• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1193-1194
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• 2006

The magnetic ferrite nanoparticles were synthesized and coated by silica precursor in controlling the coating thicknesses and sizeses. The surface modification was performed with amino-functionalized organic silanes on silica coated magnetic nanoparticles. The use of functionalized self-assembled magnetic ferrite nanoparticles for nucleic acid separation process give a lot of advantages rather than the conventional silica based process.

• Bulletin of the Korean Chemical Society
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• 제30권4호
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• pp.869-872
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• 2009

Double-doped magnetic particles that incorporated magnetites into both the surface and inside the silica cores were fabricated via the sol-gel reaction of citrate-stabilized magnetites with silicon alkoxide. Double-doped magnetic particles were easily fabricated and exhibited an higher magnetism in comparison to the singledoped magnetic particles that were prepared by the erosion of surface-deposited magneties from double-doped magentic particles. Thin gold layer was formed over magnetic silica nanospheres via nanoseed-mediated growth of gold clusters. The plasmon-derived absorption bands of double-doped magnetic silica-gold nanoshells were more broadened and shifted down by ca. 20 nm as compared to those of single-doped magnetic silicagold nanoshells, which were attributed to not only the surface scattering of incident light due to relatively rough surafce morphology, but also heterogeneous permittivity of dielectric cores due to surface-deposited magnetites.

• Bulletin of the Korean Chemical Society
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• 제33권12호
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• pp.4165-4168
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• 2012

Magnetic fluorescent silica nanotubes were fabricated using reverse micro-emulsions coupled with conventional sol-gel methods. Anodic aluminum oxide templates were used to separate spatially the magnetic and the fluorescent moieties on individual nanotubes and so prevent quenching of the fluorescence. C18 and fluorescent layers were deposited sequentially on silica. Magnetism was then obtained by the introduction of pre-made magnetic nanoparticles inside the nanotubes. The photo- and chemical stabilities of nanotubes were demonstrated through dye release and photobleaching tests. The produced nanotubes did not show fluorescence quenching upon the addition of the nanoparticles, an advantage over conventional spherical fluorescent magnetic nanoparticles. High photostability of nanotubes, magnetism and biocompatiblily make them potentially useful in bioanalysis.

• Advances in concrete construction
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• 제5권2호
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• pp.87-99
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• 2017

After passing through a magnetic field, the physical quality of water improves, and magnetic water (MW) is produced. There are many investigations on the effects of magnetic field on water that shows MW properties like saturation and memory effect. This study investigates the fresh and hardened properties of concrete mixed with MW, which contains silica fume (SF) and superplasticizer (SP). The test variables included the magnetic field intensity for producing MW (three kinds of water), SF content replaced cement (0 and 10 percent), water-to-cementitious materials ratio (W/CM=0.25, 0.35 and 0.45) and curing time (7, 28 and 90 days). The results of this study show that MW had a positive impact on the workability and compressive strength of concrete. By rising the intensity of the magnetic field which was used for producing MW, its positive influence on both workability and compressive strength improved. MW had greater positive impacts on samples containing SP that did not have SF. Moreover, the best compressive strength improvements of concrete achieved as W/CM ratio decreased.

• 한국세라믹학회지
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• 제22권6호
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• pp.21-28
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• 1985

The properties of magnetic recording materials largely depend on their shape magnetic anisotropy. The control of their shape and size distribution is very important for improving magnetic properties. The silica-coated goethite$(SiO_2$/$\alpha$-FeOOH=1.5wt%) having acicular shape was prepared. The sillica-coated goethite was heat-treated at 40$0^{\circ}C$~1,00$0^{\circ}C$ 1hr and then reduced at 50$0^{\circ}C$ 2hr. When the silica-coated goethite was heat-treated at 80$0^{\circ}C$ its acicular shape was maintained and its magnetic properties were improved(Hc: 1,325 Oe $\sigma$m:138.8 emu/g, Rs:0.56) However the acicular shape of the paricles was broken for non-coated hematite obtained by dehydration at 80$0^{\circ}C$ They were sintered and showed poor magnetic properties.

