• Title/Summary/Keyword: main chain

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The Structural Effects on The Pretilt Angle of Alignment Materials with Alkylcyclohexylbenzene as a Side Chain in Polyimides

  • Lee, Jong-Beom;Lee, Hyun-Kyung;Park, Jae-Chul;Kim, Yong-Bae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1188-1192
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    • 2004
  • Polyamic acid precursors were prepared by mixing various main chain dianhydrides, main chain diamines and side chain diamines. Copolyimide films with alkylcyclohexylbenzene as a side chain were prepared by thermal imidization of polyamic acid precursors. Pretilt angles on rubbed polyimides changed according to the side chain and main chain structures of the polyimide. Consequently, we found that LC pretilt angles of polyimide films with a liquid crystal structure as a side chain showed to be approximately 90$^{\circ}$ when a linear and rigid polyimide main chain and a side chain of suitable length were employed.

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Investigation of Gas Transport Properties of Polymeric Membranes having Different Chain Lengths Via Molecular Dynamics (MD) (분자동역학을 이용한 고분자 주쇄의 길이 변화에 따른 기체 투과 성능 연구)

  • Kang, Hoseong;Park, Chi Hoon
    • Membrane Journal
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    • v.28 no.1
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    • pp.67-74
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    • 2018
  • In the molecular dynamics study of polymeric membranes, it is very important to select the proper length of the polymer main chain because it requires a large number of constituent atoms and a long time to simulate the permeation behavior. In this study, we tried to investigate how the correlation between polymer main chain length and permeation behavior appears in actual molecular dynamics simulation results. Molecular dynamics were performed using the widely known commercial polymer Kapton(R) polyimide structure and the gas permeation behavior was simulated. The movement of the polymer main chain was not related to its length and the short main chain length did not act more actively. In addition, unlike the prediction that the end group of the polymer main chain is relatively easy to move, there are many cases where the atoms located at the middle of the polymer main chains have a higher movement than the atoms located at the end groups. Finally, permeabilities of the gas molecules was not affected by the length of the main chain and the end groups of the polymer, which indicates that the end effect should be carefully mentioned and followed by the verification process.

Review of Vendor Managed Inventory: Investigation on How It Improves Supply Chain Performance

  • Ryu, Chung-Suk
    • Journal of Distribution Science
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    • v.14 no.9
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    • pp.47-64
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    • 2016
  • Purpose - This study reviews the past studies that have researched Vendor Managed Inventory (VMI) as a well-known supply chain collaboration program. The main goals of this study are to figure out how VMI brings significant benefits to the supply chain system and suggest additional areas that future studies would address to discover the true nature of VMI. Research design, data, methodology - This study conducts literature reviews on numerous studies that have researched VMI. The past studies are classified in terms of several main issues that have been commonly addressed by many researchers. This study also identifies three key collaborative features of VMI, which possibly explain why VMI improves the supply chain performance. Results - This study finds out that most past studies focused on a limited research issues about VMI. Many researchers have considered integrated decision making and information sharing to be key features that enables VMI to improve the supply chain performance. Conclusions - Based on the findings from the literature review, this study suggests that future studies on VMI take account of new research issues and pay attention to cost payment that researchers have rarely addressed.

Synthesis and Properties of Combined Main-Chain/Side-Chain Liquid Crystalline Polymers with Cholesteryl and Azobenzene Groups

  • Gu, Su-Jin;Lee, Eung-Jae;Bang, Moon-Soo
    • Elastomers and Composites
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    • v.54 no.1
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    • pp.14-21
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    • 2019
  • Main-chain/side-chain liquid crystalline polymers (MCSCLCPs) combined with an azobenzene group and a cholesteryl group were synthesized to impart light and temperature sensitivity to the polymer. The polymers were designed with the azobenzene unit as the mesogenic group of the main-chain and various compositions of the azobenzene and cholesteryl units as the mesogenic group of the side-chain. The chemical structures and physical properties of the synthesized polymers were investigated by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, differential scanning calorimetry, thermogravimetric analysis, polarized optical microscopy, and ultraviolet-visible (UV-Vis) spectroscopy. All the MCSCLCPs were amorphous and exhibited enantiotropic liquid crystal phases; these polymers achieved the nematic phase with increasing content of the azobenzene group and exhibited the cholesteric phase with weak liquid crystallinity as the content of the cholesteryl group was increased. Furthermore, the polymers containing the azobenzene group showed photoisomerization when exposed to UV-Vis light, and the CP-A3C7 and CP-A5C5 polymers exhibited thermochromism in the temperature range of the liquid crystal phase.

A Study on Design Variables for Increasing the Breaking Strength of Synthetic Fiber Chain

  • Kyeongsoo Kim;Seonjin Kim;Hyunwoo Cho;Dokyoun Kim;Yongjun Kang;Taewan Kim
    • Journal of Ocean Engineering and Technology
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    • v.37 no.1
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    • pp.31-37
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    • 2023
  • In this study, a fiber chain was developed to replace a steel chain using high-modulus polyethylene DM20. The pick count, wrapping count, and inner length were selected as the main design variables of the fiber chain and were analyzed to increase the breaking strength. Orthogonal array experiments were conducted, and the results were analyzed with respect to the breaking strength. The analysis revealed that the pick count and wrapping count had meaningful effects at significance levels within 5%. The main effect analysis revealed that a smaller pick count, larger wrapping count, and longer inner length caused the breaking strength to increase. With the wrapping count fixed at 1, a pick count less than -0.65, and an inner length greater than 0.38, the breaking strength was calculated to be greater than 300 kN. These results are expected be important factors in the derivation of an optimal combination of design variables to attain a fiber chain with a targeted strength.

