• Title/Summary/Keyword: mass balance method

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Purity Assessment of Organic Reference Materials with a Mass Balance Method: A Case Study of Endosulfan-II

  • Kim, Seung-Hyun;Lee, Joonhee;Ahn, Seonghee;Song, Young-Sin;Kim, Dong-Kyum;Kim, Byungjoo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.531-538
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    • 2013
  • A mass balance method established in this laboratory was applied to determine the purity of an endosulfan-II pure substance. Gas chromatography-flame ionization detector (GC-FID) was used to measure organic impurities. Total of 10 structurally related organic impurities were detected by GC-FID in the material. Water content was determined to be 0.187% by Karl-Fischer (K-F) coulometry with an oven-drying method. Non-volatile residual impurities was not detected by Thermal gravimetric analysis (TGA) within the detection limit of 0.04% (0.7 ${\mu}g$ in absolute amount). Residual solvents within the substance were determined to be 0.007% in the Endosulfan-II pure substance by running GC-FID after dissolving it with two solvents. The purity of the endosulfan-II was finally assigned to be ($99.17{\pm}0.14$)%. Details of the mass balance method including interpretation and evaluating uncertainties of results from each individual methods and the finally assayed purity were also described.

Maternal Changes of Body Composition and Energy Balance in Korean Lactating Women (한국인 수유부의 체조성 변화 및 에너지 평형)

  • 임현숙
    • Journal of Nutrition and Health
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    • v.29 no.8
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    • pp.899-907
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    • 1996
  • This study was conducted to examine how Korean women mange energy metabolism during lactation. Eighteen women recruited were healthy, had normal pregnancies and were required to breast-feed their babies exclusively for at least 12wks. During the study period, all subjects were visited and interviewed five times : 3d, 9d, 4wk, 8wk, and 12wk lactation. Body composition variables were analyzed by a bioelectrical impedance method, energy intakes were assessed by using the inventory-weighing method, energy expenditure were determined by recording daily activities, and milk energy output was investigated from the amount of milk production and the gross energy content of milk. The subjects consumed less energy than current recommended allowance all over the study period, but compatible with fairly adequate lactational performance. They responded the additional energy stress of lactation by enhancing metabolic efficiency, increasing energy intakes, reduction physical activities and mobilizing body reserves. Another finding in this study was that the reduction in body fat-free mass may be the one way that women meet the energy demands of lactation like the reduction in body fat mass. The results from this study suggest that current recommended additional energy need during lactation, 2.09MJ/d(500kcal/d), is too high for healthy Korean women. Our data also indicate that the changes of body composition and energy balance at earlier postpartum are extremely different from those at later periods.

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3D Simulation Study of Biped Robot Balance Using FPE Method (FPE 방식을 활용한 이족 로봇 균형 유지 3차원 시뮬레이션 연구)

  • Jang, Tae-ho;Kim, Youngshik;Ryu, Bong-Jo
    • Journal of Digital Contents Society
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    • v.19 no.4
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    • pp.815-819
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    • 2018
  • In this study, we investigate balance of a biped robot applying Foot Placement Estimator (FPE) in simulation. FPE method is used to determine a stable foot location for balancing the biped robot when an initial orientation of the robot body is statically unstable. In this case, the 6-DOF biped robot with point foot is modelled considering contact and friction between foot and the ground. For simulation, the mass of the robot is 1 kg assuming the center of robot mass (COM) is located at the center of the robot body. The height from the ground to the COM is 1 m. Robot balance is achieved applying stable foot locations calculated from FPE method using linear and angular velocities, and the height of the COM. The initially unstable angular postures, $5^{\circ}$ and $-5^{\circ}$, of the robot body are simulated. Simulation results confirm that the FPE method provides stable balance of the robot for all given unstable initial conditions.

Approximate Response of a Non-linear Vibration Isolation System Using the Harmonic Balance Method (하모닉 밸런스법을 이용한 비선형 진동절연 시스템의 근사적 응답)

  • Lee, Gun-Myung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.6
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    • pp.124-129
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    • 2018
  • A non-linear vibration isolation system which is composed of a non-linear spring and a linear damper was proposed in past research. When the support of the isolation system is excited harmonically, the response component of the isolation system mass at the excitation frequency has been calculated approximately using the harmonic balance method. The response was approximated by a single mode, and the result was compared with a numerical result which is assumed as an accurate one. Next, the response was approximated by two modes, and the result was compared with the former one.

Management of Spent Ion-Exchange Resins From Nuclear Power Plant by Blending Method

  • Kamaruzaman, Nursaidatul Syafadillah;Kessel, David S.;Kim, Chang-Lak
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.1
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    • pp.65-82
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    • 2018
  • With the significant increase in spent ion-exchange resin generation, to meet the requirements of Waste Acceptance Criteria (WAC) of the Wolsong disposal facility in Korea, blending is considered as a method for enhancing disposal options for intermediate level waste from nuclear reactors. A mass balance formula approach was used to enable blending process with an appropriate mixing ratio. As a result, it is estimated around 44.3% of high activity spent resins can be blended with the overall volume of low activity spent resins at a 1:7.18 conservative blending ratio. In contrast, the reduction of high activity spent resins is considered a positive solution in reducing the amount of spent resins stored. In an economic study, the blending process has been proven to lower the disposal cost by 10% compared to current APR1400 treatment. Prior to commencing use of this blending method in Korea, coordinated discussion, and safety and health assessment should be undertaken to investigate the feasibility of fitting this blending method to national policy as a means of waste predisposal processing and management in the future.

