• 폴리머
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• 제25권2호
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• pp.226-232
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• 2001

The properties of poly(ethylene terephthalate) (PET)/maleic anhydride-grafted polypropylene (MAgPP)/poly(styrene-co-maleic anhydride)(PScMA) ternary blend were investigated. The ternary blend was immiscible based on the glass transition temperatures measured by dynamic mechanical analyzer (DMA). The degradation of MAgPP during melt mixing for 30 min at 280$^{\circ}C$ did not affect the properties of the ternary blend. The interaction among the components was confirmed from the rheological properties, which was increased with the PSCMA contents. In terms of the mechanical properties, it was observed to satisfy the mixture rule for a multiple system.

• 한국산업융합학회 논문집
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• 제13권2호
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• pp.93-98
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• 2010

Polypropylene / montmorillonite / wood flour nanocomposites are melt-mixed by using a twin screw extruder. The montmorillonite is intercalated by the wood flour and the basal spacing of montmorillonite is increased with increasing the content of wood flour. The exfoliation constantly occurs by adding more than 10 wt.% of maleic anhydride-grafted polypropylene as the compatibilizer, which is used for improving the interfacial adhesion between matrix and filler. Also, the maleic anhydride-grafted polypropylene enhances the mechanical properties of the nanocomposites.

• Carbon letters
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• 제20권
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• pp.39-46
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• 2016

In this work, the effects of maleic anhydride (MA) content on mechanical properties of chopped carbon fibers (CFs)-reinforced MA-grafted-polypropylene (MAPP) matrix composites. A direct oxyfluorination on CF surfaces was applied to increase the interfacial strength between the CFs and MAPP matrix. The mechanical properties of the CFs/MAPP composites are likely to be different in terms of MA content. Surface characteristics were observed by scanning electron microscope, Fourier transform infrared spectroscopy, and single fiber contact angle method. The mechanical properties of the composites were also measured by a critical stress intensity factor (K_IC). From the K_IC test results, the K_IC values were increased to a maximum value of 3.4 MPa with the 0.1 % of MA in the PP, and then decreased with higher MA content.

• 대한토목학회논문집
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• 제31권2A호
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• pp.137-143
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• 2011

본 연구는 섬유보강 시멘트 모르타르에서 무수말레인산이 그라프트된 폴리프로필렌(maleic anhydride grafted polypropylene, mPP) 분말의 첨가가 무극성 마크로 합성섬유(마크로 합성섬유)의 부착특성에 미치는 효과를 평가하였다. 다양한 mPP의 첨가율(시멘트 중량의 0%, 5%, 10%, 15%, 20%, 25%, 30%)에 따른 시멘트 모르타르와 마크로 합성섬유의 부착거동을 평가하기 위하여 Dog-bone 부착시험을 수행하였다. 시멘트 모르타르내에서 마크로 합성섬유의 부착 특성(일반거동, 인발하중 및 계면인성)은 mPP의 사용량 증가할수록 증가하였다. 인발시험 후 마크로 합성섬유 표면의 미세구조 분석은 mPP의 첨가율에 따른 마찰 저항력을 평가하기 위하여 관찰하였다. mPP의 첨가율이 증가할수록 마크로 합성섬유 표면에 긁힘 현상이 증가하였다.

• Elastomers and Composites
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• 제47권2호
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• pp.162-167
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• 2012

거대분자의 표면개질은 고분자재료의 물성을 향상시키기 위한 점진적이고 바람직한 방안을 제공하며 고분자의 주요 물성을 손상시키지 않고 고분자 표면의 전도도, 젖음성, 안정성, 접착 및 항박테리아성 등을 개선시킨다. PE 또는 PP 등의 polyolefin을 관능성 단량체로서 MAH와 용액상에서 그래프트시켰다. FTIR측정을 통하여 그래프팅이 일어났음을 확인하였다. 그래프팅율은 화학적정에 의하여 결정하였다. MAH량이 많아질수록 접촉각은 낮은 값을 얻었다. 또한 MAH량이 증가함에 따라 polyolefin-g-MAH의 융점($T_m$)은 감소하는 한편 분해온도($T_d$)는 증가하는 경향을 보였다.

