• 제목/요약/키워드: magnetic transition

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Content and Distribution of Transition Metals and Rare Earth Elements in Magnetically and Mechanically Separated Brown Coal Ash

  • Malikov, Sh.R.;Pikul, V.P.;Mukhamedshina, N.M.;Sandalov, V.N.;Kudiratov, S.;Ibragimova, E.M.
    • Journal of Magnetics
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    • 제18권3호
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    • pp.365-369
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    • 2013
  • Coal ash is known to contain a noticeable amount of valuable elements, including transition metals and lanthanides. Therefore it is quite actual problem to extract them for metallurgy and other applications. This paper presents the results of high gradient magnetic and mechanical separation, microscopy, element analyses and optical spectroscopy of brown coal ash taken from the combustion camera and chimney-stalk of Angren thermal power station. The separated magnetic fraction was 3.4 wt.%, where the content of Fe in ferrospheres increased to 58 wt.%. The highest contents of Fe and rare earth elements were found in the fine fractions of $50-100{\mu}m$. Optical absorption spectroscopy of water solutions of the magnetic fractions revealed $Fe^{2+}$ and $Fe^{3+}$ ions in the ratio of ~1:1. The separated coal ash could be used for cleaning of technological liquid waste by means of the high gradient magnetic field.

Ferromagnic Transitition Temperature of Diluted Magnetic III-V Based Semiconductor (III-V 화합물 자성 반도체의 강자성체 천이온도에 관한 연구)

  • Lee, Hwa-Yong;Kim, Song-Gang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 한국전기전자재료학회 2001년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 연구회
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    • pp.143-147
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    • 2001
  • Ferromagnetism in manganese compound semiconductors open prospects for tailoring magnetic and spin-related phenomena in semiconductors with a precision specific to III-V compounds. Also it addresses a question about the origin of the magnetic interactions that lead to a Curie temperature(Tc) as high as 110 K for a manganese concentration of just 5%. Zener's model of ferromagnetism, originally suggested for transition metals in 1950, can explain Tc of $Ga_{1-x}Mn_x$ As and that of its IT-VI counterpart $Zn_{1-x}Mn_x$ Te and is used to predict materials with Tc exceeding room temperature, an important step toward semiconductor electronics that use both charge and spin. In this article, we present not only the experimental result but calculated Curie temperature by RKKY interaction. The problem in making III-V semiconductor has been the low solubility of magnetic elements, such as manganese, in the compound, since the magnetic effects are roughly proportional to the concentration of the magnetic ions. Low solubility of magnetic elements was overcome by low-temperature nonequilibrium MBE{molecular beam epitaxy) growth, and ferromagnetic (Ga,Mn)As was realized. Magnetotransport measurements revealed that the magnetic transition temperature can be as high as 110 K for a small manganese concentration.

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Consecutive transition limited code for high-density magnetic recording channel (고밀도 자기기록 채널을 위한 연속적인 천이의 제한을 갖는 코드)

  • 이주현;이재진
    • The Journal of Korean Institute of Communications and Information Sciences
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    • 제28권12C호
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    • pp.1177-1181
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    • 2003
  • The modulation code with the limitation of consecutive transition length is a type of channel codes in high-density magnetic recording channel. When code sequence has two or less successive transitions, the detection performance of channel outputs can be improved. However, the code rate is reduced considerably. We present a rate 7/8 nut-length limited (RLL) code that consecutive transition length of each codeword is limited to 2 (j=2), and j is allowed to be 3 when codewords are connected. In addition, the consecutive zeros of the proposed code is limited to 7 (k=7).

Cyclotron Resonance of the Wannier-Landau Transition System Based on the Ensemble Projection Technique

  • Jung-Il Park
    • Journal of the Korean Magnetic Resonance Society
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    • 제27권4호
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    • pp.28-34
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    • 2023
  • We study the linear-nonlinear quantum transport theory of Wannier-Landau transition system in the confinement of electrons by a square well confinement potential. We use the projected Liouville equation method with the ensemble density projection technique. We select the dynamic value under a linearly oscillatory external field. We derive the dynamic value formula and the memory factor functions in three electron phonon coupling systems and electron impurity coupling systems of two transition types, the intra-band transitions and inter-band transitions. We obtain results that can be applied directly to numerical analyses. For simple example of application, we analyze the absorption power and line-widths of ZnO, through the numerical calculation of the theoretical result in the Landau system.

