• Bulletin of the Korean Chemical Society
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• v.16 no.7
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• pp.634-641
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• 1995

The metal-carbon σ-bond cluster complexes 1-Mn(CO)5-2-R-1,2-C2B10H10 (R=CH3 Ia, C6H5 Ib) have been prepared in good yields from readily available carboranyl lithium complexes, 1-Li+-2-R-1,2-C2B10H10- (R=CH3, C6H5), by direct reaction with (CO)5MnBr. These manganese metal complexes are rapidly converted to the corresponding manganese metal carbene complexes, 1-[(CO)4Mn=C(OCH3)(CH3)]-2-R-1,2-C2B10H10 (R=CH3 IIIa, C6H5 IIIb), via alkylation with methyllithium followed by O-methylation with CF3SO3CH3. The crystal structure of IIIb was determined by X-ray diffraction. Thus, complex IIIb crystallizes in the orthorhombic space group P212121 with cell parameters a=15.5537(5), b=19.0697(5), c=7.4286(3) Å, V=2203.4(1) Å3, and Z=4. Of the reflections measured a total of 3805 unique reflections with F2>3σ(F2) was used during subsequent structure refinement. Refinement converged to R1=0.053 and R2=0.091. Structural studies showed that the manganese atom had a slightly distorted pseudo-octahedral configuration about the metal center with the carbene and ortho-carborane occupying the equatorial plane cis-orientation to each other.

• Mycobiology
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• v.49 no.5
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• pp.507-520
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• 2021

Papiliotrema huenov was previously reported to be highly tolerant of a range of extremely toxic heavy metals. This study aimed to identify the potential of P. huenov to remove manganese and copper from aqueous solution. Physical conditions which affect removal of Mn(II) and Cu(II) were determined. Optimal temperature for adsorption of both metal ions was 30 ℃, and optimal pH for maximum uptake of Mn(II) and Cu(II) were 5 and 6, respectively. Under these conditions, living cells of P. huenov accumulated up to 75.58% of 110 mg/L Mn(II) and 70.5% of 128 mg/L Cu(II) over 120 h, whereas, the removal efficiency of metal ions by dead cells over 1 h was 60.3% and 56.5%, respectively. These results indicate that living cells are more effective than dead biomass for bioremediation, but that greater time is required. The experimental data extends the potential use of P. huenov in biosorption and bioaccumulation of toxic heavy metals to copper and manganese, two of the most common industrial contaminants.

• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.483-486
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• 2021

Catalytic ozonation of methyl ethyl ketone (MEK) has been examined over mesoporous MnO_x/Al₂O₃ (MA) catalysts developed by a solvent deficient method using two different manganese precursors including manganese chloride (C) and manganese sulfate (S) at room temperature. The maximum catalytic activities of MA with C (MEK removal efficiency and ozone decomposition of 98.4 and 93.7%, respectively) were higher than those of MA with S (MEK removal efficiency and ozone decomposition of 96 and 68%, respectively). Also the catalytic stability of MA with C was much higher than that of MA with S. The physico-chemical properties of catalysts are well correlated with the activity results, which confirmed that fine dispersion of MnO_x species with high ratios of Mn³⁺/Mn⁴⁺ and more acid sites are attributed to the higher catalyst stability for the MA-C catalyst.

• Journal of the Society of Naval Architects of Korea
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• v.61 no.1
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• pp.61-67
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• 2024

A naval mine is an effective weapon system implemented for defending defends ports and seas. A mine is an underwater weapon that poses a great threat to ships sailing over the sea from shallow areas. Most of the influence-type naval mines detect magnetic field signals from ships and determine the final time of fire. Therefore, the level of underwater electro-magnetic signatures of ships is a key requirement for determining the survival of ships in wartime situations where mines are emplaced. The main reason why the high manganese steel is attracting attention for naval ship hulls is its nature as a non-magnetic steel. The non-magnetic hull does not generate electro-magnetic signatures; thus, it has the advantage improving the stealth of the ship. In this paper, I examine whether this material can be applied in the hulls material of naval ships that must be ableto reduce underwater electro-magnetic signatures by considering the non-magnetic characteristics of the first developed high manganese steel in the world.