Effects of Upright Body Exercise on Postural Balance and Foot Plantar Pressure in Elderly Women

  • Kim, Chan-Hee;Lee, Joong-Sook;Yang, Jeong-Ok;Lee, Bom-Jin;Kim, Eui-Suk;Woo, Kyung-Hee;Park, Jin-Suk
    • Korean Journal of Applied Biomechanics
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    • v.27 no.1
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    • pp.59-66
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    • 2017
  • Objective: This study investigated the effect of a 16-week upright body exercise program on body balance and plantar pressure balance in elderly women. Method: The subjects included elderly women in B Metropolitan city who participated in an upright body exercise program twice weekly for 16 weeks. The subjects' physical characteristics (height, weight, body mass index [BMI]), posture balance, and foot plantar pressure were measured before and after the experiment. Results: The upright body exercise program showed positive changes in posture balance and foot plantar pressure balance in seven elderly women. Conclusion: The second version of the upright body exercise program improved and may prevent postural imbalance in elderly women. This program could be utilized to improve posture and foot balance in elderly persons.

Analysis of Factors Influencing Risk of Fallings among Rehabilitation Patients with Impaired of Mobility: Focusing on Activities-specific Balance Confidence (기동장애 재활환자의 낙상위험성 영향요인분석 -활동특이적 균형자신감을 중심으로-)

  • Han, Dongwook;Park, Kyung-Yeon
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.20 no.3
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    • pp.220-229
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    • 2013
  • Purpose: The purpose of the study was to investigate activities-specific balance confidence and risk of fallings among rehabilitation patients with impaired of mobility, and to identify the influence of activities-specific balance confidence on their risk of fallings. Method: Data for 132 rehabilitation patients were collected between October June 20 and August 20, 2012 at nine hospitals in a metropolitan city. Data were analyzed using t-test, ANOVA, Pearson correlation coefficient and stepwise multiple regression with SPSS/WIN 20.0. Result: The mean score for rehabilitation patients' activities-specific balance confidence was 40.18 out of a possible range of 0-100 and the mean score for risk of fallings among rehabilitation patients was 31.10 within a possible range of 0-125. Significant factors affecting the risk of fallings among the rehabilitation patients were 'activity level', 'dementia', 'body mass index', 'anxiety', and 'presence of a caregiver', which together explained 34.7% of the variance. The most significantly factor influencing rehabilitation patients' risk of fallings was activities-specific balance confidence which explained 23.5% of the variance. Conclusion: The study results indicate that activities-specific balance confidence as well as physical factors should be considered for interventions to decrease risk of fallings in rehabilitation patients with impaired mobility.

Analysis of Organic Molecular Markers in Atmospheric Fine Particulate Matter: Understanding the Impact of "Unknown" Point Sources on Chemical Mass Balance Models

  • Bae, Min-Suk;Schauer, James J.
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.3
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    • pp.219-236
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    • 2009
  • Particle-phase organic tracers (molecular markers) have been shown to be an effective method to assess and quantify the impact of sources of carbonaceous aerosols. These molecular markers have been used in chemical mass balance (CMB) models to apportion primary sources of organic aerosols in regions where the major organic aerosol source categories have been identified. As in the case of all CMB models, all important sources of the tracer compounds must be included in a Molecular Marker CMB (MM-CMB) model or the MMCMB model can be subject to biases. To this end, the application of the MM-CMB models to locations where reasonably accurate emissions inventory of organic aerosols are not available, should be performed with extreme caution. Of great concern is the potential presence of industrial point sources that emit carbonaceous aerosols and have not been well characterized or inventoried. The current study demonstrates that emissions from industrial point sources in the St. Louis, Missouri area can greatly bias molecular marker CMB models if their emissions are not correctly addressed. At a sampling site in the greater St. Louis Area, carbonaceous aerosols from industrial point sources were found to be important source of carbonaceous aerosols during specific time periods in addition to common urban sources (i.e. mobile sources, wood burning, and road dust). Since source profiles for these industrial sources have not been properly characterized, method to identify time periods when point sources are impacting a sampling site, needs to avoid obtaining biases source apportionment results. The use of real time air pollution measurements, along with molecular marker measurements, as a screening tool to identify when point sources are impacting a receptor site is presented.

Estimation of Optimum Capacity for Rainwater Storage Facilities based on Mass Balance and Economic Analysis (Mass-balance 및 경제성 분석에 의한 빗물저류시설 적정 규모 산정)

  • Kim, Youngmin;Lee, Sangho;Lee, Jung-Hun;Kim, Ree-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.2
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    • pp.233-238
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    • 2008
  • Recently, rainwater harvesting facilities have increasingly constructed mainly in elementary schools and government buildings. Nevertheless, few methods are available for efficient planning and design of rainwater harvesting facilities by considering the weather conditions and purpose of rainwater management in each site, which may lead to a construction of uneconomic facilities. The current method estimates the size of rainwater storage tank by multiplying the size of building or plottage with a certain ratio and has many limitations. In this study, we first developed a method for planning and design of rainwater storage facilities using $Rainstock^{TM}$ model, which is based on mass balance, and economic analysis. Then, the model was applied for the design of a rainwater harvesting facility in a building with the catchment area of $1,000m^2$. The model calculation indicated that the economic feasibility of rainwater harvesting depends on not only the size of storage tank but also the water usage rate. When the water usage rate is $1m^3/day$, the rainwater harvesting facility is not cost-effective regardless of the size of the storage tank. With increasing the water usage rate, the economical efficiency of the facility was improved for a specific size of the storage tank. Based on the model calculation, the optimum tank sizes for $5m^3/day$ and $10m^3/day$ of water usage rates were $24m^3$ and $57m^3$, respectively. It is expected that the model is useful for optimization of rainwater storage facilities in planning and designing steps.