133Cs Nuclear Magnetic Resonance Relaxation Study of the Phase Transition of Cs2MnCl4·2H2O Single Crystals

  • Heo, Cheol;Lim, Ae-Ran
    • Journal of the Korean Magnetic Resonance Society
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    • 제14권2호
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    • pp.76-87
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    • 2010
  • The structural phase transition of $Cs_2MnCl_4{\cdot}2H_2O$ single crystals was investigated by determining the $^{133}Cs$ spin-lattice relaxation time $T_1$. The number of resonance lines in the $^{133}Cs$ spectrum changes from seven to one near 375 K, which means that above 375 K the Cs sites are symmetric. Further, the $T_1$ of the $^{133}Cs$ nucleus undergoes a significant change near 375 K, which coincides with the change in the splitting of the $^{133}Cs$ resonance lines. The change in $T_1$ near $T_C$ is related to the loss of $H_2O$, and means that the forms of the octahedra of water molecules surrounding $Cs^+$ are disrupted.

Investigation of Spin Reorientation in Ga Substituted Y-type Hexaferrite based on Mössbauer Spectroscopy

  • Lim, Jung Tae;Kim, Jeonghun;Kim, Chul Sung
    • Journal of the Korean Physical Society
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    • 제73권11호
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    • pp.1708-1711
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    • 2018
  • The polycrystalline sample of $Ba_2Co_{1.5}Mg_{0.5}Fe_{11.88}Ga_{0.12}O_{22}$ Y-type hexaferrite, doped with Ga-cation, was prepared by using the solid-state reaction method. The crystalline structure of sample was investigated by x-ray diffractometer (XRD), and the magnetic properties of sample were measured by vibrating sample magnetometer (VSM), and $M{\ddot{o}}ssbauer$ spectrometer. The crystal structure of prepared sample was determined to be rhombohedral with space group R-3m. From the temperature dependence of the magnetization curves under 100 Oe between 4.2 and 740 K, two temperature-dependent magnetic transitions occurred in the $Ba_2Co_{1.5}Mg_{0.5}Fe_{11.88}Ga_{0.12}O_{22}$ sample. $M{\ddot{o}}ssbauer$ spectra of the sample were analyzed at various temperatures ranging from 4.2 to 620 K, and the $Ba_2Co_{1.5}Mg_{0.5}Fe_{11.88}Ga_{0.12}O_{22}$ sample showed abrupt changes in $H_{hf}$ and $E_Q$ at 200 K, indicating the spin transition effect. We have also determined the magnetic transition temperature $T_C$, in addition to the temperature dependent magnetization and ZVC measurements.

Electrical resistivity and magnetization of Sr$_{1-x}K_xBiO_3$ superconductor in magnetic field: Observation of a reentrant superconducting resistive transition at low temperature

  • Kim, J.S.;Kim, D.C.;Joo, S.J.;Kim, G.T.;Lee, S.Y.;Khim, Z.G.;Bougerol-Chaillout, C.;Kazakov, S.M.;Pshirkov, J.S.;Antipov, E.V.;Park, Y.W.
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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    • pp.210-213
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    • 1999
  • Magnetoresistance and magnetization of Sr$_{l-x}K_xBiO_3$ were both measured as functions of temperature and magnetic field. Resistivity goes to zero at T=10.1K and the overall superconducting transition behavior under applied magnetic fields is similar to that of other BiO based superconductors. Also, below T<5K we have observed the reappearance of finite resistivity with a power law temperature dependence( ${\rho}$ ${\sim}$T$^1$); the reentrant superconducting transition of resistivity. Contrary to the Josephson weak link effect in polycrystalline samples, which gives the depression of the superconducting state with increasing electrical current or magnetic field, the superconducting state for T<5K is resumed by applying a higher current or magnetic field. Magnetic susceptibility( ${\chi}$ ) of Sr$_{l-x}K_xBiO_3$ for T<5K also shows similar trends to that observed in transport measurements: increase of ${\chi}$ (paramagnetic-like behavior) at a low magnetic fields(B=50 Oe) and, the resumption of perfect diamagnetism at high fields.