• Korean Journal of Materials Research
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• v.12 no.11
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• pp.860-864
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• 2002

$Li^{+}$ extraction reactions with ion-exchange type lithium manganese oxide in an aqueous phase were examined using chemical and x-ray diffraction (XRD) analysis. In the process of extraction reaction, the lithium manganese oxide showed a topotactic extraction of $Li^{+ }$ in the aqueous phase mainly through an ion-exchange mechanism, and the $Li^{+}$ extracted samples indicated a high selectivity and a large capacity for $Li^{+}$ . The electronic structures and chemical bonding properties were also studied using a discrete variational (DV)-X$\alpha$ molecular orbital method with cluster model of (Li$Mn_{12}$ $O_{40}$ )$^{27-}$ for tetrahedral sites and ($Li_{7}$ Mn $O_{38}$ )$^{3}$ for octahedral site in $Li_{1.33}$ $Mn_{1.67}$ / $O_{4}$ respectively. Li in the manganese oxides is highly ionized in both sites, but the net charge of Li was greater for tetrahedral sites than octahedral. These calculations suggest that the tetrahedral sites have higher $Li^{+}$ $H^{+}$ exchangeability than the octahedral sites, and are preferable for the selective adsorption for L $i^{+}$ ions.s.

• Economic and Environmental Geology
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• v.23 no.2
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• pp.161-181
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• 1990

The lead-zinc-silver-iron deposits from the Janggun mine are of hydrothermal-metasomatic origin, characterized by the marked hydrothermal alteration of the wallrocks, such as hydrothermal manganese enrichment of carbonate rocks, silicification, chloritization, sericitization, montmorillonitization and argillic alteration. The ore deposits have been emplaced within the Janggun Limestone of Cambro-Ordovician age at the immediate contacts with apophyses injected from the Chunyang Granite plutons of Late Jurrasic age. They have been structurally controlled by fractures in the carbonate rocks and the irregular intrusive contacts of granitic rocks, and are closely associated with hypogene manganese carbonate deposits. In the mine nine seperate orebodies are being mined. On the basis of the petrological study, hydrothermal alteration zone of this mine may be divided into the following four zones from wallrock to orebody. (I) Primary calcite and dolomite zone${\rightarrow}$(II) dolomitic limestone zone${\rightarrow}$(III) dolomitic zone${\rightarrow}$(IV) rhodochrosite zone${\rightarrow}$ orebody. There was not recongnized Mn and Fe elements in the primary calcite and dolomite zone. But, in the dolomitic limestone and dolomite zone, calcite and dolomite were subjected to weak hydrothermal manganese enrichment and the grade of the manganese enrichment increase oreward. By means of electron probe microanalysis, it was found that manganoan dolomite occured between primary dolomite grains, cross the cleavage of the primary dolomite and around the dolomite grains. Above these result supports that the Janggun manganese carbonate deposits are of hydrothermal metasomatic origin.

• Journal of the Korean Chemical Society
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• v.48 no.1
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• pp.46-52
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• 2004

The effect of crystallinity on the structural stability of layered manganese oxide has been systematically investigated. While well-crystalline manganate was prepared by solid-state reaction-ion exchange method, nanocrystalline one was obtained by Chimie-Douce reaction at room temperature. According to micro-Raman and Mn K-edge X-ray absorption spectroscopic results, manganese ions in both the manganese oxides are stabilized in the octahedral sites of the layered lattice consisting of edge-shared MnO6 octahedra. The differential potential plot clarifies that the layered structure of nanocrystalline material is well maintained during electrochemical cycling, in contrast to the well-crystalline homologue. From the micro-Raman results, it was found that delithiation-relithiation process for well-crystalline material gives rise to the structural transition from layered to spinel-type structure. On the basis of the present experimental findings, it can be concluded that nanocrystalline nature plays an important role in enhancing the structural stability of layered manganese oxides.