• Advances in materials Research
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• 제3권3호
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• pp.129-137
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• 2014

Biocomposites from polypropylene (PP) and corn cob (CC) were investigated. The effect of corn cob content and maleic anhydride polypropylene (MAPP) as compatibilizer were studied. Results showed that addition of corn cob (CC) in PP have decreased the tensile strength and elongation at break, whereas modulus of elasticity of biocomposites increased. The biocomposites with the MAPP as compatibilizer exhibited higher tensile strength and modulus of elasticity compared biocomposites without MAPP. The morphology study of biocomposites indicates that enhanced the interfacial interaction and adhesion between filler and matrix with the presence of MAPP.

• 폴리머
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• 제33권4호
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• pp.358-363
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• 2009

반응성기를 가지는 산무수물(maleic anhydride, MAH)을 폴리프로필렌(PP)에 도입함으로써 PP/극성 고분자의 블렌드 및 PP/filler의 복합소재 제조에서 계면과 계면 사이에 물리적 결합 이외의 화학적 결합을 향상시키고 기계적 특성 및 열적 특성을 극대화할 수 있다. 본 실험에서는 개시제(di-cumyl periofide, DCP)와 MAH 함량에 따른 그래프트율을 FT-IR과 화학적 적정법(chemical titration)을 이용하여 측정하였다. 그 결과 MAH의 함량이 증가할수록 그래프트율이 증가하였고 DCP의 함량이 0.06 wt% 일때에 가장 높은 그래프트율을 나타내었다. 또한, MAH의 함량에 따라 용융 흐름지수(melt index)가 증가하는 것을 볼 수 있었으며, 용융온도 및 열 분해 등의 열적 거동은 시차주사열량계(DSC) 및 열중량 분석기(TGA)를 이용하여 MAH 그래프트율에 따른 변화를 분석하였다.

• 터널과지하공간
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• 제14권4호
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• pp.241-247
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• 2004

본 연구에서는 숏크리트 보강용으로 폴리프로필렌 섬유의 표면을 무수말레인산이 그라프트된 폴리프로필렌(mPP)으로 표면 개질 처리한 새로운 폴리프로필렌 섬유를 개발하고, 개발된 섬유의 분산성을 조사하였다. 이 보강섬유가 혼입된 숏크리트의 강도 특성을 조사하였다.

• International Journal of Automotive Technology
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• 제6권6호
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• pp.665-670
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• 2005

Nanocomposites of polypropylene with organically modified clays were compounded on a twin-screw extruder by two-step melt compounding of three components, i.e., polypropylene, maleic anhydride grafted polypropylene (PP-g-MA), and organically modified clay. The effect of PP-g-MA compatibilizers, including PH-200, Epolene-43, Polybond-3002, Polybond-3200, with a wide range of maleic anhydride (MA) content and molecular weight was examined. Morphologies of nanocomposites and their mechanical properties such as stiffness, strength, and impact resistance were investigated. X-ray diffraction patterns showed that the dispersion morphology of clay particles seemed to be determined in the first compounding step and the further dispersion of clays didn't occur in the second compounding step. As the ratio of PP-g-MA to clay increased, the clay particles were dispersed more uniformly in the matrix resin. As the dispersibility of clays was enhanced, the reinforcement effect of the clays increased, however impact resistance decreased.

• Elastomers and Composites
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• 제57권2호
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• pp.40-47
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• 2022

The effects of maleic-anhydride-grafted polypropylene (PP-g-MAH) and montmorillonite (MMT) on the wear resistance of polypropylene (PP) were investigated. The surface of MMT was modified with 3-aminopropyltriethoxysilane, and the interfacial interaction between PP and MMT was improved using PP-g-MAH. Fourier-transform infrared spectroscopy was used to confirm that silane was grafted on the surface of MMT. The Taber abrasion test and scanning electron microscopy were used to determine the wear resistance and observe the surface morphology of PP, respectively, after wear testing. Energy-dispersive X-ray spectroscopy was used to compare the effects of PP-g-MAH and silane modification of MMT on the dispersion of MMT. The results indicated that silane was successfully grafted onto the surface of MMT. Moreover, the wear resistance of PP was improved by the addition of MMT. The wear resistance of PP composites comprising silane-modified MMT and PP-g-MAH was higher than those of other PP composites. This was attributed to silane improving the interfacial interaction between MMT and PP.