• 한국산학기술학회논문지
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• 제17권1호
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• pp.181-187
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• 2016

실리카는 다양한 산업용 소재로 이용되고 있으며, 특히 불순물의 함량이 적은 고품위 실리카는 전자소재인 LCD 및 OLED 등의 원재료로 큰 주목을 받고 있다. 본 연구에서는 물리적 정제방법인 자력선별 방식에 의한 실리카의 고순도화 연구를 위해 세 가지 형태의 자력 선별기를 고려하여 $SiO_2$와 $Fe_2O_3$를 대상으로 전산모사를 실시하였다. 전산모사 결과, $Fe_2O_3$ 입자를 끌어당길 수 있는 유효면적이 자력선별의 매우 중요한 변수로 작용함을 확인하였으며, $SiO_2$ 입자의 손실율 및 $Fe_2O_3$ 입자의 제거율은 입자의 크기와 유속에 매우 큰 영향을 받음을 알 수 있었다. 본 연구에서는 입자크기 $10{\mu}m$, 유속 0.2 m/s의 조건에서 가장 우수한 분리효율의 확보가 가능하였으며, 자력선별기의 구성에 있어 입자의 크기, 유속, 자속 밀도가 매우 핵심적인 변수임을 증명하였다.

• 한국자기학회지
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• 제3권2호
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• pp.108-114
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• 1993

자기기록매체에 적합한 실리카 피착 ${\gamma}-Fe_{2}O_{3}$ 제조에 있어서 실리카 피착의 효과와 영향에 대하여 검토하였다. 특히 ${\gamma}-Fe_{2}O_{3}$ 제조시 열처리단계에 있어서 실리카 피착의 효과와 분말의 특성과의 상관관계를 조사하는데 연구의 중점을 두었다. 수산화철 표면에 무기물질인 실리카성분을 물유리를 사용하여 피착한 시료와 피복하지않은 시료를 후속 열처리하여 ${\gamma}-Fe_{2}O_{3}$를 제조한후 이들 분말의 특성을 조사하였다. ${\gamma}-Fe_{2}O_{3}$에 피복된 실리카 피착층은 환원 시 과환원과 급속한 산화반응을 억제하는 확산장벽으로 작용하여 최종제품내에 ${\alpha}-Fe_{2}O_{3}$의 혼입을 방지하기 때문에 실리카 피복된 ${\gamma}-Fe_{2}O_{3}$는 높은 자화특성을 나타내었다. 또한 실리카 피척층은 소결 억제제로 작용하여 실리카가 피복된 시료의 경우 침상성이 우수하여 높은 보자력과 비표면적을 나타내었다.

• 한국세라믹학회지
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• 제47권2호
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• pp.113-116
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• 2010

The silica coated $Fe_3O_4$ nanoparticles have been synthesized using a micro-emulsion method. The $Fe_3O_4$ nanoparticles with the sizes 6 nm in diameter were synthesized by thermal decomposition method. Hydrophobic $Fe_3O_4$ nanoparticles were coated silica using surfactant and tetraethyl orthosilicated (TEOS) as a $SiO_2$ precursor. Shell thickness of silica coated $Fe_3O_4$ can be controlled (11~20 nm) through our synthetic conditions. The $Fe_3O_4$ and silica coated $Fe_3O_4$ nano powders were characterized by transmission electron microscopy (TEM), x-ray diffraction (XRD) and vortex magnetic separation (VMS).

• 한국세라믹학회지
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• 제23권2호
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• pp.31-37
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• 1986

The effect of dehydration temperature on the reduction process of silica-coated hematite was invest-igated The particle shape and magnetic properties of the products reduced from hematite at various conditions and the oxidation resistance of silica-coated iron powder were examined. It was revealed that single phase iron powder obtained over 45$0^{\circ}C$ had good magnetic properties. The iron powder manufactured between 45$0^{\circ}C$ and 50$0^{\circ}C$ displayed the maximum coercive force as a result of maintaining its acicular shaped. However the coercive force of iron powder reduced over 50$0^{\circ}C$ was decreased. The oxidation resistance of silica-coated iron powder in air was very good up to 11$0^{\circ}C$ and for 12 days.

• 한국세라믹학회지
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• 제45권10호
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• pp.605-609
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• 2008

This work describes the preparation of functionalized magnetic nanoparticles(MNPs) and their bioapplication to human DNA separation. Silica coated MNPs were prepared by changing the volume ratio of tetraethyl orthosilicate(TEOS) for controlled coating thickness on the original nanoparticle of MNPs. The sol-gel process in silica coating on MNPs surface was adapted for relatively mild reaction condition, low-cost, and surfactant-free. And then amino functionalized magnetic nanoparticles were synthesized using amine groups as surface modifiers. The result of adsorption efficiency for human DNA with amino-functionalized silica coated MNPs was calculated as a function of the number of amine groups.