• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
• /
• pp.1188-1192
• /
• 2004

Polyamic acid precursors were prepared by mixing various main chain dianhydrides, main chain diamines and side chain diamines. Copolyimide films with alkylcyclohexylbenzene as a side chain were prepared by thermal imidization of polyamic acid precursors. Pretilt angles on rubbed polyimides changed according to the side chain and main chain structures of the polyimide. Consequently, we found that LC pretilt angles of polyimide films with a liquid crystal structure as a side chain showed to be approximately 90$^{\circ}$ when a linear and rigid polyimide main chain and a side chain of suitable length were employed.

• 멤브레인
• /
• 제28권1호
• /
• pp.67-74
• /
• 2018

고분자 분리막의 분자동역학 연구에서는 구성 원자 개수가 많고 투과 거동 계산시 긴 시간을 필요로 하기 때문에 적절한 고분자 주쇄의 길이를 선택하는 것이 매우 중요하다. 본 연구에서는 이러한 고분자 주쇄 길이와 투과 거동 간의 상관관계가 실제 분자동역학에서 어떻게 나타나는지 조사를 하고자 하였다. 널리 알려진 상용 고분자 Kapton(R) 폴리이미드 구조를 이용하여 분자동역학을 수행하였고 기체 투과 거동을 분석하였다. 고분자 주쇄의 움직임은 그 길이와 큰 연관성이 없었으며, 일반적인 인식과 달리 짧은 주쇄 길이를 갖고 있다고 해서 더 활발하게 움직이는 것은 아니라는 것을 확인할 수 있었다. 또한, 고분자 주쇄의 말단기는 상대적으로 움직이기 쉬울 것이라는 예상과 달리, 말단에 위치하지 않은 경우라도 말단기에 위치한 원자보다 더 높은 움직임을 보이는 경우도 많았다. 최종적으로 기체 분자의 투과 성능에서도 고분자 주쇄의 길이 및 말단기에 따른 영향은 관찰되지 않았다. 이는 기체 투과 전산모사에서 많이 언급되는 말단기 효과를 실제 전산모사에 적용할 경우, 각각의 모델 특성에 따라 제한적으로 적용을 하고 이에 대한 검증 과정을 반드시 수행하여야 한다는 것을 의미한다.

• 유통과학연구
• /
• 제14권9호
• /
• pp.47-64
• /
• 2016

Purpose - This study reviews the past studies that have researched Vendor Managed Inventory (VMI) as a well-known supply chain collaboration program. The main goals of this study are to figure out how VMI brings significant benefits to the supply chain system and suggest additional areas that future studies would address to discover the true nature of VMI. Research design, data, methodology - This study conducts literature reviews on numerous studies that have researched VMI. The past studies are classified in terms of several main issues that have been commonly addressed by many researchers. This study also identifies three key collaborative features of VMI, which possibly explain why VMI improves the supply chain performance. Results - This study finds out that most past studies focused on a limited research issues about VMI. Many researchers have considered integrated decision making and information sharing to be key features that enables VMI to improve the supply chain performance. Conclusions - Based on the findings from the literature review, this study suggests that future studies on VMI take account of new research issues and pay attention to cost payment that researchers have rarely addressed.

• Elastomers and Composites
• /
• 제54권1호
• /
• pp.14-21
• /
• 2019

Main-chain/side-chain liquid crystalline polymers (MCSCLCPs) combined with an azobenzene group and a cholesteryl group were synthesized to impart light and temperature sensitivity to the polymer. The polymers were designed with the azobenzene unit as the mesogenic group of the main-chain and various compositions of the azobenzene and cholesteryl units as the mesogenic group of the side-chain. The chemical structures and physical properties of the synthesized polymers were investigated by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, differential scanning calorimetry, thermogravimetric analysis, polarized optical microscopy, and ultraviolet-visible (UV-Vis) spectroscopy. All the MCSCLCPs were amorphous and exhibited enantiotropic liquid crystal phases; these polymers achieved the nematic phase with increasing content of the azobenzene group and exhibited the cholesteric phase with weak liquid crystallinity as the content of the cholesteryl group was increased. Furthermore, the polymers containing the azobenzene group showed photoisomerization when exposed to UV-Vis light, and the CP-A3C7 and CP-A5C5 polymers exhibited thermochromism in the temperature range of the liquid crystal phase.

