• Journal of the Korean Society for Heat Treatment
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• v.11 no.2
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• pp.111-120
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• 1998

The effects of chemical composition and thermal cycling on the martensitic transformation characteristics in Cu-rich, equiatomic and Zr-rich CuZr binary alloys have been studied by calorimetry. Only martensite could be indentified in equiatomic $Cu_{49.9}Zr_{50.1}$ alloy, while $Cu_{10}Zr_7$ and $CuZr_2$ intermetallic compounds as well as martensite were formed by rapid cooling from the melts in Cu-rich $Cu_{52.2}Zr_{47.5}$ alloy and Zr-rich $Cu_{48.4}Zr_{51.6}$ alloy, respectively. The $M_s$ temperature of $Cu_{49.9}Zr_{50.1}$ was $156^{\circ}C$ but those of $Cu_{52.5}Zr_{47.5}$ and $Cu_{48.4}Zr_{51.6}$ alloys, being $109^{\circ}C$ and $138^{\circ}C$, were lower than that of equiatomic $Cu_{49.9}Zr_{50.1}$ alloy. In all the alloys, the $M_s$ temperature has fallen but the $A_s$ temperature has risen, resulting in widening of the transformation hysteresis with thermal cycling. The anomalous characteristics in the transformation temperature are due to the presence of the intermetallic compounds i.e. $Cu_{10}Zr_7$ and $CuZr_2$ formed by an eutectoid reaction during thermal cycling in the temperature range between $-100^{\circ}C$ < $T_c$ < $400^{\circ}C$.

• Korean Journal of Materials Research
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• v.2 no.6
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• pp.436-442
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• 1992

When $N_2$was used as shielding gas during the formation of Ti surface-alloyed layer by irradiation of $CO_2$laser beam on steel, TiN and F$e_2$Ti were formed regardness of carbon-content in steel. When Ti content was increased in low carbon-content steel, formation of martensitic structure was suppressed due to increase of critical cooling rate for martensitic transformation. In case of high-carbon steel, even though Ti content was about 1.5% in alloyed layer, hardness was increased by formation of martensitic structure instead of ferrite. In addition to that structure, hardness was incrreased further by precipitation of TiC in Ti alloyed-layer of high carbon-steel.

• Journal of Welding and Joining
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• v.17 no.6
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• pp.84-89
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• 1999

Most of ferrous b.c.c weld materials may experience martensitic transformation during rapid cooling after welding. It is well known that volume expansion due to the phase transformation could influence on the relaxation of welding residual stress. To apply this effect practically, it is a prerequisite to establish a numerical model which is able to estimate the effect of phase transformation on residual stress relaxation quantitatively. For this purpose, the analysis is carried out in two regions. i.e., heating and cooling, because the variation of material properties following a phase transformation in cooling is different in comparison with the case in heating, even at the same temperature. The variation of material properties following phase transformation is considered by the adjustment of specific heat and thermal expansion coefficient, and the distribution of residual stress in analysis is compared with that of experiment by previous study. consequently, in this study, simplified numerical procedures considering phase transformation, which based on a commercial finite element package was established through comparing with the experimental data of residual stress distribution by other researcher. To consider the phase transformation effect on residual stress relaxation, the transition of mechanical and thermal property such as thermal expansion coefficient and specific heat capacity was found by try and error method in this analysis.

• Proceedings of the KWS Conference
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• 2003.11a
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• pp.216-218
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• 2003

Most of ferrous b.c.c weld materials may experience martensitic transformation during rapid cooling after welding. And it is well known that volume expansion due to phase transformation could influence in the case of welding of high tensile strength steels on the relaxation of welding residual stress. To apply this effect practically, it is a prerequisite to establish a numerical model which is able to estimate the effect of phase transformation on residual stress relaxation quantitatively. In this study, we investigated the effect of phase transformation on the relaxation of welding residual stress through experiment. And three-dimensional thermal elastic-plastic FEM analysis is conducted to compare the effect of phase transformation on the relaxation of welding residual stress in high strength steels(POSTEN60, POSTEN80) with analytical results which is not considering the effect of phase transformation on residual stress relaxation. According to the results, the extents of welding residual stress relaxation due to phase transformation in the case of welding of POSTEN60, POSTEN80 are 0.85 $\sigma$/$\sigma$$\sub$Y0/, 0.75$\sigma$/$\sigma$$\sub$Y0/, respectively.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.5 s.176
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• pp.1352-1361
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• 2000