Synthesis and Properties of the Vertical Alignment Materials containing Liquid Crystal-like Side Chain

  • Lee, J.B.;Kang, K.H.;Kim, Y.B.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.389-392
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    • 2005
  • Poly(amic acid) precursors were prepared by mixing various main chain dianhydrides, main chain diamines and side chain diamines. The side chain diamine has an alkylbicyclohexyl group as a side chain. The copolyimide films, produced by casting the poly (amic acids) solution, exhibited the vertical alignment property without the rubbing process in the range of the curing themperature from $90^{\circ}C$ to $240^{\circ}C$ for 1h. The thermal and surface properties of the poly(amic acids) depending on the curing temperature was examined.

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A Case Study on the e-SCM Web-service Design for Auto-parts Industry of a Commercial Vehicle (상용차 부품 조달 기업을 위한 e-SCM 웹서비스 설계 및 구현 사례 연구)

  • Oh, Myung-Hyun;Yang, Jae-Kyung
    • Journal of the Korea Safety Management & Science
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    • v.14 no.1
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    • pp.129-136
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    • 2012
  • This study proposes a collaboration system framework on the web service in a supply chain to implement an efficient virtual supply chain and improve an ability to fulfill received orders over a supply chain. The system based on the framework proposed in this paper plays an important role for automatic order negotiation and placing/receiving an order noticed in web service by the main system. Furthermore, it can evaluate the fulfillment of received orders over a supply chain by using the transaction results from hierarchically related vendors and establish efficient manufacturing plans. In a word, this system is the automated system for creating manufacturing plans, placing and receiving orders. A little more important main function of this system is that it has a dynamic evaluation capability about fulfillment with received orders over a supply chain, and improves the evaluation method of fulfillment ability with received orders with related to direct dealing vendors, which is a main problem in existing system. As a result, this system is able to reduce the work load of the sales and purchasing materials, production control division, to manage accurate inventory promptly, to maintain the optimal inventory level by analyzing the information of fulfillment ability with received orders, and to enhance the level of service for customers.

Facile Synthesis and Characterization of Poly(dialkoxy-p-phenylene 1,3,4-oxadiazole-alt-phenylene 1,3,4-oxadiazole)s

  • Kim, Hoon-Seok;Kang, Soon-Min;Do, Jung-Yun
    • Macromolecular Research
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    • v.16 no.4
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    • pp.360-366
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    • 2008
  • Poly(dialkoxyphenylene 1,3,4-oxadiazole)s were conveniently synthesized to compare their material properties of solvent solubility, thermal stability and molecular alignment with respect to alkyl chain length and meta/para-phenylene structure. All prepared polymers exhibited good solubility in co-solvents containing various volume levels of chloroform to trifluoroacetic acid. Meta-polymers showed slightly better solubility than para-polymers. All polymers produced were thermally stable up to $320^{\circ}C$. Photoluminescence of polymer films was observed with blue light emission at around 450 nm. X-ray diffraction patterns of all polymers indicated that they were composed of stacked molecular sheets with the same layer-to-layer distance of $3.4\;{\AA}$. However, side chain-to-side chain and main chain-to-main distances within the layers increased with increasing alkyl chain lengths. The meta-polymer chains were separated more than the para-polymer chains.

Properties of Cylindrical Brush Polymers

  • Zhang Bin;Fischerl Karl;Grohn Franziska;Pedersen J S.;Schmidt Manfred
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.109-109
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    • 2006
  • Flexible polymers with densely grafted side chains adopt the shape of cylindrical brushes, because the steric repulsion of the side chains overcomes the entropic restoring force of the main chain. Combined light-and neutron scattering measurements elucidate the extend of main chain and side chain stretching as function of side chain length. The application of cylindrical brushes as molecular actuators in response to external stimuli which is discussed.

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Bullwhip Effect and Lot Size: the Main Cause of BwE is Lot Size (황소채찍효과와 발주크기: 대형할인마트에서의 황소채찍효과)

  • Paik, Si-Hyun
    • IE interfaces
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    • v.21 no.2
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    • pp.161-169
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    • 2008
  • Normally, suppliers have to decide on what, how much, and when to replenish stocks of goods based on a data flow generated by a vendor managed inventory(VMI) system. But information from supply chain is often misleading. It is common for such data to be distorted by a lack of coordination and synchronization across several business entities managing different supply chain operations. This phenomenon is called the 'bullwhip effect(BwE)'. Many researchers, working over many years, have studied the reasons for the BwE. They have proposed various remedies, but this phenomenon persists. Though overlooked in previous research, this paper reveals that the 'lot size' of a supply chain of distribution is indeed the main cause of the BwE. In addition, some problems in the existing methods of measuring the BwE are identified and a revised much improved method of measurement is suggested.