serum albumin level and blood lipid levels (total cholesterol, HDL-cholesterol, triglyceride) were significantly lower in patients receiving less than 80% of the required calories. These results indicate the high prevalence of malnutrition and the need for increased attention and nutritional care of elderly patients undergoing long-term enteral nutrition.

Response modification factor of mixed structures

  • Fanaie, Nader;Shamlou, Shahab O.
    • Steel and Composite Structures
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    • v.19 no.6
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    • pp.1449-1466
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    • 2015
  • Mixed structures consist of two parts: a lower part and an upper part. The lower part is usually made of concrete while the upper part is made of steel. Analyzing these structures is complicated and code-based design of them has many associated problems. In this research, the seismic behavior of mixed structures which have reinforced concrete frames and shear walls in their lower storeys and steel frames with bracing in their upper storeys were studied. For this purpose, seventeen structures in three groups of 5, 9 and 15 storey structures with different numbers of concrete and steel storeys were designed. Static pushover analysis, linear dynamic analysis and incremental dynamic analysis (IDA) using 15 earthquake records were performed by OpenSees software. Seismic parameters such as period, response modification factor and ductility factor were then obtained for the mixed (hybrid) structures using more than 4600 nonlinear dynamic analysis and used in the regression analysis for achieving proper formula. Finally, some formulas, effective in designing such structures, are presented for the mentioned parameters. According to the results obtained from this research, the response modification factor values of mixed structures are lower compared to those of steel or concrete ones with the same heights. This fact might be due to the irregularities of stiffness, mass, etc., at different heights of the structure. It should be mentioned that for the first time, the performance and seismic response of such structures were studied against real earthquake accelerations using nonlinear dynamic analysis, andresponse modification factor was obtained by IDA.

Numerical Analysis of Convective Heat and Mass Transfer around Human Body under Strong Wind

  • Li, Cong;Ito, Kazuhide
    • International Journal of High-Rise Buildings
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    • v.1 no.2
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    • pp.107-116
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    • 2012
  • The overarching objective of this study is to predict the convective heat transfer around a human body under forced strong airflow conditions assuming a strong wind blowing through high-rise buildings or an air shower system in an enclosed space. In this study, computational fluid dynamics (CFD) analyses of the flow field and temperature distributions around a human body were carried out to estimate the convective heat transfer coefficient for a whole human body assuming adult male geometry under forced convective airflow conditions between 15 m/s and 25 m/s. A total of 45 CFD analyses were analyzed with boundary conditions that included differences in the air velocity, wind direction and turbulence intensity. In the case of approach air velocity $U_{in}=25m/s$ and turbulent intensity TI = 10%, average convective heat transfer coefficient was estimated at approximately $100W/m^2/K$ for the whole body, and strong dependence on air velocity and turbulence intensity was confirmed. Finally, the formula for the mean convective heat transfer coefficient as a function of approaching average velocity and turbulence intensity was approximated by using the concept of equivalent steady wind speed ($U_{eq}$).

A Study on the Classification of Health Food Circulated in the Market -Surveyed on Mass Media and Internet- (시중에서 유통되는 건강식품의 종류에 관한 연구 -매스미디어와 인터넷 미디어를 중심으로-)

  • Son, Suk-Mi;Park, Jin-Gyeong
    • Journal of the Korean Dietetic Association
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    • v.10 no.1
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    • pp.58-64
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    • 2004
  • This study was performed to investigate the kinds of health food advertised and sold through media like printed matter, TV broadcasting or internet. It was found that fifty three percent of the health food was circulated through internet, 27% through printed matter, 9% through TV Broadcasting. When the health foods was classified, the proportion of special purpose nutritious foods was 36.1%, health aid foods 33.9%, uncooked powdered foods 18.5%, functional foods for health 4.9%, Ginseng products 3.9%, and tea 0.9%. The special purpose nutritious foods was composed of 59% of nutrition supplementary foods, 24% of dietary fiber foods, 9% of weaning foods, 7% of milk formula and 2% of HCA. Vegetable extracts occupied 21.1% of health aid foods, yeast 7.5%, mushroom extracts 7.0%, chitosan 6.2%, aloe 5.3%. Dried powdered type health food occupied the highest proportion. The other type were capsule(18.8%), tablet(18.1%), and liquid type(16.4%). When the health food was classified with health claim, the proportion of "nutrition supplementation" was the highest (23.9%), "diet" 14.9%, "ergogenic"(18.8%), "promoting bowel movement" 7.8%, "growth" 5.7%, "regulation of blood sugar" 4.5%, "improving of immunity"(2.4%) and anti-aging effect(2.4%).