We obtain a micromechanics-based Helmholtz free energy and then in the framework of irreversible thermodynamics, a kinetic relation, a martensitic nucleation criterion and the reorientation criterion of martensitic variants are obtained. These relations are valid for a three-dimensional proportional and non-proportional loadings and for a combination of mechanical and thermal loading. From the simulated pseudoelastic stress-strain relation of a single crystal with loading rate effect, polycrystalline behavior in case of proportional and non-proportional loading is predicted by a homogenization method. The obtained results are compared quantitatively with experimental results.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.79-84
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• 2004

Strain energy due to the mechanical interaction between self-accommodation groups of martensitic phase transformation is called interaction energy. Evaluation of the interaction energy should be accurate since the energy appears in constitutive models for predicting the mechanical behavior of shape memory alloy. In this paper, the interaction energy is evaluated in terms of theoretical formulation and explicit finite element calculation. A simple example with two habit plane variants was considered. It was shown that the theoretical formulation assuming elastic interaction between the self-accommodation group and matrix gives larger interaction energy than explicit finite element calculation in which transformation softening is accounted for.

• Korean Journal of Materials Research
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• v.17 no.1
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• pp.37-42
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• 2007

The effects of immersion time in the liquid nitrogen and deformation-induced martensitic transformation on the behavior of austenite stainless steels used for the hydrogen storage tank of auto-mobile at cryogenic temperature were investigated. With increasing of immersion time in the liquid nitrogen, the tensile strength of all austenite stainless steels at cryogenic temperature was increased because the martensite transformation of unstable austenite. The restraint of crack generation ana transmission also increased the tensile strength by the active ${\alpha}'$ transformation. The elongation decreasing of 321 steel is not the mechanical deformation of austenite phase but the stress induced martensite phase during the tensile test.

• Journal of the Korean Ceramic Society
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• v.28 no.7
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• pp.549-555
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• 1991

Mullite-zirconia (0∼4 mol% yttria) composites were obtained by In-situ sintering of zircon and alumina mixture, and their mechanical properties were studied in conjuction with microstructure observation. Martensitic transformation temperature (Ms) of zirconia dispersed in the mullite matrix decreased with Y2O3 contents and was about 600$^{\circ}C$ for ZrO2 containing 4 mol% Y2O3. On cooling of this composites, tetragonal to monoclinic phase transformation induced microcracks at the grain boundary of mullite matrix. The microcracks seemed to absorb the fracture energy in stress field during mechanical tests. Therefore, toughening mechanisms of this composite were considered to nucleation and extension of microcrack, and crack deflection mechanism due to the difference of thermal expansion coefficient between matrix and dispersed phase.

• Smart Structures and Systems
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• v.16 no.1
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• pp.183-194
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• 2015

Shape memory alloy (SMA) helical springs have found a large number of different applications in industries including biomedical devices and actuators. According to the application of SMA springs in different actuators, they are usually under tension and torsion loadings. The ability of SMAs in recovering inelastic strains is due to martensitic phase transformation between austenite and martensite phases. Stress or temperature induced martensite transformation induced of SMAs is a remarkable property which makes SMA springs more superior in comparison with traditional springs. The present paper deals with the simulation of SMA helical spring at room temperature. Three-dimensional phenomenological constitutive model is used to describe superelastic behavior of helical spring. This constitutive model is implemented as a user subroutine through ABAQUS STANDARD (UMAT), and the process of the implementation is presented. Numerical results show that the developed constitutive model provides an appropriate approach to captures the general behavior of SMA helical springs.

• Journal of the Korean Society for Heat Treatment
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• v.3 no.4
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• pp.1-9
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• 1990

In this study, the ausformed martensite cooled to $-196^{\circ}C$ with various deformation degrees in Fe-30%Ni-0.24%C alloy was transformed to reversed austenite at $500^{\circ}C$ by cyclic reverse martensitic transformation. The effects of prior deformation and the number of cyclic reverse transformation on the microstructure and the mechanical properities of reversed anstensite were investigated. Experimental results showed that the strength of reversed austenite was higher than that of original austenite. This is due to higher dislocation density and grain refining. The reversed austenite formed from ausformed martensite was highly strengthened by prior deformation. This strengthening effect of reversed austenite is attributed to higher dislocation density than grain fefining. The yield strength of reversed austenite below 30% prior deformation, but above 30% prior deformation the strength of reversed austenite is lower than that of deformed austenite. This is due to partly disappearance of strain hardening effect at higher deformation degree by reverse transformation. The strength of reversed austenite is increased with the number of cyclic transformation. Especially, it is principally strengthened by the first cyclic transformation and shows higher increase in yield strength than that of ultimate tensile strength.