• 한국해양공학회지
• /
• 제37권1호
• /
• pp.31-37
• /
• 2023

In this study, a fiber chain was developed to replace a steel chain using high-modulus polyethylene DM20. The pick count, wrapping count, and inner length were selected as the main design variables of the fiber chain and were analyzed to increase the breaking strength. Orthogonal array experiments were conducted, and the results were analyzed with respect to the breaking strength. The analysis revealed that the pick count and wrapping count had meaningful effects at significance levels within 5%. The main effect analysis revealed that a smaller pick count, larger wrapping count, and longer inner length caused the breaking strength to increase. With the wrapping count fixed at 1, a pick count less than -0.65, and an inner length greater than 0.38, the breaking strength was calculated to be greater than 300 kN. These results are expected be important factors in the derivation of an optimal combination of design variables to attain a fiber chain with a targeted strength.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
• /
• pp.389-392
• /
• 2005

Poly(amic acid) precursors were prepared by mixing various main chain dianhydrides, main chain diamines and side chain diamines. The side chain diamine has an alkylbicyclohexyl group as a side chain. The copolyimide films, produced by casting the poly (amic acids) solution, exhibited the vertical alignment property without the rubbing process in the range of the curing themperature from $90^{\circ}C$ to $240^{\circ}C$ for 1h. The thermal and surface properties of the poly(amic acids) depending on the curing temperature was examined.

• 대한안전경영과학회지
• /
• 제14권1호
• /
• pp.129-136
• /
• 2012

This study proposes a collaboration system framework on the web service in a supply chain to implement an efficient virtual supply chain and improve an ability to fulfill received orders over a supply chain. The system based on the framework proposed in this paper plays an important role for automatic order negotiation and placing/receiving an order noticed in web service by the main system. Furthermore, it can evaluate the fulfillment of received orders over a supply chain by using the transaction results from hierarchically related vendors and establish efficient manufacturing plans. In a word, this system is the automated system for creating manufacturing plans, placing and receiving orders. A little more important main function of this system is that it has a dynamic evaluation capability about fulfillment with received orders over a supply chain, and improves the evaluation method of fulfillment ability with received orders with related to direct dealing vendors, which is a main problem in existing system. As a result, this system is able to reduce the work load of the sales and purchasing materials, production control division, to manage accurate inventory promptly, to maintain the optimal inventory level by analyzing the information of fulfillment ability with received orders, and to enhance the level of service for customers.

• Macromolecular Research
• /
• 제16권4호
• /
• pp.360-366
• /
• 2008

Poly(dialkoxyphenylene 1,3,4-oxadiazole)s were conveniently synthesized to compare their material properties of solvent solubility, thermal stability and molecular alignment with respect to alkyl chain length and meta/para-phenylene structure. All prepared polymers exhibited good solubility in co-solvents containing various volume levels of chloroform to trifluoroacetic acid. Meta-polymers showed slightly better solubility than para-polymers. All polymers produced were thermally stable up to $320^{\circ}C$. Photoluminescence of polymer films was observed with blue light emission at around 450 nm. X-ray diffraction patterns of all polymers indicated that they were composed of stacked molecular sheets with the same layer-to-layer distance of $3.4\;{\AA}$. However, side chain-to-side chain and main chain-to-main distances within the layers increased with increasing alkyl chain lengths. The meta-polymer chains were separated more than the para-polymer chains.

• 한국고분자학회:학술대회논문집
• /
• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
• /
• pp.109-109
• /
• 2006

Flexible polymers with densely grafted side chains adopt the shape of cylindrical brushes, because the steric repulsion of the side chains overcomes the entropic restoring force of the main chain. Combined light-and neutron scattering measurements elucidate the extend of main chain and side chain stretching as function of side chain length. The application of cylindrical brushes as molecular actuators in response to external stimuli which is discussed.

• 산업공학
• /
• 제21권2호
• /
• pp.161-169
• /
• 2008

Normally, suppliers have to decide on what, how much, and when to replenish stocks of goods based on a data flow generated by a vendor managed inventory(VMI) system. But information from supply chain is often misleading. It is common for such data to be distorted by a lack of coordination and synchronization across several business entities managing different supply chain operations. This phenomenon is called the 'bullwhip effect(BwE)'. Many researchers, working over many years, have studied the reasons for the BwE. They have proposed various remedies, but this phenomenon persists. Though overlooked in previous research, this paper reveals that the 'lot size' of a supply chain of distribution is indeed the main cause of the BwE. In addition, some problems in the existing methods of measuring the BwE are identified and a revised much improved method of measurement is suggested.