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The Study on Magnetic Properties of Transition Metal Doped Semiconductor (전이금속이 치환된 반도체 물질의 자기적 특성 연구)

  • Kim, Jae-Uk;Cha, Byung-Kwan;Ji, Myoung-Jin;Kwon, Tae-Phil;Park, Byoung-Cheon;Kyoung, Dong-Hyoun;Jin, Hoon-Yeol;Kim, Seung-Hoi;Kim, Jong-Gyu
    • Journal of the Korean Chemical Society
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    • 제54권6호
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    • pp.766-770
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    • 2010
  • This is the study of magnetic properties of transition metal doped diluted magnetic semiconductors(DMSs). The wurtzite structure samples were synthesized by the sol-gel method. The thermodynamic characteristics and magnetic properties of $Zn_{1-x}Co_xO$ single phase was investigated for different doping concentration (x = 0%, 1%, 2%, 3%, 4%, 5%, 10%, 15%). The property of diluted magnetic semiconductors has been comfirmed by X-ray diffraction (XRD), Scanning Electronic Microscope (SEM) and Vibrating sample magnetometer (VSM). The magnetic properties of pure $Zn_{1-x}Co_xO$ is found to be dominated by the ferromagnetic interaction between doped transition metal ions, where by the ferromagnetic coupling strength is simply increased with the concentration(>5%) of the doped transition metal.

Bonding And Anti-bonding Nature of Magnetic Semiconductor Thin Film of Fe(TCNQ:tetracyanoquinodimethane)

  • Jo, Junhyeon;Jin, Mi-jin;Park, Jungmin;Modepalli, Vijayakumar;Yoo, Jung-Woo
    • Proceedings of the Korean Vacuum Society Conference
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.294-294
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    • 2014
  • Developing magnetic thin films with desirable physical properties is a key step to promote research in spintronics. Organic-based magnetic material is a relatively new kind of materials which has magnetic properties in a molecular and microscopic level. These materials have been constructed by the coordination between 3d transition metal and organic materials producing long-range magnetic orders with a relatively high transition temperature. However, these materials were mostly synthesized as a form of powder, which is difficult to study for their physical properties as well as apply for electronic/spintronic devices. In this study, we have employed physical vapor deposition (PVD) to develop a new organic-based hybrid magnetic film that is achieved by the coordination of Fe and tetracyanoquinodimethane (TCNQ). The IR spectra of the grown film show modified CN vibration modes in TCNQ, which suggest a strong bonding between Fe and TCNQ. The thin film has both ferromagnetic and semiconducting behaviors, which is suitable for molecular spintronic applications. The high resolution photoemission (HRPES) spectra also show shift of 1s peak point of nitrogen and the carbon 1s peaks display traces of charge transfer from Fe to TCNQ as well as shake-up features, which suggest strong bonding and anti-bonding nature of coordination between Fe and TCNQ.

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Consideration the Writing and Reproducting Pattern of Isolated Transition of Magnetization in Perpendicular Magnetic Recording System by using F.E.M. (유한요소법에 의한 수직자기기록장치의 단일자화반전기록 및 재생에 관한 고찰)

  • Lee, Hyang-Beom;Park, Gwan-Soo;Hahn, Song-Yop
    • Proceedings of the KIEE Conference
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    • 대한전기학회 1990년도 추계학술대회 논문집 학회본부
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    • pp.28-31
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    • 1990
  • In perpendicular magnetic recording system, the magnetic recording and reproduction characteristics of isolated transition of magnetization is simulated in this paper. The recording system which is magneto-static system is analyzed using two-dimensional finite element method and the characteristics of hysteresis of recording media is considered. The results show that the optimizing current is exist in magnetic recording system.

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