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Comparison of Predicted and Measured Resting Energy Expenditure in Overweight and Obese Korean Women (한국 과체중 및 비만 여성의 휴식대사량 측정 및 예측값의 비교)

  • Park, Ji-Sook;Yim, Jung-Eun
    • Korean Journal of Community Nutrition
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    • v.23 no.5
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    • pp.424-430
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    • 2018
  • Objectives: The purpose of this study was to compare predictions and measurements of the resting energy expenditure (REE) of overweight and obese adult women in Korea. Methods: The subjects included 65 overweight or obese adult women ranging in age from 20~60 with a recorded body mass index (BMI) of 23 or higher. Their height, weight, waist-hip ratio, and blood pressure were measured. The investigator also measured their body fat, body fat percentage, and body composition of total weight without fat using Dual energy X-ray absorptiometry (DXA) and measured resting energy expenditure by indirect calorimetry. Measured resting energy expenditures were compared with predictions from six methods: Harris-Benedict, Mifflin, Owen, WHO-WH, Henry-WH, and KDRI. Results: Harris-Benedict predictions showed the smallest differences from measured resting energy expenditure at an accurate prediction rate of 70%. The study analyzed regression between measured resting energy expenditure and body measurements including height, weight and age. The formula proposed by this research is as follows: Proposed REE equation for overweight and obese Korean women = $721-(1.5{\times}age)+(0.4{\times}height)+(9.9{\times}weight)$. Conclusions: These findings suggest that age is a significant variable when predicting resting energy expenditure in overweight and obese women. Therefore, prediction of resting energy expenditure should consider age when determining energy requirements in overweight and obese women.

A Study on the Improvement of Classification of Explosion Hazardous Area using Hypothetic Volume through Release Characteristic (누출특성을 통한 폭발위험장소 선정방법의 개선에 대한 연구)

  • Kim, Dae-Yeon;Chon, Young-Woo;Lee, Ik-Mo;Hwang, Yong-Woo
    • Journal of the Korea Safety Management & Science
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    • v.19 no.2
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    • pp.31-39
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    • 2017
  • Classify of explosion hazardous areas must be made at the site where flammable materials are used. This reason is that it is necessary to manage ignition sources in of explosion hazardous areas in order to reduce the risk of explosion. If such an explosion hazard area is widened, it becomes difficult to increase the number of ignition sources to be managed. The method using the virtual volume currently used is much wider than the result using CFD(Computational Fluid Dynamics). Therefore, we tried to improve the current method to compare with the new method using leakage characteristics. The result is a realistic explosion hazard if the light gas is calibrated to the mass and the heavy gas is calibrated to the lower explosion limit. However, it is considered that the safety factors should be taken into account in the calculated correction formula because such a problem should be considered as a buffer for safety.

Isolation and Structural Determination of Aldose Reductase Inhibitor from Korean Fermented Soybean Paste

  • Choi, Sung-Won;Yang, Jae-Sung;Jung, Eun-A;Choi, Hak-Jong;Lee, Han-Seung;Shin, Chul-Soo;Kim, Dong-Seob;Hur, Nam-Yun;Baik, Moo-Yeol
    • Food Science and Biotechnology
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    • v.14 no.3
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    • pp.344-349
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    • 2005
  • Aldose reductase catalyzes the conversion of glucose into sorbitol. Inhibiting this enzyme in diabetes mellitus can delay or prevent pathogenic process. Aldose reductase inhibitor was screened from Korean fermented soybean pastes (Doen-jang) and purified via sequential processes of ethanol extraction, HP-20 column chromatography, ethyl acetate extraction, silica gel column chromatography, and crystallization. Aldose reductase inhibitor was identified as genistein with molecular weight of 270 Da and molecular formula of $C_{15}H_{10}O_5$ based on UV spectrometry, $^1H$ and $^{13}C\;NMRs$, and mass spectrometry. Genistein inhibited aldose reductase of pig lens with $IC_{50}$ level of $20\;{\mu}M$. Because genistein was effective against aldose reductase of animal source, it may be a potential therapeutic agent for diabetic complications.

Experimental Method for the Identification of the Propeller Blade Vibration Characteristics (프로펠러 날개의 진동특성에 대한 실험적 연구)

  • Lee, Hyun-Yup;Kim, Young-Joong;Nho, In-Sik;Lee, Chang-Sup
    • Journal of the Society of Naval Architects of Korea
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    • v.42 no.2 s.140
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    • pp.136-141
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    • 2005
  • An experiment method has been developed to analyse the vibration characteristics of marine propeller blades, and vibration tests have been carried out on the model scale propeller in air and in water. The driving point transfer function(acceleration/excitation force) has been measured and modified by compensating the attachment effect of the impedance head. The measured natural frequencies in air have been compared with the theoretical results by an in-house FEM code PROSTEC. The added masses have been derived by comparing the measured natural frequencies in air and in water, and the results have been compared to the results using existing formula based on experience.