• Journal of Environmental Health Sciences
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• v.21 no.2
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• pp.54-67
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• 1995

The biosynthesis of galactolipid and galactose and their composition of fatty acid in E. coli and B. subtilis treated ] with copper chloride (10 ppm), nickel chloride (50 ppm), manganese chloride (100 ppm) during the culture were analyzed. The contents of MGDG, DGDG and total lipids in treatment with metal compounds were lower to compared with the control. In E. coli, the major fatty acid unitized for biosyntheis of MGDG were palimitic acid (ave. 36.87%) and linolenic acid (ave. 14.79%) in control. In MGDG, the major fatty acids were utilized for palmitic acid (ave. 20.00%) and myristic acid (ave. 7.32%) in treatment with copper chloride, lauric acid (ave. 11.71%) and linolenic acid (ave. 11.06%) in manganese chloride treatment. And in nickel chloride treatment, it was palmitic acid (ave. 36.16%) and oleic acid (ave. 6.43%) were use in MGDG formation. In DGDG, in copper chloride treatment, it was lauric acid (ave. 19.41%) and oleic acid (ave. 9.95%) in biosynthesis of galactolipid. and in treatment with nickel chloride linolenic acid (ave. 15.39%) and linoleic acid (ave. 13.51%), in manganese chloride treatment palmitic acid (ave. 29.76%) and palmitoleic acid (ave. 11.35%) were used in DGDG formation. In B. subtilis, the major fatty acids utilized for biosynthesis of galactolipid was palmitic acid (ave. 30.86%) and linolenic acid (ave. 8.36%) in control. Otherwise, in MGDG, the major fatty acids were utilized for palmitic acid (ave. 28.92%) and stearic acid (ave. 13.25%) in treatment with copper chloride, and palmitic acid (ave. 15.73%) and lauric acid (ave. 11.88%) in manganese chloride treatment. It was continned that nickel chloride treatment was palmitic acid (ave. 35.16%) and palmitoleic acid (ave. 12.47%). The major fatty acids in DGDG were utilized for palmitic acid(ave. 34.19%) and linoleic acid (ave. 17.45%) in copper chloride treatment, and lauric acid (ave. 11.16%) and myrisitic acid (ave. 8.65%) in manganese chloride treatment. In treatment with nickel chloride, it was palmitoleic acid (ave. 10.30%) and myristic acid (ave. 7.81%) were used galactolipid formation.

• Applied Chemistry for Engineering
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• v.19 no.1
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• pp.66-72
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• 2008

Manganese hydrogen phosphate hydrate, $MnHPO_4{\cdot}2.25H_2O$, is a major constituent of the pre-conditioning compositions for the manganese phosphate coating treatment over carbon steel substrate. This compound is conventionally produced by the synthesis in the aqueous solution process followed by the filtration and drying processes and a series of size reduction and classification processes in dry state. However, it is evident that the conventional process is neither environment-friendly nor cost-effective. In this work, a new process principle was examined based on the controlled double-jet precipitation technology to produce the manganese chemical product of fairly uniform particle size distribution in an aqueous solution media. The effects of stabilizing agents were comparatively studied by the scanning electron microscope analysis in a uniformity point of view of the resulting particle size. Polyvinylpyrrolidone and Gum Arabic were excellent in controlling the crystal growth step, resulting in fairly uniform size distributions of the particles from the controlled double-jet process.

• Journal of Environmental Science International
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• v.1 no.2
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• pp.71-79
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• 1992

Selective extraction procedure has been used to quantify copper and cadmium In association with the various phases of aquatic sediment such as exchangeable/adsorbed, carbonate, manganese oxides, organic matter and iron oxides. Changes of pH influenced on the partitioning of copper in carbonate and exchangeable/ad- sorbed phases and of cadmium in carbonate phase of aquatic sediment. Addition of NTA and EDTA, copper and cadmium associated with carbonate phase were released from sediment to water. Total partitioning coefficient was 8.361 for copper and 0.497 for cadmium. The relative binding strengths of copper and cadmium to each solid phase can be ranked by using the partitioning coefficints. For copper it was observed that carbonate > organic matter > exchangeable/adsorbed > manganese oxides > iron oxides and for cadmiunm it was observed that exchangeable/adsorbed > carbonate > manganese oxides > organic matter > iron oxides.